tert-Butyldimethylsilylacetylene
- CAS No.
- 86318-61-8
- Chemical Name:
- tert-Butyldimethylsilylacetylene
- Synonyms
- (tert-Butyldimethylsilyl)ethyne;(T-BUTYLDIMETHYLSILYL)ACETYLENE;tert-BUTYLDIMETHYLSILYLACETYLENE, 98%tert-BUTYLDIMETHYLSILYLACETYLENE, 98%tert-BUTYLDIMETHYLSILYLACETYLENE, 98%;DK416;DKSI029;DKFELEX0321;ethynyl-t-butyldimethylsilane;tert-Butyldimethylethynylsilane;ETHYNYL-TERT-BUTYLDIMETHYLSILANE;tert-Butyldimethylsilylacetylene
- CBNumber:
- CB1385265
- Molecular Formula:
- C8H16Si
- Molecular Weight:
- 140.3
- MDL Number:
- MFCD00191877
- MOL File:
- 86318-61-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 98-102℃ (chloroform hexane ) |
|---|---|
| Boiling point | 116-117 °C (lit.) |
| Density | 0.751 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 43 °F |
| storage temp. | Flammables area |
| form | powder to lump to clear liquid |
| Specific Gravity | 0.751 |
| color | White or Colorless to Almost white or Almost colorless |
| Water Solubility | Sparingly soluble in water (0.043 g/L at 25°C). |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| BRN | 1921466 |
| InChI | InChI=1S/C8H16Si/c1-7-9(5,6)8(2,3)4/h1H,2-6H3 |
| InChIKey | RTYNRTUKJVYEIE-UHFFFAOYSA-N |
| SMILES | [Si](C)(C)(C#C)C(C)(C)C |
| CAS DataBase Reference | 86318-61-8 |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS02 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225 | |||||||||
| Precautionary statements | P210 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | F | |||||||||
| Risk Statements | 11 | |||||||||
| Safety Statements | 9-16-23-24/25-29-33 | |||||||||
| RIDADR | UN 1993 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Flam. Liq. 2 | |||||||||
| NFPA 704 |
|
tert-Butyldimethylsilylacetylene price More Price(39)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 399264 | (tert-Butyldimethylsilyl)acetylene 99% | 86318-61-8 | 1g | $87.1 | 2026-04-30 | Buy |
| Sigma-Aldrich | 399264 | (tert-Butyldimethylsilyl)acetylene 99% | 86318-61-8 | 5g | $185 | 2026-04-30 | Buy |
| TCI Chemical | B4365 | (tert-Butyldimethylsilyl)acetylene >97.0%(GC) | 86318-61-8 | 5g | $130 | 2026-04-30 | Buy |
| TCI Chemical | B4365 | (tert-Butyldimethylsilyl)acetylene >97.0%(GC) | 86318-61-8 | 25g | $511 | 2026-04-30 | Buy |
| Apolloscientific | OR40614 | [(tert-Butyl)dimethylsilyl]acetylene >99% | 86318-61-8 | 1g | $21 | 2026-06-04 | Buy |
tert-Butyldimethylsilylacetylene Chemical Properties, Uses, Production
Chemical Properties
Clear colorless liquid
Uses
tert-Butyldimethylsilylacetylene may be used in the synthesis of β-alkynylketone and β-alkynyl aldehydes. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.
General Description
(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.
tert-Butyldimethylsilylacetylene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Funing xunpeng new material technology co., ltd. | 13092380301 | 656319980@qq.com | China | 8 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Shanghai Sinch Parmaceuticals Tech. Co. Ltd. | +86-21-54098501 | sales@sinch.com.cn | China | 11592 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Shanghai Cuisen Pharmaceutical Technology Co., Ltd. | 13472757003 | yongnan.wang@cendrix.cn | China | 971 | 65 |
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