4-(MethoxyMethoxy)benzoicacid
- CAS No.
- 25458-44-0
- Chemical Name:
- 4-(MethoxyMethoxy)benzoicacid
- Synonyms
- 4-(MethoxyMethoxy)benzoic;4-(MethoxyMethoxy)benzoicacid;Benzoic acid, 4-(methoxymethoxy)-
- CBNumber:
- CB12696378
- Molecular Formula:
- C9H10O4
- Molecular Weight:
- 182.17
- MDL Number:
- MFCD21101751
- MOL File:
- 25458-44-0.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-(Methoxymethoxy)benzoic acid AldrichCPR | CBR02123 | 1 g | $191 |
| 4-(Methoxymethoxy)benzoic acid | ABA45844 | 10g | $500 |
| 4-(Methoxymethoxy)benzoic acid 98% | OR961500 | 250mg | $21 |
| 4-(Methoxymethoxy)benzoic acid 98% | OR961500 | 1g | $24 |
| 4-(Methoxymethoxy)benzoic acid 98% | OR961500 | 5g | $56 |
| Melting point | 70-71 °C |
|---|---|
| Boiling point | 320.2±22.0 °C(Predicted) |
| Density | 1.223±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| pka | 4.34±0.10(Predicted) |
| form | solid |
| Appearance | White to off-white Solid |
| InChI | InChI=1S/C9H10O4/c1-12-6-13-8-4-2-7(3-5-8)9(10)11/h2-5H,6H2,1H3,(H,10,11) |
| InChIKey | XIFRBTZCMICRPL-UHFFFAOYSA-N |
| SMILES | C(O)(=O)C1=CC=C(OCOC)C=C1 |
| UNSPSC Code | 12352106 |
| NACRES | NA.21 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| Risk Statements | 36 |
| Safety Statements | 26 |
| WGK Germany | WGK 3 |
| HS Code | 2918999090 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral Eye Irrit. 2 |
4-(MethoxyMethoxy)benzoicacid price More Price(37)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | CBR02123 | 4-(Methoxymethoxy)benzoic acid AldrichCPR | 1 g | $191 | 2026-04-30 | Buy | |
| Biosynth | ABA45844 | 4-(Methoxymethoxy)benzoic acid | 25458-44-0 | 10g | $500 | 2026-06-04 | Buy |
| Apolloscientific | OR961500 | 4-(Methoxymethoxy)benzoic acid 98% | 25458-44-0 | 250mg | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR961500 | 4-(Methoxymethoxy)benzoic acid 98% | 25458-44-0 | 1g | $24 | 2026-06-04 | Buy |
| Apolloscientific | OR961500 | 4-(Methoxymethoxy)benzoic acid 98% | 25458-44-0 | 5g | $56 | 2026-06-04 | Buy |
4-(MethoxyMethoxy)benzoicacid Chemical Properties,Uses,Production
Synthesis
107-30-2
99-96-7
25458-44-0
4-Hydroxybenzoic acid (2.00 g, 14.5 mmol) was suspended in dichloromethane (50 mL) and diisopropylethylamine (10.1 mL, 57.9 mmol) and chloromethylmethyl ether (2.20 mL, 29.0 mmol) were added sequentially under ice bath cooling. The reaction mixture was gradually warmed to room temperature with continuous stirring for 2.5 hours. Under ice bath cooling again, chloromethyl methyl ether (1.10 mL, 14.5 mmol) was added to the reaction mixture, followed by stirring at room temperature for 17 hours. After completion of the reaction, the solvent was removed by concentration under reduced pressure and methanol (50 mL) and 4 mol/L aqueous potassium hydroxide (50 mL) were added to the residue and stirred at room temperature for 3 hours. The solvent was again concentrated under reduced pressure to remove the solvent, and the residue was acidified with 4 mol/L hydrochloric acid, diluted with water and extracted with ethyl acetate. The organic phase was washed with saturated brine and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give white solid 4-(methoxymethyl)benzoic acid (2.63 g, 100% yield). The product was detected by ESI-MS showing m/z: 181 [M-H] ; 1H-NMR (CDCl3) δ (ppm): 3.37 (s, 3H), 5.26 (s, 2H), 7.00-7.16 (m, 2H), 7.80-7.96 (m, 2H), 12.65 (br s, 1H).
References
[1] Patent: EP2108642, 2009, A1. Location in patent: Page/Page column 122
[2] Patent: CN105593204, 2016, A. Location in patent: Paragraph 0352; 0353
[3] Patent: US2016/200662, 2016, A1. Location in patent: Paragraph 0232
[4] Patent: TWI557105, 2016, B. Location in patent: Paragraph 0237
4-(MethoxyMethoxy)benzoicacid Preparation Products And Raw materials
4-(MethoxyMethoxy)benzoicacid Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Changzhou Guiding Bio-Tech. Co.,Ltd. | +86-519-519-86686860 +86-18795626222 | ning@guiding-bio.com | China | 299 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 +8619957148339 | market18@leapchem.com | China | 24569 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49709 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52906 | 58 | |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
| Shanghai potentpharm CO.,Ltd | 13524892556 | sales-cn@potentpharm.com | China | 1011 | 55 |
| Jiaxing Deyi Chemical Co., Ltd. | 86-0573-85866609 13325730825 | 945717149@qq.com | China | 9241 | 58 |
| Shanghai Jizhi Biochemical Technology Co. Ltd. | 021-4009004166/18616739031 18616739031 | 3007523370@qq.com | China | 52641 | 58 |
| Shanghai Kaiwei Chemical Technology Co., Ltd. | 021-58461859 15821823057 | service@aiviche.com | China | 49299 | 58 |
View Lastest Price from 4-(MethoxyMethoxy)benzoicacid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2022-06-02 | 4-(methoxymethoxy)benzoic acid
25458-44-0
|
1kg | 98.0% | 100kg | Changzhou Guiding Bio-Tech. Co.,Ltd. |
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- 4-(methoxymethoxy)benzoic acid
25458-44-0
- 98.0%
- Changzhou Guiding Bio-Tech. Co.,Ltd.
