(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol

(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol Struktur
101203-31-0
CAS-Nr.
101203-31-0
Englisch Name:
(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol
Synonyma:
BIPHEN H2;-2,2′-dioL;(S) BIPHEN H2;(R) BIPHEN H2;rac-BIPHEN H2;(R)-(+)-BIPHEN H2;(S)-(-)-BIPHEN H2;-3,3′-di-tert-butyL;5,5′,6,6′-TetramethyL;Tetramethyldibutylbiphenyldiol,
CBNumber:
CB3494592
Summenformel:
C24H34O2
Molgewicht:
354.53
MOL-Datei:
101203-31-0.mol

(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol Eigenschaften

Schmelzpunkt:
170-174 °C
Siedepunkt:
420.8±45.0 °C(Predicted)
Dichte
1.012±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
10.95±0.50(Predicted)
Aggregatzustand
crystal
Farbe
white to off-white
InChI
1S/C24H34O2/c1-13-11-17(23(5,6)7)21(25)19(15(13)3)20-16(4)14(2)12-18(22(20)26)24(8,9)10/h11-12,25-26H,1-10H3
InChIKey
NMVVBVMYPLMIOU-UHFFFAOYSA-N
SMILES
Cc1cc(c(O)c(c1C)-c2c(C)c(C)cc(c2O)C(C)(C)C)C(C)(C)C

Sicherheit

R-Sätze: 36/37/38
S-Sätze: 26-36/37/39
WGK Germany  3
Speicherklasse 11 - Combustible Solids

(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Verwenden

  • Cocatalyst in titanium-catalyzed intermolecular hydroamination

Reactant in preparation of:
  • Sulfonate phenol ligands via sulfonylation
  • Catalysts for asymmetric olefin hydroamination/cyclization reactions
  • Single site catalyst precursors for catalysis of ring-opening reactions
  • Biphen-Mo complex used for catalysis of enantioselective ring-closing metathesis

(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 45)Lieferanten
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J & K SCIENTIFIC LTD. 18210857532 18210857532
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Alfa Aesar 400-6106006
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Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097
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Energy Chemical 400-0056266
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ShangHai D&B Biological Science and Technology Co.Ltd 400-008-9730,021-54359730 400-008-9730
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Sigma-Aldrich 021-61415566 800-8193336
orderCN@merckgroup.com China 51389 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980
1029026415@qq.com China 4501 58
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105
2881489226@qq.com China 89667 60

  • raceMic-5,5',6,6'-TetraMethyl-3,3'-di- t-butyl-1,1'-biphenyl-2,2'-diol rac-BIPHEN H2
  • 6-tert-butyl-2-(3-tert-butyl-2-hydroxy-5,6-dimethylphenyl)-3,4-dimethylphenol
  • 5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol 97%
  • 3,3'-Di-tert-butyl-5,5',6,6'-tetramethyl-[1,1'-biphenyl]-2,2'-diol
  • (S) BIPHEN H2
  • (S)-(-)-BIPHEN H2
  • (R) BIPHEN H2
  • (R)-(+)-BIPHEN H2
  • (S)-(-)-5,5',6,6'-TETRAMETHYL-3,3'-DI-T-BUTYL-1,1'-BIPHENYL-2,2'-DIOL
  • (S)-(-)-3,3'-DI-T-BUTYL-5,5',6,6'-TETRAMETHYL-1,1'-BIPHENYL-2,2'-DIOL
  • (R)-(+)-5,5',6,6'-TETRAMETHYL-3,3'-DI-T-BUTYL-1,1'-BIPHENYL-2,2'-DIOL
  • RACEMIC-5,5',6,6'-TETRAMETHYL-3,3'-DI-T-BUTYL-1,1'-BIPHENYL-2,2'-DIOL
  • (R)-(+)-5,5',6,6'-TETRAMETHYL-3,3'-DI-TERT-BUTYL-1,1'-BIPHENYL-2,2'-DIOL
  • RAC-3,3'-DI-T-BUTYL-5,5',6,6'-TETRAMETHYL-1,1'-BIPHENYL-2,2'-DIOL
  • BIPHEN H2
  • Tetramethyldibutylbiphenyldiol,
  • rac-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol, BIPHEN H2
  • RAC-5,5',6,6'-TETRAMETHYL-3,3'-DI-TER-B&
  • 5,5',6,6'-TETRAMETHYL-3,3'-DI-TERT-&
  • RACEMIC-5,5',6,6'-TETRAMETHYL-3,3'-DI-T-BUTYL-1,1'-BIPHENYL-2,2'-DIOL, 99% RAC-BIPHEN H2
  • rac-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol,99%BIPHENH2
  • (R)-(+)-5,5'',6,6''-TETRAMETHYL-3,3''-DI-T-BUTYL-1,1''-BIPHENYL-2,2''-DIOL (R) BIPHEN H2
  • (±)-3,3'-Di-tert-butyl-5,5',6,6'-tetramethylbiphenyl-2,2'-diol, 99%
  • 5,5′,6,6′-TetramethyL
  • -3,3′-di-tert-butyL
  • -2,2′-dioL
  • [1,1'-Biphenyl]-2,2'-diol, 3,3'-bis(1,1-dimethylethyl)-5,5',6,6'-tetramethyl-
  • rac-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol
  • 3,3'-Di-tert-butyl-5,5',6,6'-tetramethyl-[1,1'-biphenyl]-2,2'-diol[rac-BIPHEN H2]
  • rac-BIPHEN H2
  • 5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol
  • 5,5′,6,6′-Tetramethyl-3,3′-di-tert-butyl-1,1′-biphenyl-2,2′-diol
  • (+/-)-3,3-Di-Tert-Butyl-5,5,6,6-Tetramethylbiphenyl-2,2-Diol
  • rac-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol
  • 5,5′,6,6′-Tetramethyl-3,3′-di-tert-butyl-1,1′-biphenyl-2,2′-diol, CAS 101203-31-0
  • 3,3'-Di-tert-butyl-5,5',6,6'-tetramethylbiphenyl-2,2'-diol
  • (S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol
  • 101203-31-0
  • Chiral Catalysts, Ligands, and Reagents
  • Catalysis and Inorganic Chemistry
  • Asymmetric Synthesis
  • Other Ligands
  • Other Chiral Ligands
  • BIPHEN Series
  • Achiral Oxygen
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Other Ligands
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