(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
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- CAS-Nr.
- 150529-93-4
- Englisch Name:
- (R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
- Synonyma:
- (4R,4'R)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole);(R,R)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE);(R,R)-PhBOX;(R)-PheBox;2,2-Bis[(4R)-4-phenyl-2-oxazolin-2-yl]propane;(R,R)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE;(+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazo;(+)-2,2'-isopropylbis[(4R)-4-phenyl-2-azoleline];(+)-2,2’-Isopropylidenebis[(R)-4-phenyl-2-oxazoline;(R)-(+)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE)
- CBNumber:
- CB0756813
- Summenformel:
- C21H22N2O2
- Molgewicht:
- 334.41
- MOL-Datei:
- 150529-93-4.mol
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(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Eigenschaften
- Schmelzpunkt:
- 56-58 °C(lit.)
- Siedepunkt:
- 468.9±45.0 °C(Predicted)
- Dichte
- 1.18±0.1 g/cm3(Predicted)
- Brechungsindex
- 160 ° (C=1, EtOH)
- storage temp.
- -20°C
- pka
- 4.85±0.70(Predicted)
- Aggregatzustand
- clear liquid
- Farbe
- Light yellow to Amber to Dark green
- Optische Rotation
- [α]20/D +160°, c = 1 in ethanol
- BRN
- 4266906
- InChI
- 1S/C21H22N2O2/c1-21(2,19-22-17(13-24-19)15-9-5-3-6-10-15)20-23-18(14-25-20)16-11-7-4-8-12-16/h3-12,17-18H,13-14H2,1-2H3/t17-,18-/m0/s1
- InChIKey
- JTNVCJCSECAMLD-ROUUACIJSA-N
- SMILES
- CC(C)(C1=N[C@@H](CO1)c2ccccc2)C3=N[C@@H](CO3)c4ccccc4
- CAS Datenbank
- 150529-93-4
Sicherheit
| Kennzeichnung gefährlicher |
T |
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| R-Sätze: |
23/24/25 |
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| S-Sätze: |
26-36-45 |
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| RIDADR |
UN 2811 6.1/PG 3 |
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| WGK Germany |
3 |
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| HS Code |
29349990 |
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| Speicherklasse |
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects |
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| Hazard Classifications |
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral |
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(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Low melting solid or liquid
Verwenden
(+)-2,2′-Isopropylidenebis[(4
R)-4-phenyl-2-oxazoline] in the presence of copper iodide, can catalyze the asymmetric cyclopropanation reaction of phenyliodonium ylides with alkenes to form cyclopropane α-amino acid esters.
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 145)Lieferanten
150529-93-4()Verwandte Suche:
- (R)-(+)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE)
- (R,R)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE
- (R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
- (R,R)-2,2μ-Isopropylidenebis(4-phenyl-2-oxazoline), (R,R)-2,2μ-Bis(4-phenyl-2-oxazolin-2-yl)propane
- (+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazoline]
- (+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazo
- (R,R)-2,2'-(Dimethylmethylene)Bis(4-Phenyl-2-Oxazoline),96%
- (R,R)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane
(R,R)-2,2'-(Dimethylmethylene)bis(4-phenyl-2-oxazoline)
- ( -2,2'-(Dimethylmethylene)Bis(4-Phenyl-2-Oxazoline),96%
- 2,2-Bis[(4R)-4-phenyl-2-oxazolin-2-yl]propane
- 2-[2-(4,5-dihydrooxazol-2-yl)propan-2-yl]-4-phenyl-4,5-dihydrooxazole
- (4R)-2-[1-methyl-1-[(4R)-4-phenyl-4,5-dihydrooxazol-2-yl]ethyl]-4-phenyl-4,5-dihydrooxazole
- (R)-PheBox
- (R,R)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline)>
- Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4R,4'R)-
- ( )-2,2'-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline]
- (+)-2,2’-Isopropylidenebis[(R)-4-phenyl-2-oxazoline
- (+)-2,2''-isopropylidenebis[(4r)-4-phenyl-2-oxazoline
- (+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline]
- (+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline], CAS 150529-93-4
- (+)-2,2''-isopropylidenebis[(4r)-4-phenyl-2-oxazoline
- (+)-2,2'-isopropylbis[(4R)-4-phenyl-2-azoleline]
- (4R,4'R)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole)
- (R,R)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE)
- (R,R)-PhBOX
- 150529-93-4
- Asymmetric Synthesis
- Chiral Catalysts, Ligands, and Reagents
- BOX
- Privileged Ligands
- Chiral Nitrogen
- BOX series
- Asymmetric Synthesis
- Synthetic Organic Chemistry
