| Identification | Back Directory | [Name]
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold | [CAS]
951776-24-2 | [Synonyms]
IPrAuNTf2
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I)
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)
[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%
(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)((1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)methyl)sulfonamido)gold(I)
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold | [Molecular Formula]
C29H36AuF6N3O4S2 | [MDL Number]
MFCD22572651 | [MOL File]
951776-24-2.mol | [Molecular Weight]
865.7 |
| Chemical Properties | Back Directory | [Melting point ]
202-287°C (decomposition) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
solid | [color ]
white to pale yellow | [Sensitive ]
air sensitive | [InChIKey]
FLIVFZVCPOQPDV-UHFFFAOYSA-N | [SMILES]
CC(C)c1cccc(C(C)C)c1N2C=CN(C2=[Au]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F)c3c(cccc3C(C)C)C(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Gold catalyst used for the hydroarylating cyclization of 1,2-bis(2-iodoethynyl)benzenes.
- Gold catalyst used for the carbocyclization of phenols with a terminal alkyne.
- Intermolecular C-H activation through the gold(I)-catalyzed reaction of iodoalkynes.
- Reaction of ynamide with benzyl azides.
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