Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>Piperonyl acetone

Piperonyl acetone

Piperonyl acetone Structure
Piperonyl acetone structure
CAS No.
55418-52-5
Chemical Name:
Piperonyl acetone
Synonyms
DULCINYL;4-(benzo[d][1,3]dioxol-5-yl)butan-2-one;FEMA 2701;PIPERONYLACETONE;HELIOTROPYL ACETONE;Piperonylacetone>Piperonylacetone(Dulcinyl);Piperonyl acetone USP/EP/BP;4-(3,4-methylenedioxyphenyl)-2;3,4-METHYLENEDIOXYBENZYL ACETONE
CBNumber:
CB0328014
Molecular Formula:
C11H12O3
Molecular Weight:
192.21
MDL Number:
MFCD00016910
MOL File:
55418-52-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-16 07:06:08
Request For Quotation

Piperonyl acetone Properties

Melting point 49-54 °C(lit.)
Boiling point 176 °C17 mm Hg(lit.)
Density 1.175±0.06 g/cm3(Predicted)
refractive index 1.52-1.522
FEMA 2701 | 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
FLAVIS Number 07.031 | Piperonyl acetone
Flash point >230 °F
storage temp. 4°C
solubility Chloroform (Slightly), DMSO (Slightly)
form Solid
color Colourless crystals.
Odor at 10.00 % in dipropylene glycol. sweet raspberry heliotrope powdery cotton candy
Odor Type floral
JECFA Number 2048
BRN 169843
Cosmetics Ingredients Functions SKIN CONDITIONING - MISCELLANEOUS
InChIKey TZJLGGWGVLADDN-UHFFFAOYSA-N
LogP 1.53
CAS DataBase Reference 55418-52-5(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
FDA UNII 081VVC9H34
NIST Chemistry Reference 4-(3,4-Methylenedioxyphenyl)-2-butanone(55418-52-5)
EPA Substance Registry System 2-Butanone, 4-(1,3-benzodioxol-5-yl)- (55418-52-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Safety Statements  22-24/25
WGK Germany  2
TSCA  TSCA listed
HS Code  2914.19.0000
Toxicity The acute oral LD50 value in rats was reported as 4Og/kg and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Wohl, 1974).
NFPA 704
1
0 0

Piperonyl acetone price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich S114162 4-BENZO(1,3)DIOXOL-5-YL-BUTAN-2-ONE AldrichCPR 55418-52-5 1 unit $197 2026-04-30 Buy
Sigma-Aldrich S114162 4-BENZO(1,3)DIOXOL-5-YL-BUTAN-2-ONE Aldrich 55418-52-5 100mg $179 2024-03-01 Buy
TCI Chemical P1089 Piperonylacetone >98.0%(GC) 55418-52-5 25g $89 2026-04-30 Buy
Usbiological 287607 PiperOnyl acetOne Asreported 55418-52-5 10g $213 2026-06-03 Buy
Usbiological 287607 PiperOnyl acetOne Asreported 55418-52-5 25g $312 2026-06-03 Buy
Product number Packaging Price Buy
S114162 1 unit $197 Buy
S114162 100mg $179 Buy
P1089 25g $89 Buy
287607 10g $213 Buy
287607 25g $312 Buy

Piperonyl acetone Chemical Properties,Uses,Production

Aroma

Intensely sweet, floral and very slightly woody-powdery odor reminiscent of the sweetfloral notes in Mimosa and Cassie. Also remotely reminiscent of Heliotrope.
The taste in dilutions below 50 ppm is sweet, somewhat fruity and "Cherry-pit"-like. Higher concentrations tend to show a somewhat bitter taste.

Uses in Perfume

For several decades well kept as a "secret" chemical this ketone is one of the most interest ing and successful condensation products from a perfumery point of view. Piperonyl acetone finds application in Lilac, Lily, Sweet Pea, Appleblossom, Mimosa, Cassie, Ylang-Ylang, Heliotrope, Carnation, etc. and is particularly interesting in lipstick perfumes, also because it blends well with lonones.
Piperonyl acetone finds use in flavor compositions for imitation Cherry ("pit flavor") in various fruit complexes. Occasionally as a modifier in Vanilla imitation. The concentration is about 8 to 45 ppm in finished products. The highest figures are usually in icecream, about 50 ppm.

Description

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor. May be prepared by condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst.

Chemical Properties

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor reminiscent of raspberry, cotton candy (i.e., candy floss) with a cassie, heliotrope association.

Occurrence

Has apparently not been reported to occur in nature.

Definition

ChEBI: 4-(3,4-Methylenedioxyphenyl)-2-butanone is a member of benzodioxoles.

Preparation

By condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst

Taste threshold values

Taste characteristics at 40 ppm: sweet, berry-like with spicy, jamy nuances

Metabolism

The oxygen-aromatic carbon link of aromatic ethers is generally biologically stable, and possible metabolites include the p-hydroxy derivative of the ether, the phenol or the p-hydroxyphenol (Williams, 1959). Ketones are not readily metabolized in the body. As a derivative of 2-butanone, piperonyl acetone might be expected to be partially reduced to the secondary alcohol and excreted as the glucuronide (Williams, 1959), since Saneyoshi (1911) isolated the glucuronide of 2-butanol from the urine of rabbits receiving methyl ethyl ketone.

Piperonyl acetone synthesis

139-85-5
55418-52-5
Synthesis of Piperonyl acetone from Protocatechualdehyde

Piperonyl acetone Preparation Products And Raw materials

Raw materials

2-Butanone, 4-(6-iodo-1,3-benzodioxol-5-yl)- 5(2H)-Isoxazolone, 4-(1,3-benzodioxol-5-ylmethyl)-3-methyl- (E)-4-(benzo[d][1,3]dioxol-6-yl)but-3-en-2-one Piperonyl alcohol Sulfuric acid
Ethyl acetate Methyl vinyl ketone Ethanol 3,4-Methylenedioxyphenylboronic acid Acetone
Piperonyl aldehyde Protocatechualdehyde

1of3

Preparation Products

3,4-Methylenedioxyacetophenone

Piperonyl acetone Suppliers

Global( 154)Suppliers
Supplier Tel Email Country ProdList Advantage
Chengdu jingzhihuacheng Chemical Technology Co., Ltd. 028-37664989 15900794981 873239557@qq.com China 1050 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TAIYUAN RHF CO.,LTD. +86 351 7031519 sales@RHFChem.com China 2334 56
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10174 62
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Sichuan Kulinan Technology Co., Ltd 400-1166-196 18981987031 cdhxsj@163.com China 11674 57
Supplier Advantage
Chengdu jingzhihuacheng Chemical Technology Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
TAIYUAN RHF CO.,LTD. 56
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Capot Chemical Co., Ltd 66
Pure Chemistry Scientific Inc. 62
Syntechem Co.,Ltd 57
Sichuan Kulinan Technology Co., Ltd 57

View Lastest Price from Piperonyl acetone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Piperonyl acetone pictures 2026-07-15 Piperonyl acetone
55418-52-5
 $29.00 99.87% 10g TargetMol Chemicals Inc.
Piperonyl acetone pictures 2026-03-20 Piperonyl acetone
55418-52-5
 $10.00 1kg 99% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
Piperonyl acetone pictures 2025-05-23 Piperonyl acetone
55418-52-5
 $60.00 1kg 99% 20 tons Hebei Zhuanglai Chemical Trading Co Ltd

Piperonyl acetone Spectrum

Piperonyl acetone(55418-52-5)MSPiperonyl acetone(55418-52-5)1HNMRPiperonyl acetone(55418-52-5)13CNMRPiperonyl acetone(55418-52-5)IR1Piperonyl acetone(55418-52-5)IR2

55418-52-5(Piperonyl acetone)Related Search:

3-Oxobutanenitrile Selenium dioxide Piperonyl butoxide 1,4-Dioxane Calcium pyruvate
Methyltris(methylethylketoxime)silane Methoxyacetone Chlorodimethylphenylsilane Acetylacetone Piperonyl alcohol
4-Methyl-2-pentanone Phenylacetone 1-Deuteriopropan-2-one Benzylacetone Piperonyl aldehyde
2-Butanone Piperonyl methyl ketone 5-[3,4(METHYLENEDIOXY)PHENYL]-1,3-CYCLOHEXANEDIONE

1of4

PIPERONYLACETONE 2-Butanone, 4-(1,3-benzodioxol-5-yl)- 4-(2H-1,3-benzodioxol-5-yl)butan-2-one 4-(1,3-benzodioxol-5-yl)-2-butanon 3,4-METHYLENEDIOXYBENZYL ACETONE 4-BENZO[1,3]DIOXOL-5-YL-BUTAN-2-ONE 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE 4-(3,4-METHYLENDIOXYPHENYL)-2-BUTANONE 4-(1,3-BENZODIOXOL-5-YL)-2-BUTANONE 4-(1,3-Benzodioxol-5-yl)-2-butanone~3,4-(Methylenedioxy)benzylacetone 4-(1,3-benzodioxol-5-yl)butan-2-one 4-(3,4-methylenedioxyphenyl)-2 2-BUTANONE,4-(3,4-METHYLENEDIOXYPHENYL)- 4-(1,3-Benzodioxol-5-yl)butan-2-on 3 4-METHYLENEDIOXYBENZYL ACETONE 97% 4-[3,4-(Methylenebisoxy)phenyl]butan-2-one 4-(1,3-Benzodioxol-5-yl)-2-butanone 4-(3,4-Methylenedioxyphenyl)-2-butanone 4-(benzo[d][1,3]dioxol-5-yl)butan-2-one Piperonylacetone> Piperonyl acetone USP/EP/BP Factory supply Piperonyl acetone CAS 55418-52-5 high quality Piperonyl acetone, 10 mM in DMSO Piperonylacetone(Dulcinyl) DULCINYL FEMA 2701 HELIOTROPYL ACETONE 55418-52-5 Cd1H12O3 Aromatic Ketones (substituted)