Methyl 2-bromo-6-methylbenzoate
- CAS No.
- 99548-56-8
- Chemical Name:
- Methyl 2-bromo-6-methylbenzoate
- Synonyms
- Methyl 2-bromo-6-methylbenzoate;2-BROMO-6-METHYLBENZOIC ACID METHYL ESTER;Benzoic acid, 2-broMo-6-Methyl-, Methyl ester;Methyl 6-bromo-o-toluate, 3-Bromo-2-(methoxycarbonyl)toluene
- CBNumber:
- CB11484363
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD09260938
- MOL File:
- 99548-56-8.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl2-Bromo-6-methylbenzoate | M295843 | 5g | $145 |
| Methyl2-bromo-6-methylbenzoate ≥98.0% | CS-W004694 | 10g | $69 |
| 2-Bromo-6-methylbenzoic acid methyl ester | FB66994 | 10g | $75 |
| Methyl2-bromo-6-methylbenzoate ≥98.0% | CS-W004694 | 25g | $123 |
| 2-Bromo-6-methylbenzoic acid methyl ester | FB66994 | 25g | $125 |
| More product size | |||
| Boiling point | 141 °C(Press: 21 Torr) |
|---|---|
| Density | 1.433±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| Appearance | Colorless to light yellow Liquid |
| InChI | InChI=1S/C9H9BrO2/c1-6-4-3-5-7(10)8(6)9(11)12-2/h3-5H,1-2H3 |
| InChIKey | DDJSNWUTQDNGIZ-UHFFFAOYSA-N |
| SMILES | C(OC)(=O)C1=C(C)C=CC=C1Br |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H335 |
| Precautionary statements | P280 |
| HS Code | 2916399090 |
Methyl 2-bromo-6-methylbenzoate price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M295843 | Methyl2-Bromo-6-methylbenzoate | 99548-56-8 | 5g | $145 | 2021-12-16 | Buy |
| ChemScene | CS-W004694 | Methyl2-bromo-6-methylbenzoate ≥98.0% | 99548-56-8 | 10g | $69 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB66994 | 2-Bromo-6-methylbenzoic acid methyl ester | 99548-56-8 | 10g | $75 | 2021-12-16 | Buy |
| ChemScene | CS-W004694 | Methyl2-bromo-6-methylbenzoate ≥98.0% | 99548-56-8 | 25g | $123 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB66994 | 2-Bromo-6-methylbenzoic acid methyl ester | 99548-56-8 | 25g | $125 | 2021-12-16 | Buy |
Methyl 2-bromo-6-methylbenzoate Chemical Properties,Uses,Production
Synthesis
67-56-1
90259-31-7
99548-56-8
To a dichloromethane (50 mL) suspension of 2-bromo-6-methylbenzoic acid (5.05 g, 23.48 mmol) was sequentially added oxalyl chloride (2.67 mg, 30.5 mmol) and N,N-dimethylformamide (DMF, 2 drops) at room temperature. The reaction mixture was stirred at room temperature for 2 hours and then concentrated under reduced pressure to remove the solvent. Methanol (10 mL) was added to the resulting residue and stirring was continued overnight. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure. To the concentrated residue was added saturated aqueous sodium bicarbonate (20 mL) and the mixture was extracted with ethyl acetate. The organic layer was dried with anhydrous magnesium sulfate and the solvent was removed under reduced pressure. The resulting methyl 2-bromo-6-methylbenzoate (5.04 g, 94% yield) was used directly in the subsequent reaction without further purification.
References
[1] Patent: EP2455370, 2012, A1. Location in patent: Page/Page column 101
[2] Patent: WO2007/47646, 2007, A2. Location in patent: Page/Page column 52
Methyl 2-bromo-6-methylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29640 | 60 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29821 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10000 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 9546 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
View Lastest Price from Methyl 2-bromo-6-methylbenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2021-07-13 | Methyl 2-bromo-6-methylbenzoate
99548-56-8
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2021-07-10 | Methyl 2-bromo-6-methylbenzoate
99548-56-8
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2019-07-14 | Methyl 2-bromo-6-methylbenzoate
99548-56-8
|
US $1.00 / KG | 1KG | 99% | 100kg | Career Henan Chemical Co |
-
- Methyl 2-bromo-6-methylbenzoate
99548-56-8
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- Methyl 2-bromo-6-methylbenzoate
99548-56-8
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- Methyl 2-bromo-6-methylbenzoate
99548-56-8
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
