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tert-Butyldimethylsilane

tert-Butyldimethylsilane Structure
tert-Butyldimethylsilane structure
CAS No.
29681-57-0
Chemical Name:
tert-Butyldimethylsilane
Synonyms
T-BUTYLDIMETHYLSILANE;CFS-570;DKSI032;Co-Formula CFS-570;Butyldimethylsilane;t-Butyldimethylsilyl;triethyl-propyl-silane;TERT-BUTYLDIMETHYLSILANE;Dimethyl tert-butylsilane;Butyl dimethylhydrosilane
CBNumber:
CB0399704
Molecular Formula:
C6H16Si
Molecular Weight:
116.28
MDL Number:
MFCD00010754
MOL File:
29681-57-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 21:53:33
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tert-Butyldimethylsilane Properties

Melting point 13°C
Boiling point 81-83 °C (lit.)
Density 0.701 g/mL at 25 °C (lit.)
refractive index n20/D 1.4(lit.)
Flash point −9 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
color Colorless to Almost colorless
Specific Gravity 0.701
Hydrolytic Sensitivity 3: reacts with aqueous base
BRN 2231162
InChI InChI=1S/C6H16Si/c1-6(2,3)7(4)5/h7H,1-5H3
InChIKey QCIWZIYBBNEPKB-UHFFFAOYSA-N
SMILES [SiH](C(C)(C)C)(C)C
CAS DataBase Reference 29681-57-0
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  16-26-36-16/26/36
RIDADR  UN 1993 3/PG 2
WGK Germany  3
F  10-21
TSCA  Yes
HazardClass  3.1
PackingGroup  I
HS Code  29319090
Storage Class 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
2 0

tert-Butyldimethylsilane price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 294764 tert-Butyldimethylsilane 95% 29681-57-0 5g $123 2026-04-30 Buy
Sigma-Aldrich 294764 tert-Butyldimethylsilane 95% 29681-57-0 25g $303 2026-04-30 Buy
TCI Chemical B3565 tert-Butyldimethylsilane >95.0%(GC) 29681-57-0 5g $58 2026-04-30 Buy
Usbiological 263684 tert-Butyldimethylsilane Asreported 29681-57-0 2g $402 2026-06-03 Buy
Usbiological 263684 tert-Butyldimethylsilane Asreported 29681-57-0 5g $648 2026-06-03 Buy
Product number Packaging Price Buy
294764 5g $123 Buy
294764 25g $303 Buy
B3565 5g $58 Buy
263684 2g $402 Buy
263684 5g $648 Buy

tert-Butyldimethylsilane Chemical Properties,Uses,Production

Uses

Tert-Butyldimethylsilane (t-BuMe2SiH) is widely used for the protection of hydroxy groups in sugars. Its oxidation product, tert-butyldimethylsilyl hydroperoxide (t-BuMe2SiOOH), is used for preparing luminiscent sources and prostanoids, specifically clavulons[1].

Reactions

The iridium complex [Ir(COD)(PPh3)2]+SbF6- reacts with tert-butyldimethylsilane in DMA to form [IrH2(Sol)2(PPh3)2]+SbF6-, which is an active catalyst for the regioselective di- and trisilylation of a series of representative methyl hexopyranosides, β-1,6-anhydrohexopyranosides and 1,3,5-O-methylidene inositol.The silylcarbobicyclization of 4,4-disubstituted 1,6-heptadiynes with tert-butyldimethylsilane catalyzed by Rh(acac)(CO)2, Co2Rh2(CO)12, or (t-BuNC)4RhCo(CO)4 under 50 atm of carbon monoxide gives the corresponding novel 7,7-disubstituted 2-silylbicyclo[3.3.0]octa-1,5-dien-3-ones in good yields[2-3].
tert-Butyldimethylsilane

References

[1] Iwao Ojima, Jiawang Zhu, Dora Fracchiolla Kass. “New and Efficient Catalytic Route to Bicyclo[3.3.0]octa-1,5-dien-3-ones.” Organometallics 15 24 (1996): 5191–5195.
[2] Mee-Kyung Chung, Marcel Schlaf. “Regioselectively Trisilylated Hexopyranosides through Homogeneously Catalyzed Silane Alcoholysis.” Journal of the American Chemical Society 127 51 (2005): 18085–18092.
[3] Iwao Ojima, Jiawang Zhu, Dora Fracchiolla Kass. “New and Efficient Catalytic Route to Bicyclo[3.3.0]octa-1,5-dien-3-ones.” Organometallics 15 24 (1996): 5191–5195.

tert-Butyldimethylsilane Preparation Products And Raw materials

Raw materials

Preparation Products

(3-Bromopropoxy)-tert-butyldimethylsilane

tert-Butyldimethylsilane Suppliers

Global( 167)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai chuqing Organosilane technology ltd 021-61530618; 18721685818 sales@chuqingtech.com China 274 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Novel Chemical +86-21-64855560, 4008207808 sales@novelglobal.com China 124 62
Thermo Fisher Scientific 800-810-5118 cnchemical@thermofisher.com China 17752 75
Supplier Advantage
Shanghai chuqing Organosilane technology ltd 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Jia Xing Isenchem Co.,Ltd 66
Shanghai Hanhong Scientific Co.,Ltd. 64
Syntechem Co.,Ltd 57
Novel Chemical 62
Thermo Fisher Scientific 75

View Lastest Price from tert-Butyldimethylsilane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
tert-Butyldimethylsilane pictures 2026-09-11 tert-Butyldimethylsilane
29681-57-0
 1KG 96% 20t Hubei Changfu Chemical Co., Ltd.
tert-Butyldimethylsilane pictures 2026-08-25 tert-Butyldimethylsilane
29681-57-0
 $1.10-9.90 1kg 99%min 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
T-BUTYLDIMETHYLSILANE pictures 2025-06-20 T-BUTYLDIMETHYLSILANE
29681-57-0
 $10.00-30.00 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.

tert-Butyldimethylsilane Spectrum

T-BUTYLDIMETHYLSILANE(29681-57-0)1HNMRT-BUTYLDIMETHYLSILANE(29681-57-0)IRT-BUTYLDIMETHYLSILANE(29681-57-0)Raman

29681-57-0(tert-Butyldimethylsilane)Related Search:

Allyloxy-t-butyldimethylsilane tert-Butyldimethylsilanol tert-Butyldimethylsilyl chloride tert-butyldimethyl(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane Tert-butyl-dimethyl-(tributylstannylmethoxy)silane
TERT-BUTYLDIMETHYLSILYL (R)-(-)-GLYCIDY& tert-butyl-methoxy-dimethylsilane t-butyldimethylIsopropoxylsilane t-Butyl methyl fumarate 5-O-(tert-Butyldimethylsilyl)-2,3-O-isoproylidene-D-ribofuranose
N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide O-(tert-Butyldimethylsilyl)hydroxylamine Dimethylthexylsilyl chloride Dimethylsilane (2-Bromoethoxy)-tert-butyldimethylsilane
n-Butyldimethylsilane (3-Bromopropoxy)-tert-butyldimethylsilane tert-Butyldimethylsilylacetylene

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TERT-BUTYLDIMETHYLSILANE Butyldimethylsilane triethyl-propyl-silane Dimethyl tert-butylsilane tert-ButyldiMethylsilane 95% tert-Butyldimethylsilane Dimethyl(2-methyl-2-propanyl)silane CFS-570 (1,1-dimethylethyl)dimethyl- Co-Formula CFS-570 Silane,(1,1-dimethylethyl)dimethyl- tert-Butyldimethylsilane > t-Butyldimethylsilyl tert-butyl(dimethyl)silicon DKSI032 tert-butyldimethylsiliconalkane T-BUTYLDIMETHYLSILANE Butyl dimethylhydrosilane 29681-57-0 91-22-2 CH33CSiHCH32 Organosilicon Others Organometallic Reagents Organometallic Reagents Organosilicon Others