2,2-Dimethylbutan Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R11:Leichtentzündlich.
R38:Reizt die Haut.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R65:Gesundheitsschädlich: kann beim Verschlucken Lungenschäden verursachen.
R67:Dämpfe können Schläfrigkeit und Benommenheit verursachen.
S-Sätze Betriebsanweisung:
S9:Behälter an einem gut gelüfteten Ort aufbewahren.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S29:Nicht in die Kanalisation gelangen lassen.
S33:Maßnahmen gegen elektrostatische Aufladungen treffen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ärztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.
Chemische Eigenschaften
2,2-dimethylbutane is the chain isomeric form of hexane. It is a colorless and flammable liquid with a specific gravity of 0.6444. Insoluble in water, miscible with alcohol, ether, acetone, benzene and petroleum ether. The solubility is similar to that of hexane and 2-methylpentane.
Physikalische Eigenschaften
Clear, colorless liquid with a mild petroleum-like odor. Liquid quickly evaporates and forms
conbustible fumes. An odor threshold concentration of 20 ppm
v was reported by Nagata and
Takeuchi (1990).
Verwenden
2,2-Dimethylbutane is an acyclic alkane. Its Research Octane Number (RON) has been reported to be 91.8. It is used to Component of high-octane motor and aviation fuels, intermediate for agricultural chemicals.
Vorbereitung Methode
2,2-Dimethylbutane is produced from crude oil, natural
liquid gases, and petroleum refining processes.
synthetische
2,2-Dimethylbutane can be synthesised by the hydroisomerisation of 2,3-dimethylbutane using an acid catalyst.
By the thermal or catalytic union (alkylation) of ethylene and isobutane, both recovered from refinery gases.
Allgemeine Beschreibung
Colorless liquid with an odor of gasoline. Less dense than water and insoluble in water. Hence floats on water. Irritating vapor. Flash point -54°F.
Air & Water Reaktionen
Highly flammable. Insoluble in water.
Reaktivität anzeigen
2,2-Dimethylbutane may be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce carbon dioxide and water.
Hazard
Highly flammable, dangerous fire and
explosion risk, explosion limits 1.2–7%
Health Hazard
Inhalation causes dizziness, nausea, and vomiting; concentrated vapor may cause unconsciousness and collapse. Contact with liquid causes irritation of eyes; repeated contact may produce irritation of skin. Ingestion causes irritation of stomach. Aspiration causes severe lung irritation, rapidly developing pulmonary edema, and central nervous system excitement followed by depression.
Sicherheitsprofil
Probably an irritant and
narcotic in high concentration. A very
dangerous fire and explosion hazard when
exposed to heat or flame; can react
vigorously with oxidzing materials. Keep
away from heat or open flame. To fight fire,
use foam, CO2, dry chemical. When heated
to decomposition it emits acrid smoke and
irritating fumes.
Environmental Fate
Photolytic. Reported photooxidation rate constants for the reaction of 2,2-dimethylbutane with
OH radicals at 297, 299, and 300 K are 2.59 x 10
-12, 6.16 x 10
-12, and 2.59 x 10
-12
cm
3/moleculesec, respectively (Atkinson, 1985, 1990).
Chemical/Physical. Complete combustion in air yields carbon dioxide and water vapor. 2,2-
Dimethylbutane will not hydrolyze because it has no hydrolyzable functional group.
läuterung methode
Distil it azeotropically with MeOH, then wash it with water, dry (Na2SO4) it, and distil it. [Beilstein 1 IV 367.]
2,2-Dimethylbutan Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
