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5-BROMO-2 2'-BITHIOPHENE 96

5-BROMO-2 2'-BITHIOPHENE 96 structure

CAS No.: 3480-11-3

Chemical Name:: 5-BROMO-2 2'-BITHIOPHENE 96

Synonyms: 2T-Br;5-Bromo-2,2'-bithienyl;5-Bromo-alpha-dithienyl;5-Bromo-2,2'-bithiophene;2,2'-Bithiophene, 5-bromo-;5-Bromo-[2,2']bithiophenyl;5-BroMo-2,2'-bithiophene 96%;5-BROMO-2 2'-BITHIOPHENE 96;5-Bromo-2,2'-bithiophene USP/EP/BP;5-Bromo-2,2′-bithiophene, CAS 3480-11-3

CBNumber:: CB0500267

Molecular Formula:: C8H5BrS2

Molecular Weight:: 245.16

MDL Number:: MFCD01461947

MOL File:: 3480-11-3.mol

MSDS File:: SDS

Last updated:2026-05-27 22:46:24

Product description	Number	Pack Size	Price
5-Bromo-2,2′-bithiophene 96%	522856	1g	$77.8
5-Bromo-2,2'-bithiophene min. 98.0 %	B4789	1G	$185
2-BROMODITHIOPHENE 97%	51544	1G	$79
2-BROMODITHIOPHENE 97%	51544	5G	$238
5-Bromo-2,2'-bithiophene	094838	1.00g	$53
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5-BROMO-2 2'-BITHIOPHENE 96 Properties

Melting point	29-32 °C(lit.)
Boiling point	50 °C(Press: 0.006 Torr)
Density	1.635±0.06 g/cm3(Predicted)
Flash point	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	solid
Appearance	Light yellow to green yellow Solid
InChI	1S/C8H5BrS2/c9-8-4-3-7(11-8)6-2-1-5-10-6/h1-5H
InChIKey	OMOAIGVIYUXYAU-UHFFFAOYSA-N
SMILES	Brc1ccc(s1)-c2cccs2
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS08
Signal word	Danger
Hazard statements	H317-H334
Precautionary statements	P501-P261-P272-P280-P284-P302+P352-P342+P311-P362+P364-P304+P340-P333+P313
PPE	Eyeshields, Gloves, type N95 (US)
WGK Germany	3
Storage Class	11 - Combustible Solids

5-BROMO-2 2'-BITHIOPHENE 96 price More Price(60)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	522856	5-Bromo-2,2′-bithiophene 96%	3480-11-3	1g	$77.8	2026-04-30	Buy
TCI Chemical	B4789	5-Bromo-2,2'-bithiophene min. 98.0 %	3480-11-3	1G	$185	2026-04-30	Buy
AstaTech	51544	2-BROMODITHIOPHENE 97%	3480-11-3	1G	$79	2026-04-30	Buy
AstaTech	51544	2-BROMODITHIOPHENE 97%	3480-11-3	5G	$238	2026-04-30	Buy
Matrix Scientific	094838	5-Bromo-2,2'-bithiophene	3480-11-3	1.00g	$53	2026-05-18	Buy

Product number	Packaging	Price	Buy
522856	1g	$77.8	Buy
B4789	1G	$185	Buy
51544	1G	$79	Buy
51544	5G	$238	Buy
094838	1.00g	$53	Buy

5-BROMO-2 2'-BITHIOPHENE 96 Chemical Properties,Uses,Production

Uses

5-Bromo-2,2′-bithiophene may be used in the synthesis of trimethyl-[2,2′;5′,2″;5″,2″]quaterthiophen-5-yl-silane (4TTMS) and 5-hexylsulfanyl-2,2′:5′,2′′-terthiophene.

General Description

5-Bromo-2,2′-bithiophene is a bromothiophene derivative. Its reaction with various aryl iodides bearing an electron-donating or electron-withdrawing substituent has been described. It can be synthesized from 2,2′-bithiophene.

Synthesis

492-97-7

3480-11-3

General procedure for the synthesis of 5-bromo-2,2-bithiophene from bithiophene: 3 g (18 mmol) of 2,2'-bithiophene and 50 mL of N,N-dimethylformamide (DMF) were placed in a 250 mL two-necked round-bottomed flask and dissolved by stirring. A solution of 3.2 g (18 mmol) of N-bromosuccinimide (NBS) dissolved in 10 mL of DMF was added slowly and dropwise under cooling in an ice bath. After completion of the reaction, the reaction mixture was extracted with dichloromethane (DCM) and the organic phase was collected. Purification by recrystallization from methanol (MeOH) gave 2.5 g of light yellow solid product in 56% yield. The resulting intermediate (1) was characterized by nuclear magnetic resonance hydrogen spectroscopy (1H NMR, CDCl3, 400 MHz) with the following chemical shifts: δ= 6.91 (1H, d), 6.96 (1H, d), 7.00 (1H, dd), 7.22 (1H).

References

[1] Patent: US6342610, 2002, B2. Location in patent: Page column 58
[2] ACS Catalysis, 2016, vol. 6, # 2, p. 1113 - 1121
[3] RSC Advances, 2017, vol. 7, # 89, p. 56586 - 56593
[4] Chemistry of Materials, 2010, vol. 22, # 7, p. 2325 - 2332
[5] Journal of Organic Chemistry, 1996, vol. 61, # 20, p. 6906 - 6921

5-BROMO-2 2'-BITHIOPHENE 96 Preparation Products And Raw materials

Raw materials

2,2'-BITHIOPHENE N-Bromosuccinimide N,N-Dimethylformamide

Preparation Products

2,2'-BITHIOPHENE-5-BORONIC ACID

5-BROMO-2 2'-BITHIOPHENE 96 Suppliers

Global( 81)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-173 9270 1263	1057@dideu.com	China	3957	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14026	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29812	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413	contact@trustwe.com	China	5746	58
Neostar United (Changzhou) Industrial Co., Ltd.	+86-0519-85551759	marketing1@neostarunited.com	China	8828	58
CD Chemical Group Limited	+86-13651442114	info@codchem.com	China	17259	58
Henan Alfa Chemical Co., Ltd	+8618339805032	sale03@alfachem.cn	China	9813	58
Zhengzhou Gecko Scientific Inc.	13938510057	1974496791@qq.com	China	283	58
GIHI CHEMICALS CO.,LIMITED	+86-571-86217390; +8618058761490	info@gihichemicals.com	China	49895	58
Aladdin Scientific		tp@aladdinsci.com	United States	57505	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
Shanghai Daken Advanced Materials Co.,Ltd	58
career henan chemical co	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Neostar United (Changzhou) Industrial Co., Ltd.	58
CD Chemical Group Limited	58
Henan Alfa Chemical Co., Ltd	58
Zhengzhou Gecko Scientific Inc.	58
GIHI CHEMICALS CO.,LIMITED	58
Aladdin Scientific	58

View Lastest Price from 5-BROMO-2 2'-BITHIOPHENE 96 manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-07-11	2-Bromodithiophene 3480-11-3	$1.00	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd
2022-08-31	5-bromo-2,2'-bithiophene 3480-11-3		10g	98%	20kg	Zhengzhou Gecko Scientific Inc.
2019-07-06	5-BROMO-2 2'-BITHIOPHENE 96 3480-11-3	$1.00	1G	98%	1000KG	Career Henan Chemical Co

2-Bromodithiophene
3480-11-3
$1.00
99%
Shaanxi Dideu Medichem Co. Ltd

5-bromo-2,2'-bithiophene
3480-11-3
98%
Zhengzhou Gecko Scientific Inc.

5-BROMO-2 2'-BITHIOPHENE 96
3480-11-3
$1.00
98%
Career Henan Chemical Co

5-BROMO-2 2'-BITHIOPHENE 96 Spectrum

5-BROMO-2 2'-BITHIOPHENE 96(3480-11-3)¹HNMR

3480-11-3(5-BROMO-2 2'-BITHIOPHENE 96)Related Search:

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5-BROMO-2 2'-BITHIOPHENE 96 5-Bromo-[2,2']bithiophenyl 5-BroMo-2,2'-bithiophene 96% 5-Bromo-alpha-dithienyl 2,2'-Bithiophene, 5-bromo- 5-Bromo-2,2'-bithiophene USP/EP/BP 2T-Br 5-Bromo-2,2'-bithiophene 5-Bromo-2,2'-bithienyl 5-Bromo-2,2′-bithiophene, CAS 3480-11-3 3480-11-3 Building Blocks C7 to C9 Chemical Synthesis Halogenated Heterocycles Heterocyclic Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks Thiophenes ThiophenesBuilding Blocks