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ChemicalBook >> CAS DataBase List >>(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Structure
(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine structure
CAS No.
292638-88-1
Chemical Name:
(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine
Synonyms
SL-J006-1;CID 145705900;(R)-(-)-1-{(S)-2-[Bis(3,5-ditrifluoromethylphenyl)dicyclohexylphosphine;(R)-(-)-1-{(S)-2-(Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}eth;(R)-1-{(S)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldicy;(R)-1-[(S)-2-Bis[3,5-bis(trifluoromethyl)phenylphosphino] ferrocenyl]ethyldicyclohexylphosphine;(R)-1-{(R)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine;(R)-1-{(SP)-2-[Bis[3,5-bis(trifluoroMethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine;(R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoroMethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine;(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine
CBNumber:
CB0318127
Molecular Formula:
C40H40F12FeP210*
Molecular Weight:
866.52
MDL Number:
MFCD03426991
MOL File:
292638-88-1.mol
MSDS File:
SDS
Last updated:2026-09-12 18:48:07
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(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Properties

alpha -260° ±15° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
InChIKey QRWXESUNHGCSDF-GHVWMZMZSA-N
SMILES [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3cc(cc(c3)C(F)(F)F)C(F)(F)F)c4cc(cc(c4)C(F)(F)F)C(F)(F)F)P(C5CCCCC5)C6CCCCC6
CAS DataBase Reference 292638-88-1
UNSPSC Code 12352101

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
WGK Germany  3
HS Code  29319090
Storage Class 13 - Non Combustible Solids

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 26-0960 (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethyl­phenyl)phosphino]ferrocenyl}ethyldi­cyclohexylphosphine, min. 97% min.97% 292638-88-1 100mg $111 2026-04-30 Buy
Strem Chemicals 26-0960 (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethyl­phenyl)phosphino]ferrocenyl}ethyldi­cyclohexylphosphine, min. 97% min.97% 292638-88-1 500mg $387 2026-04-30 Buy
Strem Chemicals 26-0960 (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethyl­phenyl)phosphino]ferrocenyl}ethyldi­cyclohexylphosphine, min. 97% min.97% 292638-88-1 2g $1062 2026-04-30 Buy
Strem Chemicals 26-0960 (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethyl­phenyl)phosphino]ferrocenyl}ethyldi­cyclohexylphosphine, min. 97% min.97% 292638-88-1 10g $4511 2026-04-30 Buy
aablocks AA002XTA (R)-1-{(Sp)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine ≥97% 292638-88-1 50mg $11 2026-05-28 Buy
Product number Packaging Price Buy
26-0960 100mg $111 Buy
26-0960 500mg $387 Buy
26-0960 2g $1062 Buy
26-0960 10g $4511 Buy
AA002XTA 50mg $11 Buy

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Chemical Properties,Uses,Production

Reaction

  1. Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products2,3. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain.4 These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
  2. Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
  3. Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
  4. Asymmetric hydrogenation of ketones and phosphinylketimines.
  5. Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
  6. Boration of ∀,∃-unsaturated esters and nitriles.
  7. Reaction of aryl halides with ammonia.
  8. Cu-catalyzed reduction of activated C=C bonds with PMHS.
  9. Regio- and enantioselective hydroboration of vinyl arenes.
  10. Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
  11. 1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
  12. Catalyst for the homodimerization of ketoketenes.
  13. Ligand for the Rh catalyzed synthesis of lactones.
  14. Ligand for the Cu-catalyzed synthesis of syn and anti γ-amino alcohols.
Reactions of 292638-88-1_1
Reactions of 292638-88-1_2
Reactions of 292638-88-1_3

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Suppliers

Global( 66)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Holy Biohemdeviser Co., Ltd 021-61551100 China 443 57
T&W GROUP 021-61551611 13296011611 contact@trustwe.com China 9884 58
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232 307593986@qq.com China 475 58
Zhengzhou HQ Material Co., Ltd. 0371-67759225 13526468238 sales@hqmat.com China 510 60
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 282 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Zhengzhou HQ Material Co., Ltd. 67759225 13526468238 sales@hqmat.com China 812 55
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Shanghai Holy Biohemdeviser Co., Ltd 57
T&W GROUP 58
Shanghai Incat Chemtech Co.,Ltd. 58
Zhengzhou HQ Material Co., Ltd. 60
Bide Pharmatech Ltd. 60
Xinxiang Runyu Material Co., Ltd. 55
Sigma-Aldrich 80
Zhengzhou HQ Material Co., Ltd. 55

View Lastest Price from (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE pictures 2026-08-07 (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
292638-88-1
 1KG 98% 1000kg Shaanxi Dideu New Materials Co. Ltd
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE pictures 2020-01-10 (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
292638-88-1
 $1.00 1g 98% 200kgs Career Henan Chemical Co
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE pictures 2020-01-10 (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
292638-88-1
 $1.00 1g 98% 200kgs Career Henan Chemical Co

(R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Spectrum

(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE(292638-88-1)1HNMR

292638-88-1((R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine)Related Search:

(R)-1-[(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl]-ethyldi-tert-butylphosphine (R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-(S)-JOSIPHOS (R)-(-)-1-[(S)-2-(Di(3,5-dimethyl-4-methoxyphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine
(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine Bis(3,5-di(trifluoromethyl)phenyl)phosphine (R)-(+)-1-((R)-2-(Diphenylphosphino)ferrocenyl)ethyldicyclohexylphosphine

1of2

(R)-1-{(S)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldicy (R)-(-)-1-{(S)-2-(Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine,min.97% (r,r)-1-{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (acc to cas) (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine, min. 97% (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}
ethyldicyclohexylphosphine, min. 97% (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoroMethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine (R)-1-{(SP)-2-[Bis[3,5-bis(trifluoroMethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine (R)-1-{(SP)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine >=97% (1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2-[(1R)-1-(dicyclohexylphosphino)ethyl]ferrocene (R)-(-)-1-{(S)-2-[Bis(3,5-ditrifluoromethylphenyl)dicyclohexylphosphine SL-J006-1 (R)-(-)-1-{(S)-2-(Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}eth Ferrocene, 1-[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2-[(1R)-1-(dicyclohexylphosphino)ethyl]-, (1R)- (R)-1-[(S)-2-Bis[3,5-bis(trifluoromethyl)phenylphosphino] ferrocenyl]ethyldicyclohexylphosphine (R)-1-{(R)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine (R)-(-)-1-{(Sp)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine CID 145705900 (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine,97% (R)-1-{(SP)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine 292638-88-1 C40H40F12FeP2 Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Solvias Ligands Privileged Ligands Chiral Phosphine Ferrocene Series Josiphos Series organophosphine ligand