TRIBUTYLSTANNYLACETYLENE
- CAS No.
- 994-89-8
- Chemical Name:
- TRIBUTYLSTANNYLACETYLENE
- Synonyms
- TRIBUTYLETHYNYLSTANNANE;ETHYNYLTRI-N-BUTYLTIN;ETHYNYLTRIBUTYLSTANNANE;Ethynyltri-n-butylstannane~Tri-n-butyl(ethynyl)tin~Tri-n-butylstannylacetylene;SKL1071;NSC 203201;ETHYNYLTRIBUTYLIN;ethenyltributyltin;ETHYNYLTRIBUTYLTIN;TRIBUTYL(ETHYNYL)TIN
- CBNumber:
- CB0161680
- Molecular Formula:
- C14H28Sn
- Molecular Weight:
- 315.08
- MDL Number:
- MFCD00009420
- MOL File:
- 994-89-8.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Ethynyltributylstannane 95% | 275069 | 1g | $90.7 |
| Ethynyltributylstannane 95% | 275069 | 5g | $109 |
| Tributylethynylstannane Asreported | 290772 | 1g | $352 |
| Tributylethynylstannane Asreported | 290772 | 2g | $468 |
| Tributylethynylstannane Asreported | 290772 | 5g | $582 |
| Boiling point | 70 °C0.2 mm Hg(lit.) |
|---|---|
| Density | 1.089 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 165 °F |
| storage temp. | Sealed in dry,Store in freezer, under -20°C |
| form | liquid |
| Specific Gravity | 1.089 |
| Appearance | Colorless to light yellow Liquid |
| Water Solubility | Not miscible or difficult to mix with water. |
| Sensitive | Moisture Sensitive |
| BRN | 3537659 |
| InChI | InChI=1S/3C4H9.C2H.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;1H; |
| InChIKey | YEMJHNYABQHWHL-UHFFFAOYSA-N |
| SMILES | [Sn](CCCC)(CCCC)(CCCC)C#C |
| CAS DataBase Reference | 994-89-8(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() ![]() GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H312-H315-H319-H360FD-H372-H410 | |||||||||
| Precautionary statements | P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | T,N,Xn | |||||||||
| Risk Statements | 21-25-36/38-48/23/25-50/53 | |||||||||
| Safety Statements | 35-36/37/39-45-60-61 | |||||||||
| RIDADR | UN 2788 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 21 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Acute Tox. 3 Oral Acute Tox. 4 Dermal Aquatic Acute 1 Aquatic Chronic 1 Eye Irrit. 2 Repr. 1B Skin Irrit. 2 STOT RE 1 |
|||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
TRIBUTYLSTANNYLACETYLENE price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 275069 | Ethynyltributylstannane 95% | 994-89-8 | 1g | $90.7 | 2023-06-20 | Buy |
| Sigma-Aldrich | 275069 | Ethynyltributylstannane 95% | 994-89-8 | 5g | $109 | 2023-06-20 | Buy |
| Usbiological | 290772 | Tributylethynylstannane Asreported | 994-89-8 | 1g | $352 | 2026-06-03 | Buy |
| Usbiological | 290772 | Tributylethynylstannane Asreported | 994-89-8 | 2g | $468 | 2026-06-03 | Buy |
| Usbiological | 290772 | Tributylethynylstannane Asreported | 994-89-8 | 5g | $582 | 2026-06-03 | Buy |
TRIBUTYLSTANNYLACETYLENE Chemical Properties,Uses,Production
Chemical Properties
clear colorless liquid
Uses
Used to prepare vinylstannanes and stannylisoxazoles. Ethynylation reagent for azaaromatics.
Uses
Ethynyltributylstannane can be used as a reactant to prepare:
- Terminal arylacetylene derivatives by Stille coupling reaction with aryl halides in the presence of palladium catalyst.
- 1,4-bis(tributylstannyl)but-1-en-3-yne by dimerization using a metal complex having bulky ligand catalyst system.
- Isoquinolone derivatives by reacting with benzotriazinones via denitrogenative insertion in the presence of nickel catalyst.
- Enyne key intermediates in the total synthesis of (-)-acutumine and (-)-dechloroacutumine.
Purification Methods
Purify it by dissolving the reagent (ca 50g) in heptane (250mL), washing it with H2O (100mL), drying (MgSO4), evaporating and distilling in a vacuum. It has IR: max 3280 ( C), 2950, 2850, 2005 (CC), 1455, 1065 and 865cm-1. [Bottaro et al. J Org Chem 46 5221 1981, Stille & Simpson J Am Chem Soc 109 2138 1987, Zavgorodnii et al. J Gen Chem USSR (Engl Edn) 37 1469 1967.]
TRIBUTYLSTANNYLACETYLENE Preparation Products And Raw materials
Raw materials
Preparation Products
TRIBUTYLSTANNYLACETYLENE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Sach biotech Co.,Ltd | +86-15888865902; +8615888865902 | sales@hzsqchem.com | China | 66 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Kindchem(Nanjing)Co.,Ltd | +86-025-025-85281586 +8618651653755 | sales@kindchem.cn | China | 1226 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 8741 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9996 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 | sale03@alfachem.cn | China | 9796 | 58 |
View Lastest Price from TRIBUTYLSTANNYLACETYLENE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-06-14 | TRIBUTYLSTANNYLACETYLENE
994-89-8
|
$980.00-1096.00 | 1kg | 98% | 5mt | Sach biotech Co.,Ltd | |
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2022-02-22 | Tributylstannylacetylene
994-89-8
|
1KG | 97.6% | 100 tons | Honest Joy Holdings Limited | ||
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2021-08-12 | TRIBUTYLSTANNYLACETYLENE
994-89-8
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-

- TRIBUTYLSTANNYLACETYLENE
994-89-8
- $980.00-1096.00
- 98%
- Sach biotech Co.,Ltd
-

- Tributylstannylacetylene
994-89-8
- $0.00
- 97.6%
- Honest Joy Holdings Limited
-

- TRIBUTYLSTANNYLACETYLENE
994-89-8
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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