N-Phenyl-bis(trifluoromethanesulfonimide)
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- CAS-Nr.
- 37595-74-7
- Englisch Name:
- N-Phenyl-bis(trifluoromethanesulfonimide)
- Synonyma:
- PHENYL TRIFLIMIDE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);phenyltrifluoromethanesulfonimide;trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
- CBNumber:
- CB5289550
- Summenformel:
- C8H5F6NO4S2
- Molgewicht:
- 357.25
- MOL-Datei:
- 37595-74-7.mol
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N-Phenyl-bis(trifluoromethanesulfonimide) Eigenschaften
- Schmelzpunkt:
- 100-102 °C(lit.)
- Siedepunkt:
- 305.3±52.0 °C(Predicted)
- Dichte
- 1.766±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- Löslichkeit
- Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
- pka
- -13.12±0.50(Predicted)
- Aggregatzustand
- Crystals or Crystalline Powder
- Farbe
- White or colorless
- Sensitive
- Moisture Sensitive
- BRN
- 1269141
- Stabilität:
- Moisture Sensitive
- InChI
- InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
- InChIKey
- DIOHEXPTUTVCNX-UHFFFAOYSA-N
- SMILES
- C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
- CAS Datenbank
- 37595-74-7(CAS DataBase Reference)
- NIST chemische Informationen
- N-phenyltrifluoromethanesulfonimide(37595-74-7)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Kennzeichnung gefährlicher |
Xi |
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| R-Sätze: |
36/37/38 |
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| S-Sätze: |
26-36 |
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| WGK Germany |
3 |
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| F |
21 |
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| TSCA |
No |
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| HazardClass |
IRRITANT |
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| HS Code |
29242100 |
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| Speicherklasse |
11 - Combustible Solids |
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| Hazard Classifications |
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
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P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
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P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P271 |
Nur im Freien oder in gut belüfteten Räumen verwenden. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P302+P352 |
BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
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N-Phenyl-bis(trifluoromethanesulfonimide) Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Beschreibung
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating
reagent as well as a transparent strong electron-withdrawing p-type
dopant in carbon nanotubes. It is also employed as a reactant for the
preparation of amphoteric alfa-boryl aldehydes. It plays an important
role in the enantioselective synthesis of the core ring skeleton of
leucosceptroids A-D and in steroselective sulfoxidation.
Chemische Eigenschaften
white to off-white crystalline powder
Synthese
Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).
N-Phenyl-bis(trifluoromethanesulfonimide) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
N-Phenyl-bis(trifluoromethanesulfonimide) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 525)Lieferanten
37595-74-7()Verwandte Suche:
- phenyltrifluoromethanesulfonimide
- N-PHENYLTRIFLUOROMETHANESULFONIMIDE
- N-PHENYLTRIFLUOROMETHANESULPHONIMIDE
- 1,1,1-TRIFLUORO-N-PHENYL-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE
- N-Phenylbis(trifluoromethanesulphonimide), Phenyl triflimide
- NSC 240874
- N-Phenyl bis trifluorosulphonamide
- N-Bis(trifluoromethylsulfonyl)aniline
- 1,1,1-trifluoro-N-(methylsulfonyl)methanesulfonamide
- N- phenyl-bis (trifluoromethanesulfonyl) imide
- N-Phenylbis(trifluoroMethanesulfoniMide), 97% 5GR
- N,N-Bis(trifluoromethylsulfonyl)aniline
Phenyl Triflimide
N-Phenyltrifluoromethanesulfonimide
- N,N-Bis(trifluoroMethylsufonyl)aniline
- N,N-Bis(trifluoroMethylsulfonyl)aniline SynonyMs N-Phenylbis(trifluoroMethanesulfon)iMide
- N-phenyldouble(threefluoro Methanesulfonic acidiMide
- N-Phenyl-bis(trifluoroMethanesulfoniMide) >=98.0% (HPLC)
- N-phenyl bis(trifluoromethanesulfonyl)amide
- N-PHENYLT
- N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
- N,N-Bis(trifluoromethylsulfonyl)aniline 37595-74-7
- N,N-Bis(trifluoromethanesulphonyl)aniline~Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide
- Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide
- N-PHENYL-BIS-(TRIFLUORMETHANSULFONIMID)
- N,N-BIS-(TRIFLUOROMETHANESULFONYL)ANILINE
- 1,1,1-Trifluoro-N-phenyl-N-(trifluoromethyl)sulphonylmethanesulphonamide
- n-phenylbis(trifluorometanesulfonimide)
- N-Phenyl-bis(trifluoromethyl)sulfonimide
- N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
- N-phenyl-bis(trifluoromethanesulfonamide)
- N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Phenyl triflimide, 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
- N-Phenyltrifluoromethanesulfonimide ,98%
- N-Phenyl-bis(trifluoromethanesulfonimide),1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Pheny
- N,N-Bis(trifluoromethylsulphonyl)aniline 98%
- N-Phenylbis(trifluoromethanesulfonyl)amine
- N-Phenylbis(trifluoromethylsulfonyl)amine
- N-Phenyl-N,N-bis(trifluoromethylsulfonyl)amine
- N-Phenylbis(trifluoromethanesulphonimide)97%
- N-Phenylbis(trifluoromethanesulfonimide),97%
- N-Phenylbis(trifluromethanesulphonimide)99%
- trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide
- -bis(trifL
- fonimide)
- N-Phenylbis(trifluoromethanesulfonimide)[TriflatingReagent]>
- Methanesulfonamide, 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]-
- 1,1,1-trifluoro-N-phenyl-N
- TIANFUCHEM--37595-74-7--N-Phenyl-bis(trifluoromethanesulfonimide) factory price
- Bis(trifluoromethylsulfonyl)aniline
- N- phenylbis (trifluoromethanesulfonyl) imine
- N-PHENYL-BIS(TRIFLUROMETHANSULPHONIMIDE)
- N-phenylbis (trifluoromesulfonimide)
- N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide
- N-Phenyl-bis(trifluoromethanesulfonimide)
- N-Phenylbis(trifluoromethylsulfonyl)imide
- PhNTf2
- N-phenyl bistrifluoromethane sulfonate, 97%min
- N,N-Bis(trifluoromethylsulphonyl)aniline
- N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE)
- N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE)
