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2-BROMO-6-METHYL-4-NITROANILINE

2-BROMO-6-METHYL-4-NITROANILINE structure

CAS No.: 102170-56-9

Chemical Name:: 2-BROMO-6-METHYL-4-NITROANILINE

Synonyms: 6-Bromo-2-methyl-4-nitroaniline;2-Methyl-4-nitro-6-bromoaniline;2-BROMO-6-METHYL-4-NITROANILINE;2-Bromo-6-methyl-4-nitroaniline,98%;2-BROMO-6-METHYL-4-NITROANILINE 98%;2-Bromo-6-methyl-4-nitrobenzenamine;2-BroMo-6-Methyl-4-nitro-phenylaMine;Benzenamine, 2-bromo-6-methyl-4-nitro-;2-BROMO-6-METHYL-4-NITROANILINE ISO 9001：2015 REACH

CBNumber:: CB1709674

Molecular Formula:: C7H7BrN2O2

Molecular Weight:: 231.05

MDL Number:: MFCD00053089

MOL File:: 102170-56-9.mol

MSDS File:: SDS

Last updated:2026-05-27 23:43:04

Product description	Number	Pack Size	Price
2-Bromo-6-methyl-4-nitroaniline 97%	655937	5g	$176
2-Bromo-6-methyl-4-nitroaniline	FB66370	2g	$150
2-Bromo-6-methyl-4-nitroaniline	FB66370	1g	$150
2-Bromo-6-methyl-4-nitroaniline	FB66370	0.5g	$150
2-Bromo-6-methyl-4-nitroaniline	FB66370	5g	$196.3
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2-BROMO-6-METHYL-4-NITROANILINE Properties

Melting point	180-184 °C
Boiling point	366.0±37.0 °C(Predicted)
Density	1.7207 (rough estimate)
refractive index	1.5150 (estimate)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	solid
pka	-1.34±0.20(Predicted)
Appearance	Light yellow to yellow Solid
InChI	InChI=1S/C7H7BrN2O2/c1-4-2-5(10(11)12)3-6(8)7(4)9/h2-3H,9H2,1H3
InChIKey	DCNWQCOXGLGSRC-UHFFFAOYSA-N
SMILES	C1(N)=C(C)C=C([N+]([O-])=O)C=C1Br
CAS DataBase Reference	102170-56-9
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338
PPE	Eyeshields, Gloves, type N95 (US)
Hazard Codes	Xi
Risk Statements	20/21/22-36/37
Safety Statements	36/37
WGK Germany	3
HazardClass	IRRITANT
HS Code	2921430090
Storage Class	13 - Non Combustible Solids

2-BROMO-6-METHYL-4-NITROANILINE price More Price(37)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	655937	2-Bromo-6-methyl-4-nitroaniline 97%	102170-56-9	5g	$176	2023-06-20	Buy
Biosynth	FB66370	2-Bromo-6-methyl-4-nitroaniline	102170-56-9	2g	$150	2026-06-04	Buy
Biosynth	FB66370	2-Bromo-6-methyl-4-nitroaniline	102170-56-9	1g	$150	2026-06-04	Buy
Biosynth	FB66370	2-Bromo-6-methyl-4-nitroaniline	102170-56-9	0.5g	$150	2026-06-04	Buy
Biosynth	FB66370	2-Bromo-6-methyl-4-nitroaniline	102170-56-9	5g	$196.3	2026-06-04	Buy

Product number	Packaging	Price	Buy
655937	5g	$176	Buy
FB66370	2g	$150	Buy
FB66370	1g	$150	Buy
FB66370	0.5g	$150	Buy
FB66370	5g	$196.3	Buy

2-BROMO-6-METHYL-4-NITROANILINE Chemical Properties,Uses,Production

Chemical Properties

yellow needles

Synthesis

99-52-5

102170-56-9

General procedure for the synthesis of 2-bromo-6-methyl-4-nitroaniline from 4-nitro-2-methylaniline: 2-methyl-4-nitroaniline (2.0 g, 13.2 mmol) was dissolved in acetonitrile (40 mL) at 60 °C, followed by the addition of N-bromosuccinimide (2.8 g, 15.8 mmol). The reaction mixture was heated to reflux for 3 hours and then cooled to room temperature. The reaction mixture was concentrated and diluted with dichloromethane (50 mL). The organic phase was washed sequentially with 2.5 M sodium hydroxide solution and saturated saline, dried over anhydrous sodium sulfate, filtered and concentrated. The crude product was purified by silica gel column chromatography (eluent: n-hexane/ethyl acetate, 4/1, v/v) to afford 2-bromo-6-methyl-4-nitroaniline as a yellow solid (2.75 g, 91% yield). Melting point: 178-179°C. Thin layer chromatography Rf value: 0.40 (unfolding agent: n-hexane/ethyl acetate, 5/1, v/v).1H NMR (DMSO-d6, 400MHz) δ 8.15 (d, J=2.5Hz, 1H), 7.93 (d, J=2.1Hz, 1H), 6.53 (s, 2H), 2.23 (s, 3H). Mass spectrum (ESI) m/z: 228.5 [M-H]-.

References

[1] Patent: WO2016/176460, 2016, A1. Location in patent: Page/Page column 97
[2] Bulletin of the Chemical Society of Japan, 1988, vol. 61, # 2, p. 597 - 599
[3] European Journal of Medicinal Chemistry, 2017, vol. 131, p. 1 - 13
[4] Journal of the Chemical Society, 1929, p. 1255
[5] Bulletin de la Societe Chimique de France, 1924, vol. <4>35, p. 1328

2-BROMO-6-METHYL-4-NITROANILINE synthesis

Synthesis of 2-BROMO-6-METHYL-4-NITROANILINE from 2-Methyl-4-nitroaniline

2-BROMO-6-METHYL-4-NITROANILINE Preparation Products And Raw materials

Raw materials

Zinc oxide Formic acid Diethyl ether Ethyl acetate Lithium Aluminum Hydride

2-Methyl-4-nitroaniline Bromine Dichloromethane Acetic acid 4-Fluoroaniline

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Preparation Products

Disperse red 129

2-BROMO-6-METHYL-4-NITROANILINE Suppliers

Global( 90)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21135	58
Accela ChemBio Inc.	+1-858-6993322 +86-18019713315	info@accelachem.com	United States	21189	58
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49906	58
career henan chemical co	+86-0371-86658258	factory@coreychem.com	China	29780	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14301	58
Dideu Industries Group Limited	+86-29-89586680 +86-15129568250	1059@dideu.com	China	29096	58
Henan Alfa Chemical Co., Ltd	+8618339805032	sale03@alfachem.cn	China	9811	58
Alfa Chemistry	+1-5166625404;	Info@alfa-chemistry.com	United States	20000	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +86-18949823763	sales@tnjchem.com	China	25333	58
Aromsyn Co., Ltd.	+86-0571-85585865 +86-13336024896	CB@aromsyn.com	China	19176	58

Supplier	Advantage
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Accela ChemBio Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Win-Win chemical CO., Limited	58
Dideu Industries Group Limited	58
Henan Alfa Chemical Co., Ltd	58
Alfa Chemistry	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Aromsyn Co., Ltd.	58

View Lastest Price from 2-BROMO-6-METHYL-4-NITROANILINE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2025-11-18	2-BROMO-6-METHYL-4-NITROANILINE 102170-56-9	$1.10	1g	99.00%	100 Tons Min	Dideu Industries Group Limited
	2020-02-01	2-bromo-6-methyl-4-nitroaniline 102170-56-9	$1.00	1KG	Min98% HPLC		Career Henan Chemical Co

2-BROMO-6-METHYL-4-NITROANILINE
102170-56-9
$1.10
99.00%
Dideu Industries Group Limited

2-bromo-6-methyl-4-nitroaniline
102170-56-9
$1.00
Min98% HPLC
Career Henan Chemical Co

2-BROMO-6-METHYL-4-NITROANILINE Spectrum

2-BROMO-6-METHYL-4-NITROANILINE(102170-56-9)¹HNMR

102170-56-9(2-BROMO-6-METHYL-4-NITROANILINE)Related Search:

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2-BROMO-6-METHYL-4-NITROANILINE 2-Methyl-4-nitro-6-bromoaniline 2-BROMO-6-METHYL-4-NITROANILINE 98% 2-Bromo-6-methyl-4-nitroaniline,98% 2-BroMo-6-Methyl-4-nitro-phenylaMine Benzenamine, 2-bromo-6-methyl-4-nitro- 6-Bromo-2-methyl-4-nitroaniline 2-BROMO-6-METHYL-4-NITROANILINE ISO 9001：2015 REACH 2-Bromo-6-methyl-4-nitrobenzenamine 102170-56-9 102172-56-9 H3CC6H2NO2BrNH2 C7H7BrN2O2 Organic Building Blocks Nitrogen Compounds Amines Building Blocks C7 Anilines, Aromatic Amines and Nitro Compounds Amines C7 Nitrogen Compounds