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(+)-Chloromethyl menthyl ether

CAS No.
103128-76-3
Chemical Name:
(+)-Chloromethyl menthyl ether
Synonyms
(+)-Chloromethyl menthyl ether;(+)-Chloromethyl menthyl ether, 97% ee;(1R,2S,4S)-2-(chloromethoxy)-1-isopropyl-4-methyl-cyclohexane;(1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE;Cyclohexane, 2-(chloromethoxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)-
CBNumber:
CB0771672
Molecular Formula:
C11H21ClO
Molecular Weight:
204.74
MDL Number:
MFCD09039273
MOL File:
103128-76-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:48:29

(+)-Chloromethyl menthyl ether Properties

Boiling point 72 °C/0.4 mmHg (lit.)
Density 0.994 g/mL at 25 °C (lit.)
refractive index n20/D 1.467(lit.)
Flash point 225 °F
storage temp. -20°C
form liquid
Appearance Colorless to light yellow Liquid
optical activity [α]24/D +181.0°, c = 2 in methylene chloride
InChI 1S/C11H21ClO/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h8-11H,4-7H2,1-3H3/t9-,10+,11-/m0/s1
InChIKey XOPLTFUYFXWFGB-AXFHLTTASA-N
SMILES CC(C)[C@H]1CC[C@H](C)C[C@@H]1OCCl
CAS DataBase Reference 103128-76-3
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 1

(+)-Chloromethyl menthyl ether price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 349925 (+)-Chloromethyl menthyl ether 97% 103128-76-3 5g $187 2026-04-30 Buy
Chem-Impex 41371 (+)-Chloromethyl menthyl ether ≥97.5%(Chiralpurity) 103128-76-3 1G $90 2026-05-19 Buy
Chem-Impex 41371 (+)-Chloromethyl menthyl ether ≥97.5%(Chiralpurity) 103128-76-3 5G $360 2026-05-19 Buy
aablocks AA003B9Q (1R,2S,4S)-2-(Chloromethoxy)-1-isopropyl-4-methylcyclohexane 85% 103128-76-3 100mg $109 2026-05-28 Buy
aablocks AA003B9Q (1R,2S,4S)-2-(Chloromethoxy)-1-isopropyl-4-methylcyclohexane 85% 103128-76-3 250mg $183 2026-05-28 Buy
Product number Packaging Price Buy
349925 5g $187 Buy
41371 1G $90 Buy
41371 5G $360 Buy
AA003B9Q 100mg $109 Buy
AA003B9Q 250mg $183 Buy

(+)-Chloromethyl menthyl ether Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

(+)-Chloromethyl menthyl ether can be used:

  • As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
  • As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
  • To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;5- C2H5)(PPh3)COCH3].

(+)-Chloromethyl menthyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-Chloromethyl menthyl ether Suppliers

Global( 20)Suppliers
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Birdo (Shanghai) Medical Technology Co., Ltd. 021-58099077-8041 18601625411 sales@birdotech.com China 9379 58
Taizhou Nanfeng Pharmaceutical Research Institute nanfengpharma@126.co 18616377689 nanfengpharma@126.com China 20008 58
Shanghai Haohong Pharmaceutical Co., Ltd. 400-8210725 4008210725 malulu@leyan.com China 54996 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. 6206333 13167063860 anhua.mao@aladdin-e.com China 43379 58
Jiangsu Aikon Biopharmaceutical R&D Co.,Ltd. 025-66061636 19370895928 qqyang@aikonchem.com China 9995 58
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21533 55
Aladdin Scientific tp@aladdinsci.com United States 50089 58
(1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE (+)-Chloromethyl menthyl ether, 97% ee Cyclohexane, 2-(chloromethoxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)- (1R,2S,4S)-2-(chloromethoxy)-1-isopropyl-4-methyl-cyclohexane (+)-Chloromethyl menthyl ether 103128-76-3 Ethers Organic Building Blocks Chiral Building Blocks Asymmetric Synthesis Chiral Building Blocks Ethers Organic Building Blocks