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5-Bromo-2 2'-bithiophene 96

5-Bromo-2 2'-bithiophene 96 structure

CAS No.: 3480-11-3

Chemical Name:: 5-Bromo-2 2'-bithiophene 96

Synonyms: 2T-Br;5-Bromo-2,2'-bithienyl;5-Bromo-alpha-dithienyl;5-Bromo-2,2'-bithiophene;2,2'-Bithiophene, 5-bromo-;5-Bromo-[2,2']bithiophenyl;5-Bromo-2 2'-bithiophene 96;5-BroMo-2,2'-bithiophene 96%;5-Bromo-2,2'-bithiophene USP/EP/BP;5-Bromo-2,2′-bithiophene, CAS 3480-11-3

CBNumber:: CB0500267

Molecular Formula:: C8H5BrS2

Molecular Weight:: 245.16

MDL Number:: MFCD01461947

MOL File:: 3480-11-3.mol

MSDS File:: SDS

Last updated:2026-09-12 18:48:21

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5-Bromo-2 2'-bithiophene 96 Properties

Melting point	29-32 °C(lit.)
Boiling point	50 °C(Press: 0.006 Torr)
Density	1.635±0.06 g/cm3(Predicted)
Flash point	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	solid
Appearance	Light yellow to green yellow Solid
InChI	1S/C8H5BrS2/c9-8-4-3-7(11-8)6-2-1-5-10-6/h1-5H
InChIKey	OMOAIGVIYUXYAU-UHFFFAOYSA-N
SMILES	Brc1ccc(s1)-c2cccs2
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS08
Signal word	Danger
Hazard statements	H317-H334
Precautionary statements	P501-P261-P272-P280-P284-P302+P352-P342+P311-P362+P364-P304+P340-P333+P313
PPE	Eyeshields, Gloves, type N95 (US)
WGK Germany	3
Storage Class	11 - Combustible Solids

5-Bromo-2 2'-bithiophene 96 price More Price(48)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	522856	5-Bromo-2,2′-bithiophene 96%	3480-11-3	1g	$77.8	2026-04-30	Buy
TCI Chemical	B4789	5-Bromo-2,2'-bithiophene min. 98.0 %	3480-11-3	1G	$185	2026-04-30	Buy
AstaTech	51544	2-BROMODITHIOPHENE 97%	3480-11-3	1G	$79	2026-04-30	Buy
AstaTech	51544	2-BROMODITHIOPHENE 97%	3480-11-3	5G	$238	2026-04-30	Buy
Matrix Scientific	094838	5-Bromo-2,2'-bithiophene	3480-11-3	1.00g	$53	2026-05-18	Buy

Product number	Packaging	Price	Buy
522856	1g	$77.8	Buy
B4789	1G	$185	Buy
51544	1G	$79	Buy
51544	5G	$238	Buy
094838	1.00g	$53	Buy

5-Bromo-2 2'-bithiophene 96 Chemical Properties, Uses, Production

Uses

5-Bromo-2,2′-bithiophene may be used in the synthesis of trimethyl-[2,2′;5′,2″;5″,2″]quaterthiophen-5-yl-silane (4TTMS) and 5-hexylsulfanyl-2,2′:5′,2′′-terthiophene.

General Description

5-Bromo-2,2′-bithiophene is a bromothiophene derivative. Its reaction with various aryl iodides bearing an electron-donating or electron-withdrawing substituent has been described. It can be synthesized from 2,2′-bithiophene.

Synthesis

492-97-7

3480-11-3

General procedure for the synthesis of 5-bromo-2,2-bithiophene from bithiophene: 3 g (18 mmol) of 2,2'-bithiophene and 50 mL of N,N-dimethylformamide (DMF) were placed in a 250 mL two-necked round-bottomed flask and dissolved by stirring. A solution of 3.2 g (18 mmol) of N-bromosuccinimide (NBS) dissolved in 10 mL of DMF was added slowly and dropwise under cooling in an ice bath. After completion of the reaction, the reaction mixture was extracted with dichloromethane (DCM) and the organic phase was collected. Purification by recrystallization from methanol (MeOH) gave 2.5 g of light yellow solid product in 56% yield. The resulting intermediate (1) was characterized by nuclear magnetic resonance hydrogen spectroscopy (1H NMR, CDCl3, 400 MHz) with the following chemical shifts: δ= 6.91 (1H, d), 6.96 (1H, d), 7.00 (1H, dd), 7.22 (1H).

References

[1] Patent: US6342610, 2002, B2. Location in patent: Page column 58
[2] ACS Catalysis, 2016, vol. 6, # 2, p. 1113 - 1121
[3] RSC Advances, 2017, vol. 7, # 89, p. 56586 - 56593
[4] Chemistry of Materials, 2010, vol. 22, # 7, p. 2325 - 2332
[5] Journal of Organic Chemistry, 1996, vol. 61, # 20, p. 6906 - 6921

5-Bromo-2 2'-bithiophene 96 Preparation Products And Raw materials

Raw materials

2,2'-Bithiophene N-Bromosuccinimide N,N-Dimethylformamide

Preparation Products

2,2'-Bithiophene-5-boronic acid

5-Bromo-2 2'-bithiophene 96 Suppliers

Global Suppliers ( 80)

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Beijing HwrkChemical Technology Co., Ltd	89508211 18501085097	sales.bj@hwrkchemical.com	China	9407	55
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64
T&W GROUP	021-61551611 13296011611	contact@trustwe.com	China	9884	58
Shanghai Aladdin Bio-Chem Technology Co.,LTD	400-6206333 13167063860	anhua.mao@aladdin-e.com	China	29977	65
Cantotech Chemicals, Ltd.	86-0755-86635001	cantotech@126.com	China	4554	55
Zhengzhou TRIZ Pharmaceutical Technology Co., Ltd.	19943855286	94644163@qq.com	China	1934	56
Shanghai Macklin Biochemical Co.,Ltd.	15221275939 15221275939	shenlinxing@macklin.cn	China	15775	55
Hangzhou J&H Chemical Co., Ltd.	0571-87396432	sales@jhechem.com	China	14905	59

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Beijing HwrkChemical Technology Co., Ltd	55
Energy Chemical	61
Shanghai Hanhong Scientific Co.,Ltd.	64
T&W GROUP	58
Shanghai Aladdin Bio-Chem Technology Co.,LTD	65
Cantotech Chemicals, Ltd.	55
Zhengzhou TRIZ Pharmaceutical Technology Co., Ltd.	56
Shanghai Macklin Biochemical Co.,Ltd.	55
Hangzhou J&H Chemical Co., Ltd.	59

View Latest Price from 5-Bromo-2 2'-bithiophene 96 manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-07-11	2-Bromodithiophene 3480-11-3	$1.00	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd
2022-08-31	5-bromo-2,2'-bithiophene 3480-11-3		10g	98%	20kg	Zhengzhou Gecko Scientific Inc.
2019-07-06	5-BROMO-2 2'-BITHIOPHENE 96 3480-11-3	$1.00	1G	98%	1000KG	Career Henan Chemical Co

2-Bromodithiophene
3480-11-3
$1.00
99%
Shaanxi Dideu Medichem Co. Ltd

5-bromo-2,2'-bithiophene
3480-11-3
98%
Zhengzhou Gecko Scientific Inc.

5-BROMO-2 2'-BITHIOPHENE 96
3480-11-3
$1.00
98%
Career Henan Chemical Co

5-Bromo-2 2'-bithiophene 96 Spectrum

5-BROMO-2 2'-BITHIOPHENE 96(3480-11-3)¹HNMR

3480-11-3 (5-Bromo-2 2'-bithiophene 96) Related Search:

alpha-Sexithiophene α,ω-Dihexylquaterthiophene, 5,5μ-Bis(3-hexyl-2-thienyl)-2,2μ-bithiophene, DH-4T o-Quarterphenyl 5,5'-Dibromo-2,2'-bithiophene 5,5''-dibromo-[2,2':5',2"]terthiohene

5''-Bromo-3'-decyl-2,2',5',2''-terthiophene 5-Bromo-3'-decyl-2,2':5',2''-terthiophene 2-Bromoterthiophene 5-Bromo-2 2'-bithiophene 96 5-Bromo-2,2'-bithiophene-5'-carboxaldehyde

5''-Bromo-2,2':5',2''-terthiophene-5-carboxaldehyde RARECHEM AL BF 0485 RARECHEM AL BE 0509 RARECHEM AL BI 0485 RARECHEM AL BI 0509

RARECHEM AL BD 0509 RARECHEM AL BK 0485 SALOR-INT L164909-1EA

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