ChemicalBook >> CAS DataBase List >>5-broMo-2,4-diMethyl-pyriMidine

5-broMo-2,4-diMethyl-pyriMidine

CAS No.
69696-37-3
Chemical Name:
5-broMo-2,4-diMethyl-pyriMidine
Synonyms
5-broMo-2,4-diMethyl-pyriMidine;Pyrimidine, 5-bromo-2,4-dimethyl-
CBNumber:
CB12642830
Molecular Formula:
C6H7BrN2
Molecular Weight:
187.04
MDL Number:
MFCD13705449
MOL File:
69696-37-3.mol
MSDS File:
SDS
Last updated:2026-05-27 23:21:36
Product description Number Pack Size Price
5-Bromo-2,4-dimethylpyrimidine UCA69637 250mg $342.5
5-Bromo-2,4-dimethylpyrimidine UCA69637 2.5g $1091.5
5-Bromo-2,4-dimethylpyrimidine 98% AS41921 250mg $211
5-Bromo-2,4-dimethylpyrimidine 98% AS41921 1g $452
5-Bromo-2,4-dimethylpyrimidine 293633 100.00mg $130

5-broMo-2,4-diMethyl-pyriMidine Properties

Melting point 136-137 °C
Boiling point 78-81 °C(Press: 18 Torr)
Density 1.500±0.06 g/cm3(Predicted)
storage temp. 2-8°C
pka 0.96±0.29(Predicted)
Appearance Off-white to light yellow Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319-H302
Precautionary statements  P264-P270-P301+P312-P330-P501-P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362

5-broMo-2,4-diMethyl-pyriMidine price More Price(46)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth UCA69637 5-Bromo-2,4-dimethylpyrimidine 69696-37-3 250mg $342.5 2026-06-05 Buy
Biosynth UCA69637 5-Bromo-2,4-dimethylpyrimidine 69696-37-3 2.5g $1091.5 2026-06-05 Buy
Activate Scientific AS41921 5-Bromo-2,4-dimethylpyrimidine 98% 69696-37-3 250mg $211 2026-06-04 Buy
Activate Scientific AS41921 5-Bromo-2,4-dimethylpyrimidine 98% 69696-37-3 1g $452 2026-06-04 Buy
Matrix Scientific 293633 5-Bromo-2,4-dimethylpyrimidine 69696-37-3 100.00mg $130 2026-05-19 Buy
Product number Packaging Price Buy
UCA69637 250mg $342.5 Buy
UCA69637 2.5g $1091.5 Buy
AS41921 250mg $211 Buy
AS41921 1g $452 Buy
293633 100.00mg $130 Buy

5-broMo-2,4-diMethyl-pyriMidine Chemical Properties,Uses,Production

Synthesis

5-Bromo-4-chloro-2,6-dimethylpyrimidine

69696-35-1

5-broMo-2,4-diMethyl-pyriMidine

69696-37-3

c) Synthesis of 5-bromo-2,4-dimethylpyrimidine. A mixture of 5-bromo-4-chloro-2,6-dimethylpyrimidine (2.73 g, 12.33 mmol), 4-methylbenzenesulfonylhydrazine (4.19 mL, 37.0 mmol) and chloroform (40 mL) was heated and refluxed for 16 hr at 90 °C. Upon completion of the reaction, the mixture was cooled to room temperature, the solid product was collected by filtration and washed with chloroform. The resulting solid (4.75 g) was confirmed as the expected intermediate by LC-MS analysis. Subsequently, the intermediate was mixed with 0.94 M aqueous sodium carbonate solution (40 mL, 37.7 mmol) and heated and stirred at 90 °C for 1.5 hours. After the reaction mixture was cooled, it was extracted three times with ethyl acetate, the organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to afford the title compound, 5-bromo-2,4-dimethylpyrimidine (1.17 g, 51% yield), as a tan oil, which was crystallized after standing. LC-MS (ES+) m/z: 187 [M + H]+.

References

[1] Synthesis, 1984, # 3, p. 252 - 254
[2] Patent: WO2013/96151, 2013, A1. Location in patent: Page/Page column 131
[3] Patent: US2016/176882, 2016, A1
[4] Patent: WO2017/221092, 2017, A1
[5] Patent: WO2017/221100, 2017, A1

5-broMo-2,4-diMethyl-pyriMidine Preparation Products And Raw materials

5-broMo-2,4-diMethyl-pyriMidine Suppliers

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5-broMo-2,4-diMethyl-pyriMidine Spectrum

5-broMo-2,4-diMethyl-pyriMidine Pyrimidine, 5-bromo-2,4-dimethyl- 69696-37-3