1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
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- CAS-Nr.
- 29964-62-3
- Englisch Name:
- 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
- Synonyma:
- PdCl2(dppb);PDCI2(DPPB);Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II);[1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride;adium(II) DichL;[1,4-Bis(diphenyL;phosphino)butane]paL;Palladium(ii) chloride 1,4-b;[(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2;Bisdiphenylphosphinobutanepalladiumdichloride
- CBNumber:
- CB6185262
- Summenformel:
- C28H28P2.Cl2Pd
- Molgewicht:
- 603.8
- MOL-Datei:
- 29964-62-3.mol
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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Eigenschaften
- Schmelzpunkt:
- 285-305 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- Löslichkeit
- Soluble in ethanol, benzene, and ethereal solvents.
- Aggregatzustand
- Powder
- Farbe
- light-yellow
- InChI
- 1S/C28H28P2.2ClH.Pd/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;;;/h1-12,15-22H,13-14,23-24H2;2*1H;/q;;;+2/p-2
- InChIKey
- JQXJBXVWVPVTOO-UHFFFAOYSA-L
- SMILES
- P(C1=CC=CC=C1)(CCCCP(C1=CC=CC=C1)C1C=CC=CC=1)C1=CC=CC=C1.[Pd](Cl)Cl
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemische Eigenschaften,Einsatz,Produktion Methoden
S-Sätze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
yellow solid
Verwenden
Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.
synthetische
Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) (1,4-Bis(diphenylphosphino)butane-palladium(II) chloride) can be prepared conveniently in situ by mixing the bidentate phosphine ligand and
(PhCN)2PdCl2 in either benzene or chloroform.
[1] The preparation of (dppb)PdCl2 is also possible through the
reaction of PdCl2 with dppb in acetone, a process that slowly forms the catalyst as a white precipitate which
can be isolated in 51% yield.
[2] Preparation of the hydrate complex is possible via the reaction of Na2[PdCl4]
with dppb in a mixture of CH2Cl2 and water.
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 251)Lieferanten
29964-62-3()Verwandte Suche:
- Palladium(ii) chloride 1,4-b
- 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%
- Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex
- Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
- 1,4-Butylenebis(diphenylphosphine)-palladium dichloride
- Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%
- 4-Bis(diphenylphosphino)butane-palladiuM(II) chloride
- 1,4- double(twophenyl phosphinebutane)twopalladiuM chloride
- [(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2
- 1,4-bis (diphenylphosphino butane) palladiuM dichloride
- 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II)
- [1,4-Bis(diphenylphosphino) butane]dichloropalladium(II)
- PdCl2(dppb) / dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
- 4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
- dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
- DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II)
- 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II) CHLORIDE
- 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE-PALLADIUM(II) CHLORIDE
- [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II) DICHLORIDE
- PALLADIUM(II) CHLORIDE 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE COMPLEX
- Bisdiphenylphosphinobutanepalladiumdichloride
- PDCL2(DPPB)/ 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II)CHLORIDE
- Palladium(II)chloride-1,4-bis(diphenylphosphine)butane
- Dichloro 1,4-bis(diphenylphosphino)butane palladium (II) For use in coupling reactions
- Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II),PdCl2(DPPB)
- [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride >
- [1,4-Bis(diphenylphosphino)butane]dichloropalladium(Ⅱ)
- [1,4-bis(diphenylphosphino)butane] palladium(II)
- [1,4-Bis(diphenyL
- adium(II) DichL
- phosphino)butane]paL
- 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride ISO 9001：2015 REACH
- TIANFU-CHEM --1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
- ichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
- 1,4-bis(diphenylphosphinobutane)dichloropaladium
- (SP-4-2)-[1,1′-(1,4-Butanediyl)bis[1,1-diphenylphosphine-κP]]dichloropalladium
- [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride
- Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)
- PDCI2(DPPB)
- PdCl2(dppb)
- 29964-62-3
- C28H28Cl2P2Pd
- C28H28Cl2P2Pd2
- C28H28P2Cl2Pd
- Homogeneous Pd Catalysts
- Catalysis and Inorganic Chemistry
- Homogeneous Catalysts
- Pd (Palladium) Compounds
- Metal Complexes
- Classes of Metal Compounds
- Catalysts for Organic Synthesis
- Transition Metal Compounds
- Pd (Palladium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
