3-Bromofuran
- CAS No.
- 22037-28-1
- Chemical Name:
- 3-Bromofuran
- Synonyms
- 3-bromofurane;Furan, 3-bromo-;3-Furyl broMide;3-BROMOFURAN;b-Bromofuran;β-BroMofuran;BROMOFURANE-3;3-Bromofuran99%;BETA-BROMOFURAN;3-Bromofuran 97%
- CBNumber:
- CB0329248
- Molecular Formula:
- C4H3BrO
- Molecular Weight:
- 146.97
- MDL Number:
- MFCD00005347
- MOL File:
- 22037-28-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 131.5-132 °C |
|---|---|
| Boiling point | 103 °C (lit.) |
| Density | 1.635 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 38 °F |
| storage temp. | -20°C |
| solubility | Chloroform, Ethyl Acetate |
| form | Liquid |
| color | Clear yellow to orange to brown |
| Water Solubility | Soluble in chloroform, ethyl acetate. Insoluble in water. |
| BRN | 105337 |
| InChI | InChI=1S/C4H3BrO/c5-4-1-2-6-3-4/h1-3H |
| InChIKey | LXWLEQZDXOQZGW-UHFFFAOYSA-N |
| SMILES | O1C=CC(Br)=C1 |
| CAS DataBase Reference | 22037-28-1(CAS DataBase Reference) |
| FDA UNII | YQ2XT7CKM5 |
| NIST Chemistry Reference | Furan, 3-bromo-(22037-28-1) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P242-P243 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | F,Xi | |||||||||
| Risk Statements | 11-36/37/38 | |||||||||
| Safety Statements | 16-23-24/25-37/39-26-33-29-7/9 | |||||||||
| RIDADR | UN 1993 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10 | |||||||||
| Hazard Note | Highly Flammable/Irritant | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29321900 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Flam. Liq. 2 | |||||||||
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
3-Bromofuran price More Price(66)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 176524 | 3-Bromofuran 97% | 22037-28-1 | 2.5g | $276 | 2026-04-30 | Buy |
| Sigma-Aldrich | 176524 | 3-Bromofuran 97% | 22037-28-1 | 10g | $879 | 2026-04-30 | Buy |
| TCI Chemical | B2157 | 3-Bromofuran >98.0%(GC) | 22037-28-1 | 1g | $41 | 2026-04-30 | Buy |
| TCI Chemical | B2157 | 3-Bromofuran >98.0%(GC) | 22037-28-1 | 5g | $118 | 2026-04-30 | Buy |
| Usbiological | 261702 | 3-Bromofuran Asreported | 22037-28-1 | 10g | $340 | 2026-06-03 | Buy |
3-Bromofuran Chemical Properties, Uses, Production
Chemical Properties
3-Bromofuran is a colorless to light yellow liquid having a boiling point similar to that of water (102.5-102.6 °C), but with density significantly higher (1.6606 g/cm3 at 20 °C).It is colorless when it is pure; however, the color can be light yellow when minor impurities are present. It is usaually stablized by calcium carbonate. It was used in the preparation of 2-substituted 3-furfurals. It was also used in the synthesis of 5,6-dehydronorcantharidins. 3-bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.
Uses
3-Bromofuran is heterocyclic building block used in organic synthesis. 3-Bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.
Synthesis
3-Bromofuran was obtained in minor amounts in 1887 as a byproduct in a reaction of 3-bromofuroic acid with calcium hydroxide. About four decades later this compound was prepared deliberately and in higher yield. 3-bromofuran has been prepared from 3,4-dibromofuran via ortho-metalation with butyl lithium in good yield. An elegant synthesis of 3-bromofuran is due to Fechtel who prepared this compound via a Diels Alder-bromination-reverse Diels Alder sequence.
Purification Methods
Purify 3-bromofuran by two steam distillations and dry it over fresh CaO. It can be dried over Na metal (no obvious reaction) and fractionated. It is not very soluble in H2O but is soluble in organic solvents. When freshly distilled, it is a clear oil, but darkens on standing and eventually resinifies. It can be stored for long periods by covering the oil with an alkaline solution of hydroquinone and is redistilled when required. It forms a characteristic maleic anhydride adduct, m 131.5-132o. [Shepard et al. J Am Chem Soc 52 2083 1930, Huhes & Johnson J Am Chem Soc 53 737 1931, adduct: van Campen & Johnson J Am Chem Soc 55 430 1933, Beilstein 17/1 V 295.]
3-Bromofuran Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Xi'an Qingxiang Biotechnology Co., Ltd | 029-18192656670 18192656670 | 2557411153@qq.com | China | 189 | 58 |
| Shanghai NAIFU Biotechnology Co., Ltd | 18939876937 | sales@naifuchem.com | China | 49 | 58 |
| Chengdu Sino-Strong Pharmaceutical Co.,Ltd. | 0086-28-82666753 13808081195 | sales@sino-strong.com.cn | China | 187 | 60 |
| Xi 'an billiton biological technology co., LTD | 029-88764766 | wang.yali@xatuochao.com | China | 521 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 | sales@pharmablock.com | China | 5000 | 55 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| INTATRADE GmbH | +49 3493/605464 | sales@intatrade.de | Germany | 3563 | 66 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
View Latest Price from 3-Bromofuran manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-03-20 | 3-Bromofuran
22037-28-1
|
$10.00 | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-05-12 | 3-Bromofuran
22037-28-1
|
1kg | 98% | 500 kgs | PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD | ||
 |
2021-08-12 | 3-Bromofuran
22037-28-1
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- 3-Bromofuran
22037-28-1
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 3-Bromofuran
22037-28-1
- $0.00
- 98%
- PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD
-
- 3-Bromofuran
22037-28-1
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
