| Identification | More | [Name]
(2R)-Bornane-10,2-sultam | [CAS]
94594-90-8 | [Synonyms]
(-)-10,2-CAMPHORSULTAM
(1S)-(-)-2,10-CAMPHORSULTAM
(1S)-2,10-CAMPHORSULTAM
(1S,2R)-(-)-2,10-CAMPHORSULTAM
(1S,5R)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.0(1,5)]DECANE 3,3-DIOXIDE
(2R)-BORNANE-10,2-SULTAM
[3AS-(3A-ALPHA,6-ALPHA,7A-BETA)]-HEXAHYDRO-8,8-DIMETHYL-2,2-DIOXIDE-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE
[3as-(3aalpha,6alpha,7abeta)]-hexahydro-8,8-dimethyl-2,2-dioxide-3h-3a,6-methano-2,1-benzisothiazole
[3AS-(3AALPHA,6ALPHA,7ABETA)]-HEXAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE-2,2-DIOXIDE
D(-)-10,2-CAMPHORSULTAME
(-)-D-2,10-CAMPHORSULTAM
(-)-D-2,10-CAMPHOSULTAM
(-)-EXO-10,2-BORNANESULTAM
(1S)-(-)-Camphorsultam
(1S,2R)-(-)-10,2-Camphorsultam
(1S,2R)-(-)-2,10-CAMPHORSULTAME
3H-3a,6-Methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-
D-(+)-CAMPHOR SULTAM INFRA-ACIDAMIDE
L-(+)-CAMPHOR SULTAM
(-)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide | [Molecular Formula]
C10H17NO2S | [MDL Number]
MFCD00066271 | [Molecular Weight]
215.31 | [MOL File]
94594-90-8.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
183-185 °C
| [alpha ]
-33 º (c=4.9, CHCl3) | [Boiling point ]
324.8±25.0 °C(Predicted) | [density ]
1.1469 (rough estimate) | [refractive index ]
-31 ° (C=1, CHCl3) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform, Ethanol, Methanol | [form ]
Liquid | [pka]
11.05±0.40(Predicted) | [color ]
Clear colorless | [Optical Rotation]
[α]19/D 32°, c = 5 in chloroform | [Water Solubility ]
Slightly soluble in water. | [BRN ]
83811 | [InChI]
1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1 | [InChIKey]
DPJYJNYYDJOJNO-NQMVMOMDSA-N | [SMILES]
[H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C | [CAS DataBase Reference]
94594-90-8(CAS DataBase Reference) | [NIST Chemistry Reference]
(-)-10,2-Camphorsultam(94594-90-8) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P280a-P304+P340-P305+P351+P338-P405-P501a | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29349990 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
(2R)-Bornane-10,2-sultam is a reagent used to make Camphorsultam conjugates.
| [General Description]
(1S,2R,4R)-(?)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. | [Purification Methods]
The (-)-enantiomer is recrystallised from 95% EtOH and dried in a vacuum desiccator. It dissolves in dilute aqueous NaOH and can be precipitated without hydrolysis by acidifying. It forms the N-Na salt in EtOH (by addition of Na to the EtOH solution), and the salt can be methylated with MeI to give the (-)-N-Me lactam with m 80o after recrystallisation from hot H2O and has []D -59.6o (c 5, CHCl3) [Shriner et al. J Am Chem Soc 60 2794 1938]. [Oppolzer et al. Helv Chim Acta 69 1142 1986, Weismiller et al. Org Synth 69 154 1955, Beilstein 27 III/IV 1007.] |
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