[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat)

PROTOVERATRINE B Struktur
124-97-0
CAS-Nr.
124-97-0
Bezeichnung:
[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat)
Englisch Name:
PROTOVERATRINE B
Synonyma:
yrate);veratetrin;neoprotoveratrin;PROTOVERATRINE B;NEOPROTOVERATRINE;PROTOVERATRINE B (RG);PROTOVERATRINE A (RG)(CALL);4-beta,6-alpha,7-alpha,14,15-alpha-16-beta,20-octol,4,9-epoxy-cevane-3-bet;6,7-diacetate3-(threo-(+)-2,3-dihydroxy-2-methylbutyrate)15-((-)-2-methylbut;4α,9-Epoxycevane-3β,4β,6α,7α,14,15α,16β,20-octol 6,7-diacetate 3-[(2R,3R)-2,3-dihydroxy-2-methylbutanoate]15-[(R)-2-methylbutanoate]
CBNumber:
CB0376499
Summenformel:
C41H63NO15
Molgewicht:
809.94
MOL-Datei:
124-97-0.mol

[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Eigenschaften

Schmelzpunkt:
268-270°C
alpha 
D25 -37° (pyridine); D25 -3.5° (chloroform)
Siedepunkt:
755.18°C (rough estimate)
Dichte
1.1826 (rough estimate)
Brechungsindex
1.6220 (estimate)
storage temp. 
2-8°C
Löslichkeit
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Aggregatzustand
Powder
pka
10.73±0.70(Predicted)

Sicherheit

S-Sätze: 22-24/25
RIDADR  1544
WGK Germany  3
RTECS-Nr. FL5750000
HazardClass  6.1(a)
PackingGroup  II
Toxizität LD50 s.c. in male mice: 0.21 mg/kg (Tanaka)

[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Chemische Eigenschaften,Einsatz,Produktion Methoden

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Beschreibung

Also present in Veratrum album, this closely allied alkaloid may be separated from the preceding base by chromatography. It also yields colourless crystals from EtOH and is laevorotatory with [α]29D&o - 39.8° (pyridine) or - 3.5° (CHCI3). In this case, alkaline hydrolysis gives protoverine, two moles of acetic acid, one mole of (-)-2-methylbutyric acid and one mole of 2: 3-dihydroxy-2- methylbutyric acid. It may be distinguished from protoveratrine A by giving a green colour with H2S04. It also forms a complex with maleic acid having m.p. 222.2°C; [α]29D&o - 27.3°.

Einzelnachweise

Stoll, Seebeck., Helv. Chim. Acta., 36,718 (1953)

[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 21)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-173 9270 1263
1057@dideu.com China 3961 58
Shaanxi Dideu New Materials Co. Ltd
18192503167
1036@dideu.com China 13264 58
DAYANG CHEM (HANGZHOU) CO.,LTD
+86-88938639 +86-17705817739
info@dycnchem.com China 53799 58
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109
market03@meryer.com China 40202 62
Shaanxi Dideu Medichem Co. Ltd 029-81024372 17792795018
1053@dideu.com China 10000 58
Chengdu Peter-like Biotechnology Co., Ltd. 028-81700200 13308200041
2851167782@qq.com China 10763 58
Shanghai meikai technology co., ltd 021-68689288 15300790979
info@mkbio.com.cn China 9988 58

124-97-0([3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat))Verwandte Suche:


  • [3beta(2R,3R),4alpha,6alpha,7alpha,15alpha(R),16beta]-4,9-epoxycevane-3,4,6,7,14,15,16,20-octol 6,7-diacetate 3-(2,3-dihydroxy-2-methylbutyrate) 15-(2-methylbutyrate)
  • PROTOVERATRINE B (RG)
  • PROTOVERATRINE B
  • NEOPROTOVERATRINE
  • 4-beta,6-alpha,7-alpha,14,15-alpha-16-beta,20-octol,4,9-epoxy-cevane-3-bet
  • 4α,9-Epoxycevane-3β,4β,6α,7α,14,15α,16β,20-octol 6,7-diacetate 3-[(2R,3R)-2,3-dihydroxy-2-methylbutanoate]15-[(R)-2-methylbutanoate]
  • PROTOVERATRINE A (RG)(CALL)
  • 6,7-diacetate3-(threo-(+)-2,3-dihydroxy-2-methylbutyrate)15-((-)-2-methylbut
  • neoprotoveratrin
  • veratetrin
  • yrate)
  • Cevane-3,4,6,7,14,15,16,20-octol, 4,9-epoxy-, 6,7-diacetate 3-[(2R,3R)-2,3-dihydroxy-2-methylbutanoate] 15-[(2R)-2-methylbutanoate], (3β,4α,6α,7α,15α,16β)-
  • 124-97-0
  • C41H63NO15
  • Miscellaneous Natural Products
Copyright 2019 © ChemicalBook. All rights reserved