Dinocap
- CAS No.
- 39300-45-3
- Chemical Name:
- Dinocap
- Synonyms
- mildex;cr1639;DINOCAP;SIALITE;caprane;caratan;dinokap;karatan;KARATHAN;arathane
- CBNumber:
- CB0744977
- Molecular Formula:
- C18H24N2O6
- Molecular Weight:
- 364.39
- MDL Number:
- MFCD00054268
- MOL File:
- 39300-45-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Boiling point | 138-140°C |
|---|---|
| Density | 1.10 |
| refractive index | 1.5700 (estimate) |
| storage temp. | -20°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Liquid |
| Water Solubility | practically insoluble |
| Merck | 13,3316 |
| Henry's Law Constant | 2.1×103 mol/(m3Pa) at 25℃, HSDB (2015) |
| InChI | 1S/C18H24N2O6/c1-4-6-7-8-10-13(3)15-11-14(19(22)23)12-16(20(24)25)18(15)26-17(21)9-5-2/h5,9,11-13H,4,6-8,10H2,1-3H3/b9-5+ |
| InChIKey | NIOPZPCMRQGZCE-WEVVVXLNSA-N |
| SMILES | [N+](=O)([O-])c1c(c(cc(c1)[N+](=O)[O-])C(CCCCCC)C)OC(=O)\C=C\C |
| CAS DataBase Reference | 39300-45-3(CAS DataBase Reference) |
| EWG's Food Scores | 3 |
| FDA UNII | JZG115B8H5 |
| Proposition 65 List | Dinocap |
| Pesticides Freedom of Information Act (FOIA) | Dinocap |
| EPA Substance Registry System | Dinocap (39300-45-3) |
| UNSPSC Code | 41116107 |
| NACRES | NA.24 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS07,GHS08,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H302+H332-H315-H317-H360D-H373-H410 |
| Precautionary statements | P201-P261-P273-P280-P308+P313-P501 |
| Hazard Codes | T;N,N,T |
| Risk Statements | 61-20/22-38-43-48/22-50/53-22-20 |
| Safety Statements | 53-45-60-61 |
| RIDADR | UN 3082 |
| WGK Germany | WGK 3 |
| RTECS | GQ5775000 |
| HazardClass | 6.1(a) |
| PackingGroup | I |
| HS Code | 29161900 |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| Hazard Classifications | Acute Tox. 4 Inhalation Acute Tox. 4 Oral Aquatic Acute 1 Aquatic Chronic 1 Repr. 1B Skin Irrit. 2 Skin Sens. 1 STOT RE 2 |
| Hazardous Substances Data | 39300-45-3(Hazardous Substances Data) |
| Toxicity | LD50 in male rats (mg/kg): 23 i.v.; 980 orally (Larson) |
Dinocap price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | TRC-D481768-50MG | Dinocap | 39300-45-3 | 50mg | $339 | 2026-06-03 | Buy |
| TRC | TRC-D481768-25MG | Dinocap | 39300-45-3 | 25mg | $223 | 2026-06-03 | Buy |
| TRC | TRC-D481768-10MG | Dinocap | 39300-45-3 | 10mg | $116 | 2026-06-03 | Buy |
| TRC | D481768 | Dinocap | 39300-45-3 | 50mg | $250 | 2021-12-16 | Buy |
| Usbiological | 447276 | Dinocap | 39300-45-3 | 10mg | $355 | 2021-12-16 | Buy |
Dinocap Chemical Properties,Uses,Production
Description
Dinocap is shown in both the 2,4-dinitro and 2,6-dinitro configurations with 1-methylheptyl and 1-ethylhexyl chains, respectively, but may also have a 1-propylpentyl configuration for the “octyl” chain. It is a dark brown liquid with a bp = 138 to 140 C, vp = 5.3×106 mPa, a Kow LogP = 4.54, and is almost insoluble (<0.1 mgL1) in water (5).
Chemical Properties
Dinotefuran is a dark red viscous liquid with irritating odor, melting point -22.5℃, boiling point 138~140℃(0.05mmHg), it will be decomposed when it exceeds 200℃ under normal pressure. Vapor pressure 3.33×10-3 mPa(25℃), KowlgP=4.54(20℃).Henry's constant 1.36×10-3Pa- m3/mol(calculated). Relative density 1.10 (20°C). Solubility in water 0.151mg/L. Solubility in other solvents, 2,4-isomer: in acetone, 1,2-dichloroethane, ethyl acetate, n-heptane, methanol, and xylene >250g/L; 2,6-isomer: in acetone, 1,2-dichloroethane, ethyl acetate, and xylene >250g/L, n-heptane 8.5~10.2g/L, methanol 20.4~25.3g/L. Decompose rapidly at light, decompose above 32℃, stable to acid, hydrolyze ester group in alkaline environment. Flash point 67℃.
Uses
Acaricide; fungicide.
Definition
ChEBI: 2,4-dinitro-6-(octan-2-yl)phenyl (E)-but-2-enoate is an enoate ester obtained by formal condensation of the carboxy group of 3-methylacrylic acid with the phenolic hydroxy group of 2,4-dinitro-6-(octan-2-yl)phenol. It is a C-nitro compound and an enoate ester.
Production Methods
The commercial production of dinocap involves a multi-step process. It begins with the nitration of 2-(1-methylheptyl)phenol using a nitric acid-sulphuric acid mixture to introduce nitro groups at the 2 and 4 positions, forming 2,4-dinitro-6-(1-methylheptyl)phenol. This intermediate is then esterified with crotonic acid or its derivatives, typically using an acid chloride or anhydride in the presence of a base catalyst in an organic solvent under controlled temperature to yield dinocap.
General Description
Dark oily liquid. Nearly insoluble in water. Used as a fungicide and acaricide.
Air & Water Reactions
Nearly insoluble in water. Hydrolysis of the ester group occurs with alkaline pHs.
Reactivity Profile
A dinitrophenyl derivative.
Agricultural Uses
Fungicide, Acaricide: Dinocap is a foliar fungicide/miticide used to control powdery mildew. It is applied to limit mites in apples and grapes crops outside the U.S., mainly in Europe, the Middle East and northern Africa. It is also used to control powdery mildew on fruit, vegetables and ornamentals. DAS, the registrant of dinocap, intends to support tolerances for dinocap residues in/on apples and grapes to permit legal importation of these commodities into the U.S. Not approved for use in EU countries. Not currently registered in the U.S. There are 17 global suppliers.
Trade name
ACTUAL DINOCAP®; ARATHANE®; CAPRANE®; CR 1639®; CEKUCAP® 25 WP; CROTOTHANE®; DICAP®; DIKAR®; EZENOAN®; ISCOTHANE®; ISOCOTHANE®; KARATHANE®[C]; KARATHANE® WD[C]; KARATHENE®[C]; MILDANE®; MILDEX®
Mechanism of action
Contact with protective and curative action. Respiration inhibitor. Uncoupler of oxidative phosphorylation via disruption of proton gradient.
Safety Profile
Poison by ingestion and intravenous routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Questionable carcinogen with experimental neoplastigenic data. See NITRATES. When heated to decomposition it emits toxic fumes of NOx.
Toxicity evaluation
Dinocap shows moderate acute toxicity to mammals (acute oral LD50 in rats of 1,000 to 5,000 mg/kg) with moderate dermal irritation but substantial eye irritation in rabbits (Rohm & Haas MSDS C&P MSDS reference listing; MDL MSDS database listing). Dinocap is teratogenic to mice and hamsters at 10 to 100 mg/kg/day (48–51), although no evidence of teratogenic effects were seen in rabbits (Rohm & Haas MSDS C&P MSDS reference listing). Dinocap is classified as “toxic” to fish but is listed as “nontoxic” to bees (52).
Pesticide Type
Fungicide; Acaricide; Insecticide
Dinocap Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Spectrum Chemical Manufacturing Corp. | 021-021-021-67601398-809-809-809 15221380277 | marketing_china@spectrumchemical.com | China | 9643 | 60 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 | anhua.mao@aladdin-e.com | China | 29985 | 65 |
| Shanghai Meishui Chemical Technology Co., Ltd | 021-60549325 18616193163 | China | 4518 | 56 | |
| Alta Scientific Co., Ltd. | 022-6537-8550 15522853686 | sales@altasci.com.cn | China | 4508 | 55 |
| Shanghai Xilong Biochemical Technology Co., Ltd. | 021-52907766-8042 | China | 9928 | 58 | |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Shandong Ono Chemical Co., Ltd. | 0539-6362799 20） | China | 10007 | 58 |
View Lastest Price from Dinocap manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-02-13 | Dinocap
39300-45-3
|
$10.00 | 1KG | 99% | 50MT | Hebei baicao biology science and technology co., ltd | |
 |
2021-08-12 | Dinocap
39300-45-3
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2019-12-26 | Dinocap
39300-45-3
|
$1.00 | 1KG | ≥98% | Career Henan Chemical Co |
