| Identification | More | [Name]
N-(n-Butyl)thiophosphoric triamide | [CAS]
94317-64-3 | [Synonyms]
N-BUTYLTHIOPHOSPHORIC TRIAMIDE
N-(N-BUTYL)THIOPHOSPHORIC TRIAMIDE
butyl-phosphorothioictriamid
N-(N-BUTYL)-THIOPHORIC TRIAMIDE (NBPT)
N-(n-Butyl)thiophosphoricTriamide=NBPT
N-(N-BUTYL)THIOPHOSPHORICACID
Butylphosphorothioic triamide
N-(n-Butyl)thiophosphoric triamide ,97%
(Butylamino)diaminophosphine sulfide
BTPT | [EINECS(EC#)]
237-066-7 | [Molecular Formula]
C4H14N3PS | [MDL Number]
MFCD00269941 | [Molecular Weight]
167.21 | [MOL File]
94317-64-3.mol |
| Chemical Properties | Back Directory | [Appearance]
White Crystalline Solid | [Melting point ]
58-60°C | [Boiling point ]
277.4±23.0 °C(Predicted) | [density ]
1.171±0.06 g/cm3(Predicted) | [vapor pressure ]
0.001-1.7Pa at 25℃ | [Fp ]
96°C | [storage temp. ]
−20°C | [solubility ]
DMSO (Sparingly), Methanol (Slightly) | [form ]
Solid | [pka]
6.23±0.70(Predicted) | [color ]
White to Off-White | [Water Solubility ]
4.3 g/L at 25 ºC | [Sensitive ]
Stench | [Usage]
A urease inhibitor | [Detection Methods]
T,NMR | [InChI]
1S/C4H14N3PS/c1-2-3-4-7-8(5,6)9/h2-4H2,1H3,(H5,5,6,7,9) | [InChIKey]
HEPPIYNOUFWEPP-UHFFFAOYSA-N | [SMILES]
S=P(NCCCC)(N)N | [LogP]
-0.32-0.444 at 20-25℃ | [CAS DataBase Reference]
94317-64-3(CAS DataBase Reference) | [EPA Substance Registry System]
94317-64-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
WGK 1 | [Hazard Note ]
Stench | [TSCA ]
TSCA listed | [HS Code ]
29299090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Dam. 1
Repr. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
White Crystalline Solid | [Uses]
A urease inhibitor | [Flammability and Explosibility]
Nonflammable | [Synthesis]
General procedure for the synthesis of n-butylthiophosphoric triamine from the compound (CAS: 6141-81-7): first, ammonia was passed through cold hydrazine and externally observed until liquid ammonia was formed. A cooling device was started in a four-necked flask equipped with a stirrer to maintain the reaction temperature at -45°C. Subsequently, 12.75 g of liquid ammonia was added to the flask and the pre-cooled reaction solution was added dropwise stepwise. The dropwise addition process was controlled to be completed within 1.5 hours. Samples were taken during the reaction and when the content of N-butylamino thiophosphoryl dichloride decreased to 2% of the total mass, the reaction temperature was raised to 25°C. The reaction was continued until the substitution reaction was completed, with a total reaction time of 2 h 5 min. At the end of the reaction, the product was filtered, washed and vaporized, and finally recrystallized from n-hexane to obtain N-n-butylaminophosphorothioic acid triamine with a purity of 98.7% and a yield of 95.1%. | [References]
[1] Patent: CN105399767, 2016, A. Location in patent: Paragraph 0045; 0047
[2] Patent: US2011/196172, 2011, A1. Location in patent: Page/Page column 4
[3] Chemische Berichte, 1956, vol. 89, p. 1768,1770
[4] Patent: US2011/28761, 2011, A1. Location in patent: Page/Page column 4
[5] Patent: CN105440073, 2016, A. Location in patent: Paragraph 0038; 0041 |
|
|