exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol

DL-Isoborneol Struktur
124-76-5
CAS-Nr.
124-76-5
Bezeichnung:
exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol
Englisch Name:
DL-Isoborneol
Synonyma:
ISOBORNEOL;1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol;Borneolum;exo-Borneol;( )-borneol;Isobornyl alcohol;FEMA 2158;dl-isoborneo;(+/-)-Isoborneol;rel-(1R,2R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol
CBNumber:
CB6376754
Summenformel:
C10H18O
Molgewicht:
154.25
MOL-Datei:
124-76-5.mol

exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol Eigenschaften

Schmelzpunkt:
212-214 °C (subl.)(lit.)
Siedepunkt:
214°C
Dichte
0.8389 (rough estimate)
Dampfdruck
0.057-4.706Pa at 25℃
Brechungsindex
1.4710 (estimate)
FEMA 
2158 | ISOBORNEOL
Flammpunkt:
200 °F
storage temp. 
2-8°C
Löslichkeit
almost transparency in Methanol
Aggregatzustand
Powder
pka
15.36±0.60(Predicted)
Farbe
Yellow
Geruch (Odor)
at 10.00 % in dipropylene glycol. balsam camphor herbal woody
Geruchsart
balsamic
Biologische Quelle
synthetic
Wasserlöslichkeit
insoluble
Merck 
14,5128
JECFA Number
1386
BRN 
4126091
Kosmetik-Inhaltsstoffe Funktionen
PERFUMING
InChI
1S/C10H18O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7-8,11H,4-6H2,1-3H3/t7-,8-,10+/m1/s1
InChIKey
DTGKSKDOIYIVQL-MRTMQBJTSA-N
SMILES
[H][C@@]12CC[C@@](C)([C@H](O)C1)C2(C)C
LogP
2.32-2.92 at 20-25℃
CAS Datenbank
124-76-5(CAS DataBase Reference)
NIST chemische Informationen
DL-Isoborneol(124-76-5)
EPA chemische Informationen
Isoborneol (124-76-5)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher F,Xi
R-Sätze: 11-38
S-Sätze: 24/25
RIDADR  UN 1312 4.1/PG 3
WGK Germany  2
RTECS-Nr. NP7300000
TSCA  TSCA listed
HazardClass  4.1
HS Code  29061900
Speicherklasse 4.1B - Flammable solid hazardous materials
Hazard Classifications Flam. Sol. 1
Skin Irrit. 2
Giftige Stoffe Daten 124-76-5(Hazardous Substances Data)
Toxizität mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03209,
Bildanzeige (GHS) Flame (GHS02)Exclamation Mark (GHS07)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H228 Entzündbarer Feststoff. Entzündbare Feststoffe Kategorie 1 Achtung
Warnung
P210, P240,P241, P280, P370+P378
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.

exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R11:Leichtentzündlich.
R38:Reizt die Haut.

S-Sätze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.

Beschreibung

Isoborneol has a piney, camphoraceous odor. May be prepared by the hydrolysis of isobomyl acetate, or by catalytic reduction of camphor (both d- and ι-isomers); the optically inactive compound can be prepared by treating camphene with a 1:1 mixture of sulfuric acid and glacial acetic acid and then hydrolyzing the isobomyl acetat.

Chemische Eigenschaften

white to almost white crystalline powder

Occurrence

Reported found in the oil of Abies sibirica and a few other essences and in the essential oil from roots of Chamaeciparis formosensis. Also reported found in apple, papaya, blackberry, cinnamomum, ginger, thymus, cheeses, cognac, Ocimum basilicum, rosemary, temoe lawak (Curcuma xanthorriza Roxb.) turmeric, sage, clary sage, ashanti pepper, German chamomile oil, eucalyptus oil and mastic gum leaf oil

Verwenden

Isoborneol is a monoterpene and a component of several plant essential oils, showed dual viricidal activity against herpes simplex virus 1 (HSV-1).

synthetische

By the hydrolysis of isobornyl acetate, or by catalytic reduction of camphor (both d- and l-isomers); the optically inactive compound can by prepared by treating camphene with a 1:1 mixture of sulfuric acid and glacial acetic acid and then hydrolyzing the isobornyl acetate

Definition

A geometrical isomer of borneol.

Allgemeine Beschreibung

Isoborneol is a monoterpene and a known antioxidant, which is a component of several plant essential oils.

läuterung methode

Crystallise isoborneol from EtOH or pet ether (b 60-80o). It sublimes in a vacuum. The 4-nitrobenzoyl derivative has m 153o. [Yager & Morgan J Am Chem Soc 57 2081 1935, Beilstein 6 II 80, 6 III 299, 6 IV 281.]

exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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124-76-5(exo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol)Verwandte Suche:


  • Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,(1R,2R,4R)-rel-
  • Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,1R,2R,4R-rel-
  • Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,exo-
  • bicyclo{2.2.1}heptan-2-ol,1,7,7-trimethyl-,exo-
  • exo-1,7,7-trimethylbicyclo(2.2.1)heptan-2
  • exo-1,7,7-Trimethylbicyclo(2.2.1)heptan-2-ol
  • exo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol
  • exo-2-Bornanol
  • exo-2-Hydroxy-1,7,7-trimethylnorbornane
  • Exoborneol
  • exo-Borneol
  • Isoborneol, DL-
  • Isobornyl alcohol
  • isobornylalcohol
  • Isocamphol
  • DL-Isoborneol, 93%, tech
  • rel-(1S*,4S*)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2β*-ol
  • DL-Isoborneol, tech., 93% 500GR
  • Isoborneol 95%
  • BORNEOL(ISO)
  • EXO-2-CAMPHANOL
  • EXO-1,7,7-TRIMETHYLBICYCLO(2.2.1)-2-HEPTANOL
  • DL-ISOBORNEOL
  • DL-ISOBORNYL ALCOHOL
  • DL-ISOCAMPHAL
  • 1,7,7-Trimethyl-bicyclo[2.2.1]heptan-2-ol (isoborneol)
  • 1,7,7-trimethyl-exo-Bicyclo[2.2.1]heptan-2-ol
  • Trimethylbicycloheptanol
  • ISOBORNEOL 95+%
  • ISOBORNEOL(SG)
  • 2-exo-Borneol
  • 2-exo-Bornylalcohol
  • 7,7-trimethyl-exo-bicyclo(2.2.1)heptan-2-o
  • 7,7-trimethyl-exo-bicyclo[2.2.1]heptan-2-o
  • Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, exo-
  • ISOBORNEOL SOLUTION
  • (+/-)-ISOBORNEOL WITH GC
  • DL-Isoborneol, tech., 93%
  • isoborneol,exo-1,7,7,-trimethyl-bicyclo[2.2.1]heptan-2-ol,iso-camphol
  • Isoborneol Isoborneol
  • (+/-)-Isoborneol>
  • dextro,laevo-isoborneol
  • ()-Isoborneol, 96%
  • 124-76-5 DL-Isoborneol
  • rel-(1R,2R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol
  • exo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol (exo-borneol)
  • (1S,2R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol
  • Isoborneol, 95% in isooctane
  • Isoborneol, 10 mM in DMSO
  • D-Camphor Impurity I
  • Fenchol Impurity 5
  • Isoborneol (Standard)
  • ( )-borneol
  • (+/-)-Isoborneol
  • 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol
  • Borneolum
  • dl-isoborneo
  • FEMA 2158
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