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2 7-Di(tert-butyl)-9-fluorenylmethyl

CAS No.
287381-46-8
Chemical Name:
2 7-Di(tert-butyl)-9-fluorenylmethyl
Synonyms
2 7-Di(tert-butyl)-9-fluorenylmethyl;2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate 97%;2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate;(2,7-ditert-butyl-9H-fluoren-9-yl)methyl carbonochloridate;Carbonochloridic acid, [2,7-bis(1,1-diMethylethyl)-9H-fluoren-9-yl]Methyl ester
CBNumber:
CB0499783
Molecular Formula:
C23H27ClO2
Molecular Weight:
370.91
MDL Number:
MFCD03701519
MOL File:
287381-46-8.mol
Last updated:2026-09-12 18:48:21

2 7-Di(tert-butyl)-9-fluorenylmethyl Properties

Melting point 66-70 °C(lit.)
Boiling point 447.8±14.0 °C(Predicted)
Density 1+-.0.06 g/cm3(Predicted)
storage temp. 2-8°C
InChI 1S/C23H27ClO2/c1-22(2,3)14-7-9-16-17-10-8-15(23(4,5)6)12-19(17)20(18(16)11-14)13-26-21(24)25/h7-12,20H,13H2,1-6H3
InChIKey PHUMWWRUIGKGNN-UHFFFAOYSA-N
SMILES CC(C)(C)c1ccc-2c(c1)C(COC(Cl)=O)c3cc(ccc-23)C(C)(C)C
UNSPSC Code 12352100

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P305+P351+P338-P310
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B

2 7-Di(tert-butyl)-9-fluorenylmethyl price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation HCH0321478 2,7-DI-(TERT-BUTYL)-9-FLUORENYLMETHYL CHLOROFORMATE 95.00% 287381-46-8 5MG $498.74 2021-12-16 Buy
Product number Packaging Price Buy
HCH0321478 5MG $498.74 Buy

2 7-Di(tert-butyl)-9-fluorenylmethyl Chemical Properties, Uses, Production

Uses

2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate may be used in the preparation of polymer-supported (2,7-di-tert-butyl-9-fluorenyl)methyl succinimidyl carbonate (Dtb-Fmoc-P-OSu), a polymeric reagent for protecting amino groups.

General Description

2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate contains 2,7-di-tert-butyl-Fmoc protecting group (Fmoc= fluorenylmethoxycarbonyl), which is more soluble in organic solvents when compared to its Fmoc analog. It can be prepared from fluorene in three steps, by di-tert-butylation, hydroxymethylation and phosgenation.

75-44-5
136453-59-3
287381-46-8
Synthesis of 2 7-Di(tert-butyl)-9-fluorenylmethyl from Phosgene and 2 7-Di-tert-butyl-9-fluorenylmethanol

2 7-Di(tert-butyl)-9-fluorenylmethyl Preparation Products And Raw materials

Raw materials

Preparation Products

2 7-Di(tert-butyl)-9-fluorenylmethyl Suppliers

Global Suppliers ( 8)
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Hangzhou Sage Chemical Co., Ltd. +86057186818502 13588463833 info@sagechem.com China 10265 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80

287381-46-8 (2 7-Di(tert-butyl)-9-fluorenylmethyl) Related Search:

Carbonochloridic acid, [2,7-bis(1,1-diMethylethyl)-9H-fluoren-9-yl]Methyl ester 2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate 97% (2,7-ditert-butyl-9H-fluoren-9-yl)methyl carbonochloridate 2,7-Di-tert-butyl-9-fluorenylmethyl chloroformate 2 7-Di(tert-butyl)-9-fluorenylmethyl 287381-46-8 ClCOOCH2CHC6H3CCH332 Acid Halides Building Blocks Carbonyl Compounds Chemical Synthesis Organic Building Blocks Acid Halides Carbonyl Compounds Organic Building Blocks