Diniconazole
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- CAS-Nr.
- 83657-24-3
- Englisch Name:
- Diniconazole
- Synonyma:
- DINICONAZOL;enazole;DINIT;XF 779;ACIDAN;sumi-8;ALYANS;s-3308l;xe-779l;DINIZOL
- CBNumber:
- CB1105036
- Summenformel:
- C15H17Cl2N3O
- Molgewicht:
- 326.22
- MOL-Datei:
- 83657-24-3.mol
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Diniconazole Eigenschaften
- Schmelzpunkt:
- 134~156℃
- Siedepunkt:
- 501.1±60.0 °C(Predicted)
- Dichte
- 1.32
- Dampfdruck
- 2.93 x l0-3 Pa (20 °C)
- storage temp.
- Inert atmosphere,Room Temperature
- Löslichkeit
- DMSO:100.0(Max Conc. mg/mL);306.54(Max Conc. mM)
Water:0.67(Max Conc. mg/mL);2.05(Max Conc. mM)
- Aggregatzustand
- A solid
- Wasserlöslichkeit
- 4 mg l-1 (25 °C)
- pka
- 12.89±0.20(Predicted)
- Farbe
- White to off-white
- Henry's Law Constant
- 2.5×101 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
- InChI
- 1S/C15H17Cl2N3O/c1-15(2,3)14(21)13(20-9-18-8-19-20)6-10-4-5-11(16)7-12(10)17/h4-9,14,21H,1-3H3/b13-6+
- InChIKey
- FBOUIAKEJMZPQG-AWNIVKPZSA-N
- SMILES
- OC(C(C)(C)C)/C(N1N=CC=C1)=C\C2=CC=C(Cl)C=C2Cl
- CAS Datenbank
- 83657-24-3(CAS DataBase Reference)
- EPA chemische Informationen
- 1H-1,2,4-Triazole-1-ethanol, .beta.-[(2,4-dichlorophenyl)methylene]-.alpha.-(1,1-dimethylethyl)-, (.beta.E)- (83657-24-3)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| WGK Germany |
WGK 1 |
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| Speicherklasse |
11 - Combustible Solids |
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| Hazard Classifications |
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1 |
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| Toxizität |
LD50 in male, female rats (mg/kg): 639, 474 orally; >5000, >5000 dermally (Takano) |
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| Bildanzeige (GHS) |
 
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
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P264, P270, P301+P312, P330, P501 |
| H410 |
Sehr giftig für Wasserorganismen mit langfristiger Wirkung. |
Langfristig (chronisch) gewässergefährdend |
Kategorie 1 |
Warnung |
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P273, P391, P501 |
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| Sicherheit |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P270 |
Bei Gebrauch nicht essen, trinken oder rauchen. |
| P273 |
Freisetzung in die Umwelt vermeiden. |
| P301+P312 |
BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
| P391 |
Verschüttete Mengen aufnehmen. |
| P501 |
Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
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Diniconazole Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Diniconazole is used to control leaf and ear diseases in cereals,
powdery mildew in vines, rust and black spot in roses, leaf spot in peanuts,
Sigatoka disease in bananas, and Uredinales in coffee. It is also used
on fruit, vegetables and ornamentals.
Stoffwechselwegen
Diniconazole is a mixture of four isomers, which are derived from a
chiral carbon atom and a double bond in the molecule. Diniconazole M
[( E)-( S)-1-(2 ,4-dichlorophenyl)-4,4-dimethyl-2-1(H -1,2,4-triazol-l-yl)pent-
1-en-3-ol] is more potent than diniconazole. The major metabolic pathways
of diniconazole involve oxidative attack on the pentenol side chain
to give products which may form conjugates. In mammals, sulfurcontaining
metabolites may be formed.
Degradation
Diniconazole is stable to heat, light and moisture. It undergoes photolysis
and irradiation of a solution in methanol with light from a high-pressure
mercury lamp for 8 hours gave three major and seven minor products, 2-
11 (Scheme 1). The major photoproduct was identified as the 2-isomer (2).
The other major products (5 and 6) were formed by photooxidation of the
CHOH group to a carbonyl group.
When diniconazole was irradiated as a thin film under ultraviolet light
(254 nm), the major product was identified as the Z-isomer. On the surface
of a sandy loam soil, under the same irradiation conditions rapid degradation
occurred with the formation of 2, 5 and 6. A thin film of diniconazole
applied to a glass plate degraded very slowly in the dark. When the
plate was placed in the sunhght, 70% of the applied material disappeared
after 5 days exposure and isomerisation occurred to give the Z-isomer
(65%). The DT
50 in sunlight was 2.5 days. Under ultraviolet light (254 mn),
the Z-isomer was formed after 15 minutes irradiation, and after 5 hours
90% of the material had isomerised (Dureja and Walia, 1992).
Diniconazole Upstream-Materialien And Downstream Produkte
Upstream-Materialien
1-Chlor-3,3-dimethylbutan-2-on
Hydrazinium hydroxide solution
olefine ketone
Kaliumcarbonat
3-Amino-5-mercapto-1,2,4-triazole
Kaliumtetrahydroborat
3,3-Dimethyl-1-(1,2,4-triazole-1-yl)-2-butanone
2,4-Dichlorbenzaldehyd
1H-1,2,4-Triazole-1-ethanol, beta-((4-chlorophenyl)methylene)-alpha-(1 ,1-dimethylethyl)-, (Z)-
Diethylether
Downstream Produkte
Diniconazole Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 248)Lieferanten
83657-24-3()Verwandte Suche:
- MITAZOLE
- SPOTLESS
- (e)-(+-)-imethylethyl)
- 1h-1,2,4-triazole-1-ethanol,beta-((2,4-dichlorophenyl)methylene)-alpha-(1,1-d
- diniconazole(stereochemistryunspecified)
- DINICONAZOLE
- DINIT
- DINICONAZOL MIXTURE OF Z AND E ISOMERS, PESTANAL, 250 MG
- DINIXONAZOLE
- diniconazole (ansi,bsi, draft-iso)
- E-(R,S)-1-(2,4-Dichlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol
- iniconazole(stereochemistryunspecified)
- Sumi-eight
- XF 779
- (SSE)-SS-[(2,4-DICHLOROPHENYL)METHYLENE]-A-(1,1-DIMETHYLETHYL)-1H-1,2,4-TRIAZOLE-1-ETHANOL
- 1-(2,4-Dichlorophenyl)-4,4-diMethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol
- Diniconazole 0
- RAC-DINICONAZOLE
- ACIDAN
- orthospotless
- s-3308-10
- s-3308l
- sumi-8
- xe-779l
- (e)-1-(2,4,-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazole-1-yl)1-pentenyl-3-ol
- DINIZOL
- ALYANS
- DiniconazoleSolution,10mg/L,1ml
- DiniconazoleSolution,100mg/L,1ml
- Diniconazol @100 μg/mL in AcCN
- Diniconazol@1000 μg/mL in Acetone
- Diniconazol Standard
- 83657-24-3 Difenoconazole Fungicide for Orchids , Lawn , Seedlings , Grapes
- 1H-1,2,4-Triazole-1-ethanol, β-[(2,4-dichlorophenyl)methylene]-α-(1,1-dimethylethyl)-, (βE)-
- (E)-Diniconazole
- TIANFU-CHEM Diniconazole 83657-24-3
- (E)-1-(2,4-Dichlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol
- Diniconazole in Methanol
- Diniconazole in Cyclohexane
- C12777000 Diniconazole
- L12777000IO DiniconazolE10μg/mLin Isooctane
- Diniconazole, 10 mM in DMSO
- Diniconazole, CAS 83657-24-3
- Diniconazole 10 μg/mL in Isooctane
- Dinicozole
- 12.5%Diniconazole
- DINICONAZOL
- enazole
- 83657-24-3
- C15H17C12N3O
- C15H17Cl2N3O
- INSECTICIDE
