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CHLOROTRIBENZYLSILANE

CAS No.
18740-59-5
Chemical Name:
CHLOROTRIBENZYLSILANE
Synonyms
CHLOROTRIBENZYLSILANE;TRIBENZYL CHLOROSILANE;TRIBENZYLSILYL CHLORIDE;tribenzylchlorosilicane;Tribenzylchlorosilane 97%;chlorotris(phenylmethyl)-silan;Chlorotris(phenylmethyl)silane;Tribenzylchlorosilane, Tribenzylsilyl chloride;Benzene, 1,1',1''-[(chlorosilylidyne)tris(methylene)]tris-
CBNumber:
CB1337305
Molecular Formula:
C21H21ClSi
Molecular Weight:
336.93
MDL Number:
MFCD00004768
MOL File:
18740-59-5.mol
MSDS File:
SDS
Last updated:2026-05-27 23:36:05
Product description Number Pack Size Price
1,1′,1′′-[(Chlorosilylidyne)tris(methylene)]tris[benzene] AA007RV1 1g $1076
1,1′,1′′-[(Chlorosilylidyne)tris(methylene)]tris[benzene] AA007RV1 5g $3028
CHLOROTRIBENZYLSILANE 95.00% ORS0000867 5G $1292.18
More product size

CHLOROTRIBENZYLSILANE Properties

Melting point 139-142 °C(lit.)
Boiling point 437.9±14.0 °C(Predicted)
Density 1.096±0.06 g/cm3(Predicted)
solubility sparingly sol cold petroleum ether; moderately sol hot petroleum ether; sol ether.
FDA UNII VQR444HU54
EPA Substance Registry System Silane, chlorotris(phenylmethyl)- (18740-59-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P305+P351+P338-P310
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
TSCA  TSCA listed
HazardClass  8
PackingGroup  II

CHLOROTRIBENZYLSILANE price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
aablocks AA007RV1 1,1′,1′′-[(Chlorosilylidyne)tris(methylene)]tris[benzene] 18740-59-5 1g $1076 2026-05-28 Buy
aablocks AA007RV1 1,1′,1′′-[(Chlorosilylidyne)tris(methylene)]tris[benzene] 18740-59-5 5g $3028 2026-05-28 Buy
American Custom Chemicals Corporation ORS0000867 CHLOROTRIBENZYLSILANE 95.00% 18740-59-5 5G $1292.18 2021-12-16 Buy
Product number Packaging Price Buy
AA007RV1 1g $1076 Buy
AA007RV1 5g $3028 Buy
ORS0000867 5G $1292.18 Buy

CHLOROTRIBENZYLSILANE Chemical Properties,Uses,Production

Physical properties

mp 141–142 °C;1,2 a somewhat higher value (143–145 °C) is cited in the Aldrich catalog.

Uses

Tribenzylchlorosilane is widely used as reagent for alcohol protection.

Preparation

It is prepared by reaction of benzylmagnesium chloride with SiCl4 in ether; separation from mono- and dibenzylated chlorosilane byproducts is then accomplished by fractional distillation (boiling range 300–360 °C/100 mmHg). Other preparations involve the chlorination of tribenzylsilane using Cl2 or an acyl chloride. No yields are reported for any of the above preparative procedures.

Purification Methods

It is recrystallised three times from pet ether (in slender colourless needles, m 141o). It is sparingly soluble in pet ether but is soluble in Et2O. It does not fume in moist air but is decomposed by H2O to give tribenzyl silanol m 106o (from pet ether). [Robinson & Kipping J Chem Soc 93 439 1908, Jenkins & Post J Org Chem 15 556 1950, Beilstein 16 H 906, 16 IV 1498.]

CHLOROTRIBENZYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 32)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Co-Formula Material Tech Co., Ltd.
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BeiJing Hwrk Chemicals Limted 0757-86329057 18934348241 sales4.gd@hwrkchemical.com China 14063 55
Shanghai Gileader Advanced Material Technology Co.,Ltd 18516111942 823898732@qq.com China 1312 56

View Lastest Price from CHLOROTRIBENZYLSILANE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
tribenzyl(chloro)silane pictures 2025-07-02 tribenzyl(chloro)silane
18740-59-5
1KG 98.00% 1000KG /month Shanghai Daken Advanced Materials Co.,Ltd
CHLOROTRIBENZYLSILANE TRIBENZYL CHLOROSILANE TRIBENZYLSILYL CHLORIDE chlorotris(phenylmethyl)-silan Tribenzylchlorosilane, Tribenzylsilyl chloride Chlorotris(phenylmethyl)silane tribenzylchlorosilicane Tribenzylchlorosilane 97% Benzene, 1,1',1''-[(chlorosilylidyne)tris(methylene)]tris- 18740-59-5 C21H21ClSi C6H5CH23SiCl Synthetic Reagents Silicon-Based Protection and Derivatization Protecting and Derivatizing Reagents