ChemicalBook >> CAS DataBase List >>2 7-Di(tert-butyl)-9-fluorenylmethyl
2 7-Di(tert-butyl)-9-fluorenylmethyl
- CAS No.
- 287381-46-8
- Chemical Name:
- 2 7-Di(tert-butyl)-9-fluorenylmethyl
- Synonyms
- 2 7-Di(tert-butyl)-9-fluorenylmethyl;2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate 97%;2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate;(2,7-ditert-butyl-9H-fluoren-9-yl)methyl carbonochloridate;Carbonochloridic acid, [2,7-bis(1,1-diMethylethyl)-9H-fluoren-9-yl]Methyl ester
- CBNumber:
- CB0499783
- Molecular Formula:
- C23H27ClO2
- Molecular Weight:
- 370.91
- MDL Number:
- MFCD03701519
- MOL File:
- 287381-46-8.mol
Last updated:2026-09-12 18:48:21
| Melting point | 66-70 °C(lit.) |
|---|---|
| Boiling point | 447.8±14.0 °C(Predicted) |
| Density | 1+-.0.06 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| InChI | 1S/C23H27ClO2/c1-22(2,3)14-7-9-16-17-10-8-15(23(4,5)6)12-19(17)20(18(16)11-14)13-26-21(24)25/h7-12,20H,13H2,1-6H3 |
| InChIKey | PHUMWWRUIGKGNN-UHFFFAOYSA-N |
| SMILES | CC(C)(C)c1ccc-2c(c1)C(COC(Cl)=O)c3cc(ccc-23)C(C)(C)C |
| UNSPSC Code | 12352100 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS05 |
|---|---|
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280-P305+P351+P338-P310 |
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Skin Corr. 1B |
2 7-Di(tert-butyl)-9-fluorenylmethyl Chemical Properties, Uses, Production
Uses
2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate may be used in the preparation of polymer-supported (2,7-di-tert-butyl-9-fluorenyl)methyl succinimidyl carbonate (Dtb-Fmoc-P-OSu), a polymeric reagent for protecting amino groups.
General Description
2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate contains 2,7-di-tert-butyl-Fmoc protecting group (Fmoc= fluorenylmethoxycarbonyl), which is more soluble in organic solvents when compared to its Fmoc analog. It can be prepared from fluorene in three steps, by di-tert-butylation, hydroxymethylation and phosgenation.



Synthesis of 2 7-Di(tert-butyl)-9-fluorenylmethyl from Phosgene and 2 7-Di-tert-butyl-9-fluorenylmethanol
2 7-Di(tert-butyl)-9-fluorenylmethyl Preparation Products And Raw materials
Raw materials
Preparation Products
2 7-Di(tert-butyl)-9-fluorenylmethyl Suppliers
Global Suppliers ( 8)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Hangzhou Sage Chemical Co., Ltd. | +86057186818502 13588463833 | info@sagechem.com | China | 10265 | 58 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Supplier | Advantage |
|---|---|
| Energy Chemical | 61 |
| Hangzhou Sage Chemical Co., Ltd. | 58 |
| Sigma-Aldrich | 80 |
287381-46-8 (2 7-Di(tert-butyl)-9-fluorenylmethyl) Related Search:
Carbonochloridic acid, [2,7-bis(1,1-diMethylethyl)-9H-fluoren-9-yl]Methyl ester
2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate 97%
(2,7-ditert-butyl-9H-fluoren-9-yl)methyl carbonochloridate
2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate
2 7-Di(tert-butyl)-9-fluorenylmethyl
287381-46-8
ClCOOCH2CHC6H3CCH332
Acid Halides
Building Blocks
Carbonyl Compounds
Chemical Synthesis
Organic Building Blocks
Acid Halides
Carbonyl Compounds
Organic Building Blocks





