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S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate

S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate Struktur
131880-16-5
CAS-Nr.
131880-16-5
Englisch Name:
S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate
Synonyma:
5-(TrifluoroMethyl)-5H-dibenzo[b,d]thiophen-5-iuM tetrafluoroborate;Umemoto's reagent;5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TETRAFLUOROBORATE;5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TE;S-(TrifluoroMethyl)dibenzothiopheniuM tetrafluorob;S-(trifluoromethyl) dibenzothiophenol tetrafluoroborate;S-(TRIFLUOROMETHYL)-DIBENZOTHIOPHENIUM TETRAFLUOROBORATE;S-(trifluoromethyl) dibenzothiophenohm tetrafluoroborate;S-(Trifluoromethyl)dibenzothiopheniumtetrafluoroborate98%;5-(TrifluoroMethyl)dibenzothiopheniuM tetrafluoroborate 97%
CBNumber:
CB9206124
Summenformel:
C13H8BF7S
Molgewicht:
340.07
MOL-Datei:
131880-16-5.mol
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S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate Eigenschaften

Schmelzpunkt:
171-172°C
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Aussehen
White to light yellow Solid
InChI
InChI=1S/C13H8F3S.BF4/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)5/h1-8H;/q+1;-1
InChIKey
VTVISWLINKWMQZ-UHFFFAOYSA-N
SMILES
[B+3]([F-])([F-])([F-])[F-].C([S+]1C2=CC=CC=C2C2C=CC=CC1=2)(F)(F)F
CAS Datenbank
131880-16-5(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
S-Sätze: 24/25
WGK Germany  3
HS Code  29349990
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

White to yellow solid

Verwenden

5-(Trifluoromethyl)dibenzothiophenium Tetrafluoroborate is used to synthesize ortho-trifluoromethylated and ortho-(fluoro)alkylated pyridine derivatives. It is used as a CF3 source under visible light irradiation for the photoredox-catalyzed trifluoromethylation of electron rich alkene resulting in 1,3-bis(trifluoromethyl)-1-propenyl skeleton.

S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 123)Lieferanten
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131880-16-5()Verwandte Suche:

2-Thiopheneboronic acid 3-(Dimethylamino)-7-(methylamino)phenothiazin-5-iumtetrafluoroborat 4,6-Dimethyldibenzothiophen Dibenzothiophen Trimethylsulfoniumtetrafluoroborat(1-) Methyldiphenylsulfoniumtetrafluoroborat(1-)
  • 5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TETRAFLUOROBORATE
  • S-(TRIFLUOROMETHYL)-DIBENZOTHIOPHENIUM TETRAFLUOROBORATE
  • 5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TE
  • S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate 98%
  • S-(Trifluoromethyl)dibenzothiopheniumtetrafluoroborate98%
  • Umemoto's reagent
  • S-(TrifluoroMethyl)dibenzothiopheniuM tetrafluorob
  • 5-(TrifluoroMethyl)dibenzothiopheniuM tetrafluoroborate
  • 5-(TrifluoroMethyl)-5H-dibenzo[b,d]thiophen-5-iuM tetrafluoroborate
  • 5-(TrifluoroMethyl)dibenzothiopheniuM tetrafluoroborate 97%
  • 5-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate, 97%, for synthesis
  • S-(trifluoromethyl) dibenzothiophenol tetrafluoroborate
  • S-(trifluoromethyl) dibenzothiophenohm tetrafluoroborate
  • Dibenzothiophenium, 5-(trifluoromethyl)-, tetrafluoroborate(1-) (1:1)
  • S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate ISO 9001：2015 REACH
  • 131880-16-5
  • BF4C13H8F3S
  • C13H8BF7S
  • C13H8F3SBF4
  • Heterocyclic Building Blocks
  • Benzothiophenes
  • Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Fluorination Reagents
  • Heterocyclic Building Blocks
  • Synthetic Reagents
  • Trifluoromethylation
  • API intermediates
  • Benzothiophenes
  • Building Blocks
  • Heterocyclic Building Blocks
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