ChemicalBook >> CAS DataBase List >>Trimethylene di(thiotosylate)
Trimethylene di(thiotosylate)
- CAS No.
- 3866-79-3
- Chemical Name:
- Trimethylene di(thiotosylate)
- Synonyms
- s,s'NSC 82472;1,3-DI(P-TOSYLTHIO)PROPANE;1,3-Propanedithiol ditosylate;Trimethylene di(thiotosylate);1,3-PROPANEDIYL DI(THIOTOSYLATE);1,3-Propanediylbis(tosyl sulfide);1,3-bis(p-toluenesulfonylthio)propane;Trimethylene di-p-toluenethiosulfonate;TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE)
- CBNumber:
- CB0100135
- Molecular Formula:
- C17H20O4S4
- Molecular Weight:
- 416.6
- MDL Number:
- MFCD00014918
- MOL File:
- 3866-79-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-09-12 18:28:28
| Melting point | 64-67 °C |
|---|---|
| Boiling point | 592.3±60.0 °C(Predicted) |
| Density | 1.340±0.06 g/cm3(Predicted) |
| form | powder to crystal |
| color | White to Almost white |
| BRN | 2020157 |
| InChI | 1S/C17H20O4S4/c1-14-4-8-16(9-5-14)24(18,19)22-12-3-13-23-25(20,21)17-10-6-15(2)7-11-17/h4-11H,3,12-13H2,1-2H3 |
| InChIKey | QOICHLMIPNOKLN-UHFFFAOYSA-N |
| SMILES | Cc1ccc(cc1)S(=O)(=O)SCCCSS(=O)(=O)c2ccc(C)cc2 |
| CAS DataBase Reference | 3866-79-3 |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| PPE | Eyeshields, Gloves, type N95 (US) |
| Safety Statements | 22-24/25 |
| WGK Germany | 3 |
| HS Code | 2930.90.2900 |
| Storage Class | 11 - Combustible Solids |
Trimethylene di(thiotosylate) price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | D2390 | Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] >95.0%(HPLC) | 3866-79-3 | 5g | $80 | 2026-04-30 | Buy |
| TCI Chemical | D2390 | Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] >95.0%(HPLC) | 3866-79-3 | 25g | $241 | 2026-04-30 | Buy |
| Usbiological | 291737 | Trimethylene Di(thiotosylate) Asreported | 3866-79-3 | 5g | $315 | 2026-06-03 | Buy |
| Usbiological | 291737 | Trimethylene Di(thiotosylate) Asreported | 3866-79-3 | 10g | $433 | 2026-06-03 | Buy |
| Usbiological | 291737 | Trimethylene Di(thiotosylate) Asreported | 3866-79-3 | 25g | $618 | 2026-06-03 | Buy |
Trimethylene di(thiotosylate) Chemical Properties,Uses,Production
Uses
Trimethylene Di(thiotosylate) is used as a reactant in the enantioselective total synthesis of (-)-O-methylpallidinine, which is a naturally occurring morphinan alkaloid.
Reactions
1,3-Propanedithiol Bis(p-toluenesulfonate) could be used in the below reactions:
dithianylation and dithiolanylation of methylene groups adjacent to carbonyl; α,α-dithianyl cycloalkanones undergo oxidative ring scission; oxidation of ketones to 1,2-diketones can be achieved by α,α-dithianylation or dithiolanation of ketones followed by hydrolysis.
Synthesis
Treatment of potassium thiotosylate, itself made by the reaction of p-Toluenesulfonyl Chloride with Potassium Hydrogen Sulfide, with 1,3-dibromopropane or 1,2-dibromoethane in the presence of Potassium Iodide affords 1,3-propanedithiol bis(p-toluenesulfonate) and 1,2-ethanedithiol bis(p-toluenesulfonate), respectively.
Trimethylene di(thiotosylate) Preparation Products And Raw materials
Raw materials
Preparation Products
Trimethylene di(thiotosylate) Suppliers
Global( 68)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 18930552037 | 3bsc@sina.com | China | 15813 | 69 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| Shanghai civi chemical technology co.,Ltd | 86-21-34053660 | sale@labgogo.com | China | 9853 | 52 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
| TCI Europe | 320-37350700 | sales@tcieurope.eu | Europe | 23654 | 75 |
View Lastest Price from Trimethylene di(thiotosylate) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-03-20 | TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
|
1KG | 99% | 20 mt | Hebei Chuanghai Biotechnology Co., Ltd | ||
 |
2024-08-14 | TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
|
$1.00 | 1KG | 99% | 20T | Shaanxi Dideu Medichem Co. Ltd | |
![Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] pictures](/ProductImageEN/2021-06/Small/dd53fa51-0d83-4baf-81a0-89bb7f7fc1a7.jpg) |
2021-07-02 | Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]
3866-79-3
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-
- Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]
3866-79-3
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
3866-79-3(Trimethylene di(thiotosylate))Related Search:
1,3-DI(P-TOSYLTHIO)PROPANE
1,3-PROPANEDIYL DI(THIOTOSYLATE)
TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE)
Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]
S,S'-Trimethylene di(p-toluenethiosulfonate)
Benzenesulfonothioic acid, 4-methyl-, S,S-1,3-propanediyl ester
1,3-Di(p-tosylthio)propane, 1,3-Propanediyl di(thiotosylate), Trimethylene di(thiotosylate)
1,3-Propanedithiolebis(p-toluenesulfonate)
1,3-Propanediylbis(tosyl sulfide)
p-Toluenesulfonothioic acid S-[3-[(4-methylphenyl)sulfonylthio]propyl] ester
NSC 82472
Trimethylene di-p-toluenethiosulfonate
Benzenesulfonothioicacid, 4-methyl-, S1,S1'-1,3-propanediyl ester
1,3-Di(p-tosylthio)propane
1,3-Propanediyl Di(thiotosylate)
Trimethylene Bis(p-toluenethiosulfonate)
1-methyl-4-[3-(4-methylphenyl)sulfonylsulfanylpropylsulfanylsulfonyl]benzene
1-methyl-4-[3-[(4-methylphenyl)sulfonylthio]propylthio]sulfonyl-benzene
1,3-Bis(4-methylbenzenesulfonylthio)propane
1,3-Propanedithiol ditosylate
4-Methylbenzenesulfonothioic acid S1,S1'-1,3-propanediyl ester
1,3-bis(p-toluenesulfonylthio)propane
TrimethyleneDi(thiotosylate)[ProtectingReagentforActiveMethylene]>
S,S′-Trimethylene di(p-toluenethiosulfonate)
s,s'
S,S′-Trimethylene di(p-toluenethiosulfonate), CAS 3866-79-3
Trimethylene di(thiotosylate)
3866-79-3
CH3C6H4SO2SCH2CH2CH2SSO2C6H4CH3
C17H20O4S4
Protection & Derivatization Reagents (for Synthesis)
Sulfur Compounds (for Synthesis)
Building Blocks
Organic Building Blocks
Sulfur Compounds
Tosylates
Building Blocks
Chemical Synthesis
Organic Building Blocks
Sulfur Compounds
Tosylates
Synthetic Organic Chemistry
Protection & Derivatization Reagents (for Synthesis)
Sulfur Compounds (for Synthesis)
blocks
BuildingBlocks
