Oxadixyl
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- CAS-Nr.
- 77732-09-3
- Englisch Name:
- Oxadixyl
- Synonyma:
- ANCHOR;metoxazon;m10797;recoil;ripost;san371;san371f;OXADIXYL;SANDOFAN;ASN 371-F
- CBNumber:
- CB7367553
- Summenformel:
- C14H18N2O4
- Molgewicht:
- 278.3
- MOL-Datei:
- 77732-09-3.mol
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Oxadixyl Eigenschaften
- Schmelzpunkt:
- 104-105 °C
- Siedepunkt:
- 421.12°C (rough estimate)
- Dichte
- 1.1674 (rough estimate)
- Brechungsindex
- 1.5500 (estimate)
- Flammpunkt:
- >100 °C
- storage temp.
- 0-6°C
- pka
- 1.16±0.20(Predicted)
- Wasserlöslichkeit
- 3.4 mg/L at 25 ºC
- Merck
- 13,6976
- BRN
- 7098783
- Henry's Law Constant
- 2.0×106 mol/(m3Pa) at 25℃, Ebert et al. (2023)
- Major Application
- agriculture
environmental
- InChI
- 1S/C14H18N2O4/c1-10-5-4-6-11(2)13(10)16(12(17)9-19-3)15-7-8-20-14(15)18/h4-6H,7-9H2,1-3H3
- InChIKey
- UWVQIROCRJWDKL-UHFFFAOYSA-N
- SMILES
- COCC(=O)N(N1CCOC1=O)c2c(C)cccc2C
- LogP
- 0.800
- CAS Datenbank
- 77732-09-3(CAS DataBase Reference)
- NIST chemische Informationen
- Acetamide, n-(2,6-dimethylphenyl)-2-methoxy-n-(2-oxo-3-oxazolidinyl)-(77732-09-3)
- EPA chemische Informationen
- Oxadixyl (77732-09-3)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Kennzeichnung gefährlicher |
Xn |
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| R-Sätze: |
22 |
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| WGK Germany |
3 |
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| RTECS-Nr. |
AB8131400 |
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| Speicherklasse |
11 - Combustible Solids |
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| Hazard Classifications |
Acute Tox. 4 Oral |
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| Toxizität |
LD50 in female rats (mg/kg): 1860 orally; >2000 dermally (Gisi) |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
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P264, P270, P301+P312, P330, P501 |
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| Sicherheit |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P270 |
Bei Gebrauch nicht essen, trinken oder rauchen. |
| P501 |
Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
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Oxadixyl Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
Verwenden
Oxadixyl is a pesticide residue used for the detection of pesticides in vegetation.
Definition
ChEBI: An oxazolidinone that is N-(2,6-dimethylphenyl)-2-methoxyacetamide in which the amide hydrogen is replaced by a 2-oxo-1,3-oxazolidin-3-yl group. A systemic fungicide used to treat seeds of a variety of food crops, as well as lawns.
Synthese
2,6-Dimethylphenylhydrazine reacts with 2-chloroethyl chloroformate under low-temperature (0-10°C) alkaline conditions to generate N-(2-chloroethoxycarbonyl)-N'-(2,6-dimethylphenyl)hydrazine. Subsequently, this intermediate undergoes acylation with methoxyacetyl chloride in solvents such as toluene to generate a further substituted hydrazine intermediate. Finally, under the action of a strong base (such as sodium hydroxide or sodium hydride) and a phase transfer catalyst, an intramolecular condensation cyclization reaction occurs to form a 2-oxo-1,3-oxazolidine ring, yielding Oxadixyl.
Oxadixyl Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Oxadixyl Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 111)Lieferanten
77732-09-3()Verwandte Suche:
- 2-methoxy-n-(2-oxo-1,3-oxazolidine-3-yl)-acet-2,6-xylidine
- OXADIXYL
- metidaxyl
- oxadixyl anchor
- 2-methoxy-N-(2-oxo-1,3-oxazolidin-3-yl) acet-2',6'-xylidide
- METHYL-PENTACHLOROPHENYLSULFIDE PESTANA&
- Acetamide, N-(2,6-dimethylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)-
- oxadixyl (bsi,draft e-iso, draft f-iso)
- ASN 371-F
- N-(2-Methoxyacetyl)-N-(2,6-xylyl)-3-amino-1,3-oxazolidin-2-one
- N-(2,6-Dimethylphenyl)-2-methoxy-N-(2-oxooxazolidin-3-yl)acetamide
- 2-Methoxy-N-(2-oxo-1,3-oxazolidin-3-yl)acetamido-2',6'-xylidine
- Oxadixyl standard
- Ripost (TM)
- 2-Methoxy-N-(2-oxo-1,3-oxazolidine-3-yl)-acet-2,6-xylidine [french]
- Oxadixyl [bsi:iso]
- Oxadixyl 100mg [77732-09-3]
- Anchor (TM)
- SANDOFAN
- 77732-09-3)
- m10797
- n-(2,6-dimethylphenyl)-2-methoxy-n-(2-oxo-3-oxazolidinyl)-acetamid
- n-(2,6-dimethylphenyl)-2-methoxy-n-(2-oxo-3-oxazolidinyl)acetamide
- recoil
- ripost
- san371
- san371f
- Oxadixyl Solution, 1000ppm
- Oxadixyl@1000 μg/mL in Acetonitrile
- Oxadixyl @100 μg/mL in MeOH
- Oxadixyl Solution in Acetone, 1000μg/mL
- Sandofan 95%
- Oxadixyl 10 μg/ml Ethyl acetate
- Oxadixyl 10.0 μg/ml Acetonitrile
- Oxadixyl 100 μg/ml Ethyl acetate
- C15770000 Oxadixyl
- L15770000ALOxadixyL10μg/mLin Acetonitrile
- L15770000CY OxadixyL10μg/mLin Cyclohexane
- Oxadixyl 100 μg/mL in Acetone
- Oxadixyl 10 μg/mL in Acetonitrile
- Oxadixyl 10 μg/mL in Cyclohexane
- ANCHOR
- metoxazon
- 77732-09-3
- Alpha sort
- Alphabetic
- Amide structurePesticides&Metabolites
- Fungicides
- N-PAnalytical Standards
- OPesticides
- Oxazoles
- Pesticides
