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Potassium ethylxanthate

CAS No.
140-89-6
Chemical Name:
Potassium ethylxanthate
Synonyms
POTASSIUM ETHYL XANTHATE;potassium O-ethyl carbonodithioate;POTASSIUM ETHYL XANTHOGENATE;POTASSIUM XANTHATE;POTASSIUM O-ETHYL DITHIOCARBONATE;KEX;POTASSIUM XANTHOGENATE;Potassium O-ethyl xanthate;potassium (ethoxymethanethioyl)sulfanide;z3
CBNumber:
CB0723237
Molecular Formula:
C3H5KOS2
Molecular Weight:
160.3
MDL Number:
MFCD00004931
MOL File:
140-89-6.mol
MSDS File:
SDS
Last updated:2026-01-13 11:13:15
Product description Number Pack Size Price
Potassium-O-ethyldithiocarbonate for synthesis 8.20744 100g $97.9
DITHIOCARBONIC ACID O-ETHYL ESTER, POTASSIUM SALT DIMER AldrichCPR R533475 1 unit $121
Potassium ethyl xanthogenate 96% 254770 5g $82.1
Potassium-O-ethyldithiocarbonate for synthesis 8.20744 500g $421
Potassium ethyl xanthogenate 96% 254770 100g $119
More product size

Potassium ethylxanthate Properties

Melting point 209-214 °C
Boiling point 462.37℃[at 101 325 Pa]
bulk density 400-600kg/m3
Density 1,558 g/cm3
vapor pressure 0Pa at 25℃
Flash point 96°C
storage temp. Store below +30°C.
solubility alcohol: soluble(lit.)
form Crystalline Powder
color Yellow
PH 9-10 (100g/l, H2O, 20℃)
Water Solubility Soluble in water.
Merck 14,7696
BRN 3596974
Stability Stable. Incompatible with strong acids, strong bases, strong oxidizing agents.
InChI 1S/C3H6OS2.K/c1-2-4-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
InChIKey JCBJVAJGLKENNC-UHFFFAOYSA-M
SMILES [K+].CCOC([S-])=S
LogP -2.24 at 25℃
CAS DataBase Reference 140-89-6(CAS DataBase Reference)
FDA UNII 1A6K3Y576K
EPA Substance Registry System Potassium ethyl xanthate (140-89-6)
UNSPSC Code 12352107
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H228-H302+H332-H315-H319-H335
Precautionary statements  P210-P240-P301+P312-P302+P352-P304+P340+P312-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,Xi,F
Risk Statements  36/37/38-22-20/22-11
Safety Statements  37/39-26-37-36-45-36/37-16
RIDADR  3342
WGK Germany  3
RTECS  FG1575000
TSCA  TSCA listed
HazardClass  4.2
PackingGroup  II
HS Code  29309090
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Sol. 1
Skin Irrit. 2
STOT SE 3
Toxicity LD50 orally in Rabbit: 1700 mg/kg
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
1
2 0

Potassium ethylxanthate price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20744 Potassium-O-ethyldithiocarbonate for synthesis 140-89-6 100g $97.9 2026-03-19 Buy
Sigma-Aldrich R533475 DITHIOCARBONIC ACID O-ETHYL ESTER, POTASSIUM SALT DIMER AldrichCPR 140-89-6 1 unit $121 2026-03-19 Buy
Sigma-Aldrich 254770 Potassium ethyl xanthogenate 96% 140-89-6 5g $82.1 2026-03-19 Buy
Sigma-Aldrich 8.20744 Potassium-O-ethyldithiocarbonate for synthesis 140-89-6 500g $421 2026-03-19 Buy
Sigma-Aldrich 254770 Potassium ethyl xanthogenate 96% 140-89-6 100g $119 2026-03-19 Buy
Product number Packaging Price Buy
8.20744 100g $97.9 Buy
R533475 1 unit $121 Buy
254770 5g $82.1 Buy
8.20744 500g $421 Buy
254770 100g $119 Buy

Potassium ethylxanthate Chemical Properties,Uses,Production

Chemical Properties

Light Green Solid

Uses

As reagent in analytical chemistry.

Uses

Potassium ethyl xanthate is used as a reagent for extraction of metal ions into organic solvents and in the preparation of 2-mercapto benzimidazoles and 2-mercapto benzoxazoles by reacting with o-phenylenediamines and o-amino phenols respectively. It acts as a precursor in the production of unsymmetrical sulfides through cross-coupling reaction and as a floatation agent in the mining industry. It is involved in the determination of cadmium in water samples by substoichiometric radiochemical method and the adsorption of colloidal dye disperse Blue 3 onto pretreated polyester fabric.

Uses

Potassium ethyl xanthogenate (ethyl potassium xanthogenate) has been used:

  • in synthesis of unsymmetrical sulfides via cross-coupling reaction, using recyclable CuO nanoparticles under ligand-free conditions
  • as surfactant to investigate the adsorption of colloidal dye Disperse Blue 3 onto pretreated polyester fabric
  • in determination of microgram amounts of cadmium in water samples by substoichiometric radiochemical method

Definition

Colorless or light-yellow crystals. Soluble in water and alcohol; insol- uble in ether.

Hazard

Toxic by ingestion.

Flammability and Explosibility

Highly flammable

Purification Methods

Crystallise it from absolute EtOH, ligroin/ethanol or acetone by adding Et2O. Wash it with ether, then dry it in a desiccator. Its solubility in Me2CO is 8% at 25o. [Beilstein 3 H 563, 3 I 196, 3 II 367, 3 III 1101, 3 IV 1274.]

Mode of action

Potassium ethylxanthate (KEtX) has long been utilized as a collector in the flotation of chalcocite (Cu2S), bornite (Cu5FeS4), chalcopyrite (CuFeS2) and galena (PbS). KEtX acts as an inhibitor of anodic corrosion of copper in acidic sodium chloride solutions. The collection efficiency of EtX ion is ascribed to its interaction with mineral surfaces, possibly through a chemisorption bond. A similar interaction of EtX ions with Pb has been found. It is interesting to note that the anodic oxidation of copper of KEtX to diethyl dixanthogen should be considered according to the following equations:
Potassium ethylxanthate
Diethyl dixanthoges does not diffuse into the bulk solution but forms a physically adsorbed layer. Interactions of EtX ions with the Cu electrode surface are first manifested by the adsorption of EtX ions, which is then followed, at higher positive potentials, by a growth of Cu(I)EtX film. On the other hand, the inhibitory effect of EtX may probably be explained on the basis of stabilizing the +1 oxidation state of copper in the film against further oxidation and an increase in the hydrophobicity of the metal surface[1].

References

[1] Scendo, M. “Potassium ethyl xanthate as corrosion inhibitor for copper in acidic chloride solutions.” Corrosion Science 47 7 (2005): Pages 1738-1749.

Global( 362)Suppliers
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Capot Chemical Co.,Ltd.
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View Lastest Price from Potassium ethylxanthate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Potassium ethylxanthate pictures 2025-06-20 Potassium ethylxanthate
140-89-6
US $0.00-0.00 / kg 1kg 0.99 100tons Hebei Yanxi Chemical Co., Ltd.
Potassium ethylxanthate pictures 2021-08-12 Potassium ethylxanthate
140-89-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Potassium ethylxanthate pictures 2021-07-13 Potassium ethylxanthate
140-89-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(o-ethyldithiocarbonato)potassium carbonicacid,dithio-,o-ethylester,potassiumsalt Carbonodithioicacid,O-ethylester,potassiumsalt dithiocarbonicacid,o-ethylester,potassiumsalt ethylpotassiumxanthate ethylpotassiumxanthogenate ethylxanthatedepotassium ethyl-xanthicacipotassiumsalt o-ethylpotassiumdithiocarbonate O-Ethylxanticacid,potassiumsalt z3 ETHYLXANTHIC ACID POTASSIUM SALT 90+% PottasiumEthylXanthate Potassium Ethyl Xanthogenate technical grade, 90% POTASSIUMETHYLXANTHATE=ETHYLPOTASSIUMXANTHOGENAT potassium O-ethyl carbonodithioate Potassium o-ethyl dithiocarbonate ,99% ETHYLXANTHIC ACID POTASSIUM SALT, 97+% Dithiocarbonic acid O-ethyl S-potassium Dithiocarbonic acid O-ethyl S-potassium salt Ethylxanthic acid potassium salt,95%,tech. Potassium Methylxanthogenate Pesticide emulsifier No.600 Ethylxanthic acid potassium salt, tech., 95% Potassium xanthogenate, reagent grade Potassium ethyl xanthogenate,O-Ethylxanthic acid potassium salt, Potassium O-ethyl dithiocarbonate, Potassium xanthogenate Potassium ethyl xant Potassium ethylxanthogenat KEX O-Ethylxanthic acid potassium salt, Potassium O-ethyl dithiocarbonate, Potassium xanthogenate ETHYLXANTHIC ACID POTASSIUM SALT O-ETHYLXANTHIC ACID, POTASSIUM SALT POTASSIUM ETHYL XANTHATE POTASSIUM ETHYL XANTHOGENATE POTASSIUM ETHYLDITHIOCARBONATE POTASSIUM XANTHATE POTASSIUM XANTHOGENATE POTASSIUM O-ETHYL DITHIOCARBONATE Potassium O-ethylxanthogenate ETHYLXANTHIC ACID POTASSIUM SALT 97% Ethylxanthic Acid Potassium Salt Potassium O-Ethyl Dithiocarbonate Potassium Xanthogenate PotassiuM ethyl xanthogena O-ethyl S-hydrogen carbonodithioate, potassiuM salt Carbonodithioic acid, O-ethyl ester, potassiuM salt (1:1) Potassium O-ethyl xanthate DITHIOCARBONIC ACID O-ETHYL ESTER, POTASSIUM SALT DIMER Potassium Xanthogenat Potassium-O-ethyldithiocarbonate for synthesis Potassium ethylxanthate/Pesticide emulsifier 600 Potassium Ethyl Xanthate 85% Powder Potassium Ethylxanthate > Potassium Ethylxanthate,85% POTASSIUM-O-ETHYLDITHIOCARBONATE FOR SYN potassium (ethoxymethanethioyl)sulfanide ethoxymethanedithioate Potassium Ethyl Xanthate (PEX) extrapure, 98% POTASSIUM ETHYL XANTHATE Extra Pure DK538