Methyl 2-bromo-6-methylbenzoate
- CAS No.
- 99548-56-8
- Chemical Name:
- Methyl 2-bromo-6-methylbenzoate
- Synonyms
- Methyl 2-bromo-6-methylbenzoate;2-BROMO-6-METHYLBENZOIC ACID METHYL ESTER;Benzoic acid, 2-broMo-6-Methyl-, Methyl ester;Methyl 6-bromo-o-toluate, 3-Bromo-2-(methoxycarbonyl)toluene
- CBNumber:
- CB11484363
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD09260938
- MOL File:
- 99548-56-8.mol
- MSDS File:
- SDS
| Boiling point | 141 °C(Press: 21 Torr) |
|---|---|
| Density | 1.433±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| Appearance | Colorless to light yellow Liquid |
| InChI | InChI=1S/C9H9BrO2/c1-6-4-3-5-7(10)8(6)9(11)12-2/h3-5H,1-2H3 |
| InChIKey | DDJSNWUTQDNGIZ-UHFFFAOYSA-N |
| SMILES | C(OC)(=O)C1=C(C)C=CC=C1Br |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H335 |
| Precautionary statements | P280 |
| HS Code | 2916399090 |
Methyl 2-bromo-6-methylbenzoate price More Price(41)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Activate Scientific | AS33561 | Methyl 2-bromo-6-methylbenzoate 98% | 99548-56-8 | 1g | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR17046 | Methyl 2-bromo-6-methylbenzoate >97% | 99548-56-8 | 5g | $21 | 2026-06-04 | Buy |
| Activate Scientific | AS33561 | Methyl 2-bromo-6-methylbenzoate 98% | 99548-56-8 | 5g | $34 | 2026-06-04 | Buy |
| Apolloscientific | OR17046 | Methyl 2-bromo-6-methylbenzoate >97% | 99548-56-8 | 25g | $96 | 2026-06-04 | Buy |
| Activate Scientific | AS33561 | Methyl 2-bromo-6-methylbenzoate 98% | 99548-56-8 | 25g | $77 | 2026-06-04 | Buy |
Methyl 2-bromo-6-methylbenzoate Chemical Properties, Uses, Production
Synthesis
67-56-1
90259-31-7
99548-56-8
To a dichloromethane (50 mL) suspension of 2-bromo-6-methylbenzoic acid (5.05 g, 23.48 mmol) was sequentially added oxalyl chloride (2.67 mg, 30.5 mmol) and N,N-dimethylformamide (DMF, 2 drops) at room temperature. The reaction mixture was stirred at room temperature for 2 hours and then concentrated under reduced pressure to remove the solvent. Methanol (10 mL) was added to the resulting residue and stirring was continued overnight. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure. To the concentrated residue was added saturated aqueous sodium bicarbonate (20 mL) and the mixture was extracted with ethyl acetate. The organic layer was dried with anhydrous magnesium sulfate and the solvent was removed under reduced pressure. The resulting methyl 2-bromo-6-methylbenzoate (5.04 g, 94% yield) was used directly in the subsequent reaction without further purification.
References
[1] Patent: EP2455370, 2012, A1. Location in patent: Page/Page column 101
[2] Patent: WO2007/47646, 2007, A2. Location in patent: Page/Page column 52
Methyl 2-bromo-6-methylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Changzhou Kechem Bio-Scientific Co., LTD. | 0519-68985668 13685222090 | sales@kechem.cn | China | 26012 | 58 |
| WUXI SHUANGQI TECHNOLOGY CO LTD. | 0510-86529556 18114865355 | 1702606491@qq.com | China | 1104 | 58 |
| Xi 'an billiton biological technology co., LTD | 029-88764766 | wang.yali@xatuochao.com | China | 521 | 58 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Harvest Chemical Industrial Co., Ltd. | 15721252604 17321035817 | sales@harvest-chem.com | China | 2829 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Shanghai Sunway Pharmaceutical Technology Co., Ltd | 13761987713 | hxzheng@sunwaypharm.cn | China | 8663 | 57 |
| Shanghai Topbiochem Technology Co., Ltd | 021-58170097 | info@topbiochem.com | China | 9509 | 58 |
| Shanghai Topbiochem Technology Co., Ltd | +86-21-60341587 | sales@topbiochem.com | China | 6166 | 58 |
View Latest Price from Methyl 2-bromo-6-methylbenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-19 | Methyl 2-bromo-6-methylbenzoate
99548-56-8
|
1KG | 98% | 1000 KG | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2021-07-13 | Methyl 2-bromo-6-methylbenzoate
99548-56-8
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2021-07-10 | Methyl 2-bromo-6-methylbenzoate
99548-56-8
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- Methyl 2-bromo-6-methylbenzoate
99548-56-8
- $0.00
- 98%
- Shaanxi Dideu New Materials Co. Ltd
-
- Methyl 2-bromo-6-methylbenzoate
99548-56-8
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- Methyl 2-bromo-6-methylbenzoate
99548-56-8
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
