Phenylselenyl bromide
- CAS No.
- 34837-55-3
- Chemical Name:
- Phenylselenyl bromide
- Synonyms
- phenyl hypobroMoselenoite;PHENYLSELENENYL BROMIDE;bromoselenobenzene;Phenylbromoselenium;Phenylbromo selenide;Phenylseleno bromide;Phenylselenyl bromide;BENZENESELENYL BROMIDE;Phenylselenium bromide;phenylselenohypobromite
- CBNumber:
- CB1360840
- Molecular Formula:
- C6H5BrSe
- Molecular Weight:
- 235.97
- MDL Number:
- MFCD00000047
- MOL File:
- 34837-55-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 58-62 °C (lit.) |
|---|---|
| Boiling point | 107-108 °C/15 mmHg (lit.) |
| Flash point | 107-108°C/15mm |
| storage temp. | 2-8°C |
| solubility | Soluble in toluene, very faint turbidity. |
| form | solid |
| color | Orange to Brown to Dark purple |
| Odor | unpleasant smell. |
| Sensitive | Moisture Sensitive |
| BRN | 2039772 |
| Exposure limits |
ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 |
| InChI | InChI=1S/C6H5BrSe/c7-8-6-4-2-1-3-5-6/h1-5H |
| InChIKey | LCEFEIBEOBPPSJ-UHFFFAOYSA-N |
| SMILES | [Se](C1=CC=CC=C1)Br |
| CAS DataBase Reference | 34837-55-3(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H290-H301+H331-H373-H410 | |||||||||
| Precautionary statements | P234-P260-P273-P301+P310-P304+P340+P311-P314 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 23/25-33-50/53 | |||||||||
| Safety Statements | 20/21-28-45-60-61 | |||||||||
| RIDADR | UN 2928 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials |
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| Hazard Classifications | Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 1 Met. Corr. 1 STOT RE 2 |
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| NFPA 704 |
|
Phenylselenyl bromide price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 243965 | Phenylselenyl bromide 98% | 34837-55-3 | 5g | $116 | 2026-04-30 | Buy |
| Sigma-Aldrich | 243965 | Phenylselenyl bromide 98% | 34837-55-3 | 25g | $314 | 2026-04-30 | Buy |
| TCI Chemical | P1322 | Phenylselenenyl Bromide >97.0%(T) | 34837-55-3 | 5g | $147 | 2026-04-30 | Buy |
| TCI Chemical | P1322 | Phenylselenenyl Bromide >97.0%(T) | 34837-55-3 | 25g | $505 | 2026-04-30 | Buy |
| TRC | TRC-P336825-5G | Phenylselenyl Bromide | 34837-55-3 | 5g | $294 | 2026-06-03 | Buy |
Phenylselenyl bromide Chemical Properties,Uses,Production
Chemical Properties
dark brownish to black crystals
Uses
Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.
Synthesis
Phenylselenyl Bromide can be quantitatively prepared in situ by treatment of Diphenyl Diselenide with an equimolar amount of Bromine.
Purification Methods
Distil it in a vacuum, recrystallise it from pet ether, CHCl3 (EtOH free), or Et2O (cooling mixture) to give dark red or orange crystals. These sublime at 25o/0.001mm [Behaghel et al. Chem Ber 65 815 1932, Pitteloud & Petrzilka Helv Chim Acta 62 1319 1979]. [Beilstein 6 III 1111.] HIGHLY TOXIC.
Phenylselenyl bromide Preparation Products And Raw materials
Phenylselenyl bromide Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd | 0431-80514535 19917294565 | et@chemextension.com | China | 5061 | 58 |
| Chongqing Botao Biotechnology Co., LTD | 15223382610 | danny@chemdad.com | China | 2034 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9963 | 60 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
View Lastest Price from Phenylselenyl bromide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-10 | Phenylselenyl bromide
34837-55-3
|
$9.80 | 1KG | ≥98% | 20 tons | Career Henan Chemical Co |
-
- Phenylselenyl bromide
34837-55-3
- $9.80
- ≥98%
- Career Henan Chemical Co
