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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Struktur
470480-32-1
CAS-Nr.
470480-32-1
Englisch Name:
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
Synonyma:
(S,S,R,R)-TANGPHOS;(S,S',R,R')-TANGPHOS;(S,S′,R,R′)-TangPhos;(1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE;(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE;(2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane;2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-;(1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS;(1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS
CBNumber:
CB9117701
Summenformel:
C16H32P2
Molgewicht:
286.37
MOL-Datei:
470480-32-1.mol
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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Eigenschaften

Schmelzpunkt:
60-65 °C
Siedepunkt:
353.6±12.0 °C(Predicted)
InChI
1S/C16H32P2/c1-15(2,3)17-11-7-9-13(17)14-10-8-12-18(14)16(4,5)6/h13-14H,7-12H2,1-6H3/t13-,14-,17+,18+/m1/s1
InChIKey
SJNUZTRUIDRSJK-KNCCTNLNSA-N
SMILES
CC(C)(C)P1CCC[C@@H]1[C@H]2CCCP2C(C)(C)C

Sicherheit

R-Sätze: 36/37/38
S-Sätze: 22-24/25
WGK Germany  3
Speicherklasse 13 - Non Combustible Solids

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Verwenden

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Catalytic ligand used in:
  • Preparation of α-borono-substituted alkylarenes by asymmetric hydroboration of styrenes catalyzed by copper(I)
  • Enantioselective synthesis of spiroindane di-Me acetic acid via hydrogenation of spiroindane di-Me acetic acid catalyzed by Ru(II)
  • Asymmetric γ-addition of thiols to allenoates
  • Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
  • Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 10)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806
 sales@capot.com China 29626 60
J & K SCIENTIFIC LTD. 18210857532 18210857532
 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109
 market03@meryer.com China 40202 62
Sigma-Aldrich 021-61415566 800-8193336
 orderCN@merckgroup.com China 51389 80
  • (S,S',R,R')-TANGPHOS
  • (S,S,R,R)-TANGPHOS
  • (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
  • (1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE
  • (1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS
  • (1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS
  • 2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-
  • (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane
  • (S,S′,R,R′)-TangPhos
  • 470480-32-1
  • C16H32P2
  • Privileged Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • ChiralQuest Ligands
  • Asymmetric Synthesis
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