N-(Phenylthio)phthalimide
- CAS No.
- 14204-27-4
- Chemical Name:
- N-(Phenylthio)phthalimide
- Synonyms
- 2-(Phenylthio)isoindoline-1,3-dione;N-(Phenylthio)phthalimide;N-(Phenylthio)phthalimide>N-(Phenylthio)phthalimide;2-(Phenylthio)-1,3-isoindolinedione;2-(Phenylthio)-1H-isoindol-1,3(2H)-dione;2-(Phenylthio)-1H-isoindole-1,3(2H)-dione;1H-Isoindole-1,3(2H)-dione, 2-(phenylthio)-
- CBNumber:
- CB1240906
- Molecular Formula:
- C14H9NO2S
- Molecular Weight:
- 255.29
- MDL Number:
- MFCD00192396
- MOL File:
- 14204-27-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 160-163 °C(lit.) |
|---|---|
| Boiling point | 432.2±28.0 °C(Predicted) |
| Density | 1.42±0.1 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | DMSO: soluble25mg/mL, clear, yellow |
| pka | -3.05±0.20(Predicted) |
| form | powder to crystal |
| color | White to Light yellow |
| CAS DataBase Reference | 14204-27-4 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| Safety Statements | 24/25 |
| WGK Germany | 3 |
| HS Code | 29309090 |
N-(Phenylthio)phthalimide price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | P1254 | N-(Phenylthio)phthalimide >98.0%(GC)(N) | 14204-27-4 | 5g | $113 | 2026-04-30 | Buy |
| TCI Chemical | P1254 | N-(Phenylthio)phthalimide >98.0%(GC)(N) | 14204-27-4 | 25g | $448 | 2026-04-30 | Buy |
| Usbiological | 288370 | N-(Phenylthio)phthalimide Asreported | 14204-27-4 | 2g | $317 | 2026-06-03 | Buy |
| Usbiological | 288370 | N-(Phenylthio)phthalimide Asreported | 14204-27-4 | 5g | $456 | 2026-06-03 | Buy |
| Usbiological | 288370 | N-(Phenylthio)phthalimide Asreported | 14204-27-4 | 10g | $629 | 2026-06-03 | Buy |
N-(Phenylthio)phthalimide Chemical Properties, Uses, Production
Uses
Used as a mild sulfenylating reagent.
Preparation
N-(Phenylthio)phthalimide is prepared by reaction of Benzenesulfenyl Chloride with Phthalimide in the presence of Triethylamine.
Preparation
(a) Preparation of benzenesulfenyl chloride. To a stirred solution of 55 gm (0.5 mole) of benzene thiol in 300 ml of η -pentane at 0°C is added chlorine gas until an assay (GC) of the resulting red-orange solution shows quantitative conversion to the sulfenyl chloride. The reaction usually requires about 39 gm (0.6 mole) of chlorine.
(b) Reaction of benzenesulfenyl chloride with phthalimide. To a stirred solution of 73.5 gm (0.5 mole) of phthalimide in 200 ml of dimethylforma-mide is first added 60 gm (0.6 mole) of triethylamine. Then the sulfenyl chloride solution from (a) is slowly added dropwise. The reaction mixture is stirred for \ hr, poured into 2 liters of cold water, filtered, and dried to afford 121 gm (95%), m.p. 160-161°C (recrystallized from ethanol).
Complex imides such as camphorimide and 9,10-dihydroanthracene-9,10-endo-a,/3-succinimide have been alkylated in methylene dichloride with alkyl halides, using tetrabutylammonium bromide as a phase-transfer catalyst and aqueous potassium hydroxide as a base.
N-(Phenylthio)phthalimide Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Beijing Donghualituo Techonlogy Development Co.,Ltd. | 010-88425576 | sales@dhltchem.com | China | 793 | 59 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Carbott PharmTech Inc. | 0535-6385396 | info@carbottpharm.com | China | 996 | 56 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
