(S)-p-Mentha-1,8-dien

(S)-(-)-LIMONENE Struktur
5989-54-8
CAS-Nr.
5989-54-8
Bezeichnung:
(S)-p-Mentha-1,8-dien
Englisch Name:
(S)-(-)-LIMONENE
Synonyma:
L-LIMONENE;(-)-Limonene;beta-limonene;(S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;(-)-Dipentene;(s)-(-)-p-mentha-8-diene;(-)-1,8-p-menthadiene,(S)-(-)-limonene;(S)-(-)-4-ISOPROPENYL-1-METHYL-1-CYCLOHEXENE;1-methyl-4-(1-methylethenyl)-,(S)-Cyclohexene;cyclohexene,1-methyl-4-(1-methylethenyl)-,(S)-
CBNumber:
CB5178359
Summenformel:
C10H16
Molgewicht:
136.23
MOL-Datei:
5989-54-8.mol

(S)-p-Mentha-1,8-dien Eigenschaften

Schmelzpunkt:
-74°C
Siedepunkt:
175-177 °C(lit.)
alpha 
-99.5 º (C=NEAT)
Dichte
0.844 g/mL at 25 °C(lit.)
Dampfdichte
4.7 (vs air)
Dampfdruck
<3 mm Hg ( 14.4 °C)
Brechungsindex
n20/D 1.471(lit.)
Flammpunkt:
119 °F
storage temp. 
Sealed in dry,Store in freezer, under -20°C
Löslichkeit
Chloroform (Sparingly), Ethanol (Slightly), Methanol (Slightly)
Aggregatzustand
Liquid
Farbe
Clear colorless to pale yellow
Geruch (Odor)
at 100.00 %. terpene pine herbal peppery
Geruchsart
terpenic
Biologische Quelle
synthetic
Optische Rotation
[α]20/D 94±4°, c = 10% in ethanol
Explosionsgrenze
0.7-6.1%(V)
Wasserlöslichkeit
Insoluble
Merck 
14,5493
BRN 
2323991
Henry's Law Constant
3.7×10-4 mol/(m3Pa) at 25℃, Schuhfried et al. (2015)
Stabilität:
Stable. Incompatible with strong oxidizing agents. Flammable.
Major Application
flavors and fragrances
InChI
1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m1/s1
InChIKey
XMGQYMWWDOXHJM-SNVBAGLBSA-N
SMILES
CC(=C)[C@H]1CCC(C)=CC1
LogP
4.38 at 37℃
CAS Datenbank
5989-54-8(CAS DataBase Reference)
NIST chemische Informationen
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-(5989-54-8)
EPA chemische Informationen
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)- (5989-54-8)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi,N
R-Sätze: 10-38-43-50/53
S-Sätze: 24-37-60-61
RIDADR  UN 2052 3/PG 3
WGK Germany  2
RTECS-Nr. OS8350000
8-10-23
TSCA  TSCA listed
HazardClass  3
PackingGroup  III
HS Code  29029090
Speicherklasse 3 - Flammable liquids
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Asp. Tox. 1
Flam. Liq. 3
Skin Irrit. 2
Skin Sens. 1B
Bildanzeige (GHS) Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H304 Kann bei Verschlucken und Eindringen in die Atemwege tödlich sein. Aspirationsgefahr Kategorie 1 Achtung
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H400 Sehr giftig für Wasserorganismen. Kurzfristig (akut) gewässergefährdend Kategorie 1 Warnung P273, P391, P501
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.

(S)-p-Mentha-1,8-dien Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R10:Entzündlich.
R38:Reizt die Haut.
R43:Sensibilisierung durch Hautkontakt möglich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

S-Sätze Betriebsanweisung:

S24:Berührung mit der Haut vermeiden.
S37:Geeignete Schutzhandschuhe tragen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Beschreibung

ι-Limonene has a pleasant, lemon-like odor free from camphora ceous and turpentine-like notes. The most important and wide spread terpene; it is known in the d- and ι- optically active forms and in the optically inactive dl-form (known as dipentene); it has been reported found in more than 300 essential oils in amounts ranging from 90 - 95% (lemon, orange, mandarin) to as low as 1% (palmarosa);1 the most widespread form is the d-limonene, followed by the racemic form, and then ι-limonene.

Chemische Eigenschaften

colourless liquid with lemon odour

Occurrence

It has been reported found in more than 300 essential oils in amounts ranging from 90 to 95% (lemon, orange, mandarin) to as low as 1% (palmarosa); the most widespread form is the d-limonene, followed by the racemic form and then l-limo nene. Also reported found in ginger, nutmeg, pepper, mace, hop oil, coriander seed, calamus, dill herb, caraway seed and rosemary.

Verwenden

(S)-(-)-Limonene is used to inhibit the proliferation of colon cancer cells. It is also used in artificial essential oils in order to produce (+)-carvone. It is an active component of turpentine. Further, it is used in flavorings, fragrances, and cosmetics. It finds application as a solvent and wetting agent. In addition to this it is used to produce resins.

synthetische

d-Limonene may be obtained by steam distillation of citrus peels and pulp resulting from the production of juice and cold pressed oils, or from deterpenation of citrus oils; it is sometimes redistilled.

Definition

ChEBI: An optically active form of limonene having (4S)-configuration.

Allgemeine Beschreibung

(S)-(-)-Limonene, a monoterpenoid compound, is mostly used in perfumery and in flavoring. On irradiation, it undergoes radiolysis, which leads to a reduction in the optical purity. (S)-(-)-Limonene also shows potent antimicrobial activity.

Kontakt-Allergie

Limonene is a racemic form of dand l-limonene. d-Limonene is contained in Citrus species such as citrus, orange, mandarin, and bergamot. l-Limonene is contained in Pinus pinea.

Sicherheitsprofil

A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

(S)-p-Mentha-1,8-dien Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(S)-p-Mentha-1,8-dien Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 302)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21533 55
SHANDONG ZHI SHANG CHEMICAL CO.LTD
0531-68652808 18953170293
sales@sdzschem.com China 2921 58
CONIER CHEM AND PHARMA LIMITED

sales@conier.com China 49906 58
Zhengzhou Alfa Chemical Co.,Ltd
+86-18530059196
sale04@alfachem.cn China 9636 58
Career Henan Chemica Co
+86-0371-86658258 +86-13203830695
laboratory@coreychem.com China 30203 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +86-189 4982 3763
sales@tnjchem.com China 34526 58
Changzhou Xuanming Pharmaceutical Technology Co., Ltd.
+86-519-85525359 +86-15995072465
sales@xuanmingchem.com China 912 58
Shanghai UCHEM Inc.
+86-18930848214 +86-021-56762820
sales@myuchem.com China 8898 58
Chemsigma International Co., Ltd.
+86-2558742998 +86-19951791336
info@chemsigma.com China 1824 58
Finetech Industry Limited
+86-27-8746-5837 +86-18627785180
info@finetechnology-ind.com China 9539 58

5989-54-8((S)-p-Mentha-1,8-dien)Verwandte Suche:


  • (-)-1,8-p-menthadiene,(S)-(-)-limonene
  • (S)-(-)-1-methyl-4-(1-methylethenyl)cyclohexene
  • (s)-(-)-p-mentha-1,8-diene
  • (s)-(-)-p-mentha-8-diene
  • (s)-1-methyl-4-(1-methylethenyl)cyclohexene
  • cyclohexene,1-methyl-4-(1-methylethenyl)-,(S)-
  • p-Mentha-1,8-diene, (S)-(-)-
  • p-mentha-1,8-diene,(S)-(-)-
  • (s)-cyclohexen
  • 1-methyl-4-(1-methylethenyl)-,(S)-Cyclohexene
  • LIMONENE, S-(-)-
  • L-P-MENTHA-1,8-DIENE
  • L-LIMONENE
  • (-)-CARVENE
  • S-(-)-CARVENE
  • (S)-(-)-LIMONENE
  • (S)-(-)-4-ISOPROPENYL-1-METHYL-1-CYCLOHEXENE
  • (S)-4-ISOPROPENYL-1-METHYL CYCLOHEXENE
  • Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)-
  • (4S)-1-methyl-4-prop-1-en-2-yl-cyclohexene
  • LIMONENE, S-(-)-(SG)
  • LIMONENER
  • LIMONEN TECHN.
  • Cyclohexene, 1-methyl-4-(1-methyle
  • LIMONENE P&F FCC (D-)
  • (S)-(-)-LIMONENE 95+% FCC
  • (S)-(-)-4-Isopropenyl-1-methylcyclohexene~(-)-p-Mentha-1,8-diene
  • S-(-)-LIMONENE WITH GC
  • L-LIMONENE, NATURAL
  • (-)-p-Mentha-1,8-diene, (-)-Carvene, (S)-4-Isopropenyl-1-methyl cyclohexene
  • (-)-Limonene
  • (-)-LiMonene, 92% 100ML
  • (S)-(-)-LIMONENE FOR SYNTHESIS
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  • (S)-p-Mentha-1,8-dien
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  • (-)-Limonene, 10 mM in DMSO
  • (S)-(?)-Limonene
  • (-)-Dipentene
  • (S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-1-ene
  • beta-limonene
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