ChemicalBook--->CAS DataBase List--->95-03-4

95-03-4

95-03-4 Structure

95-03-4 Structure
IdentificationMore
[Name]

5-Chloro-2-methoxyaniline
[CAS]

95-03-4
[Synonyms]

2-AMINO-4-CHLOROANISOLE
2-METHOXY-5-CHLOROANILINE
4-CHLORO-2-AMINOANISOL
4-CHLORO-2-AMINOANISOLE
5-Chloro-2-anisidine
5-CHLORO-2-METHOXYANILINE
5-CHLORO-O-ANISIDINE
AKOS BBS-00003626
FAST RED RC BASE
P-CHLORO-O-AMINOANISOLE
2-Amino-4-chioroanisole
5-chloro-2-methoxy-benzenamin
5-Chloro-2-methoxybenzenamine
4-CHLORO-O-ANISIDINE 97%
5-Chloro-2-methoxyaniline,98%
5-CHLORO-ORTHO-ANISIDINE
Benzenamine,5-chloro-2-methoxy-
5-CHLORO-2-METHOXYANILINE/5-CHLORO-O-ANISIDINE
5-CHLORO-O-ANISIDINE 98%
2-Amino-4-chloroanisole, 5-Chloro-o-anisidine
[EINECS(EC#)]

202-385-2
[Molecular Formula]

C7H8ClNO
[MDL Number]

MFCD00007777
[Molecular Weight]

157.6
[MOL File]

95-03-4.mol
Chemical PropertiesBack Directory
[Appearance]

Off-white to tan crystalline powder or flakes
[Melting point ]

81-83 °C(lit.)
[Boiling point ]

135 °C (5.85078 mmHg)
[density ]

1.1760 (rough estimate)
[refractive index ]

1.5430 (estimate)
[Fp ]

136 °C
[pka]

3.48±0.10(Predicted)
[BRN ]

879161
[CAS DataBase Reference]

95-03-4(CAS DataBase Reference)
[EPA Substance Registry System]

Benzenamine, 5-chloro-2-methoxy- (95-03-4)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 2233 6.1/PG 3
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29222990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Iron-->o-Anisidine-->Iron oxide-->PETROLEUM ETHER-->63083-96-5-->4,5-Dichloro-2-Methoxyaniline-->4-Chloro-2-nitroanisole-->Phenol-->Ethanol-->4-Chlorophenol-->4-Chloroanisole
[Preparation Products]

4-Chloro-2-fluoroanisole-->4-Chloro-2-anisidine hydrochloride-->2-Chloro-5-methoxyaniline-->SOLVENT VIOLET 2-->disodium hydrogen bis[5-[(5-chloro-2-hydroxyphenyl)azo]-6-hydroxynaphthalene-2-sulphonato(3-)]chromate(3-)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

5-chloro-2-anisidine(95-03-4).msds
Hazard InformationBack Directory
[Chemical Properties]

Off-white to tan crystalline powder or flakes
[Uses]

5-Chloro-2-methoxybenzenamine is used in preparation of appetite-modulating molecules.
[Preparation]

4-Chloro-1-methoxy-2-nitrobenzene reduction.
[Purification Methods]

Purify the aniline by steam distillation and recrystallisation from H2O or 40% aqueous EtOH. The N-acetate forms needles from hot H2O with m 104o, the N-benzoyl derivative forms needles from aqueous EtOH with m 77-78o, and the picrate has m 194o(dec). [Raiford & Colbert J Am Chem Soc 48 2657 1926, Beilstein 13 IV 879.]
Spectrum DetailBack Directory
[Spectrum Detail]

5-Chloro-2-methoxyaniline(95-03-4)MS
5-Chloro-2-methoxyaniline(95-03-4)1HNMR
5-Chloro-2-methoxyaniline(95-03-4)13CNMR
5-Chloro-2-methoxyaniline(95-03-4)IR1
5-Chloro-2-methoxyaniline(95-03-4)IR2
5-Chloro-2-methoxyaniline(95-03-4)IR3
5-Chloro-2-methoxyaniline(95-03-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

5-Chloro-o-anisidine, 98%(95-03-4)
[Alfa Aesar]

5-Chloro-2-methoxyaniline, 98%(95-03-4)
[Sigma Aldrich]

95-03-4(sigmaaldrich)
[TCI AMERICA]

5-Chloro-2-methoxyaniline,>98.0%(GC)(95-03-4)
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