2-(Dimethylsilyl)pyridine
- CAS No.
- 21032-48-4
- Chemical Name:
- 2-(Dimethylsilyl)pyridine
- Synonyms
- 2-Pyridyldimethylsilane;2-(DIMETHYLSILY)PYRIDINE;dimethyl(2-pyridyl)silane;2-(Dimethylsilyl)pyridine;Pyridine, 2-(dimethylsilyl)-;dimethyl(pyridin-2-yl)silicon
- CBNumber:
- CB1735620
- Molecular Formula:
- C7H11NSi
- Molecular Weight:
- 137.25
- MDL Number:
- MFCD06797091
- MOL File:
- 21032-48-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Boiling point | 175-178 °C(Press: 758 Torr) |
|---|---|
| Density | 0.92 |
| refractive index | n20/D 1.499 |
| Flash point | 41 °C |
| storage temp. | 2-8°C |
| solubility | soluble in most common organic solvents. |
| pka | 5.40±0.12(Predicted) |
| InChI | 1S/C7H11NSi/c1-9(2)7-5-3-4-6-8-7/h3-6,9H,1-2H3 |
| InChIKey | FTSXFFCALJHVGU-UHFFFAOYSA-N |
| SMILES | C[SiH](C)c1ccccn1 |
| CAS DataBase Reference | 21032-48-4 |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H226-H315-H319-H335 |
| Precautionary statements | P210-P302+P352-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 36-26 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Eye Irrit. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 |
2-(Dimethylsilyl)pyridine price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 681490 | 2-(Dimethylsilyl)pyridine 90% | 21032-48-4 | 1g | $186 | 2026-04-30 | Buy |
| ChemScene | CS-0879100 | 2-(Dimethylsilyl)pyridine ≥98% | 21032-48-4 | 1g | $130 | 2026-06-04 | Buy |
| ChemScene | CS-0879100 | 2-(Dimethylsilyl)pyridine ≥98% | 21032-48-4 | 5g | $518 | 2026-06-04 | Buy |
| Matrix Scientific | 298523 | 2-(Dimethylsilyl)pyridine | 21032-48-4 | 250.00mg | $69 | 2026-05-19 | Buy |
| Matrix Scientific | 298523 | 2-(Dimethylsilyl)pyridine | 21032-48-4 | 1.00g | $163 | 2026-05-19 | Buy |
2-(Dimethylsilyl)pyridine Chemical Properties, Uses, Production
Physical properties
bp 68–72 °C/20 mm Hg.
Uses
2-Pyridyldimethylsilane is reagent used for metal-catalyzed hydrosilylation of alkynes and alkenes.Presumably because of the presence of catalyst-directing pyridyl group on silicon, 2- pyridyldimethylsilane exhibits greater reactivity in Rh-catalyzed hydrosilylation of alkenes than those of other related hydrosilanes. Moreover, the presence of the basic pyridyl group enables easy product separation and facile catalyst recovery through simple acid/base extraction.
Uses
A useful scaffold for a number of reactions including hydrosilylation, cross-coupling, and olefination.
Preparation
2-Pyridyldimethylsilane can be prepared by reaction of 2-pyridyllithium with chlorodimethylsilane in dry Et2O at 78°Cunder argon.
2-(Dimethylsilyl)pyridine Preparation Products And Raw materials
Raw materials
Preparation Products
2-(Dimethylsilyl)pyridine Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Suzhou Siso new material Co.,Ltd. | 0512-65402974 18550909935 | siso03@126.com | China | 1925 | 58 |
| Zhuoer Chemical Co., Ltd | 02120970332; | sales@zhuoerchem.com | China | 3000 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 | info@dycnchem.com | China | 52451 | 58 |
| CHG Opto-Electronic Corporation Limited | 2537653158 16621191650 | 2537653158@qq.com | China | 7131 | 58 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-025-66113011 15955137747 | cb5@aikonchem.com | China | 10354 | 58 |
| Shanghai Aladdin Biochemical Technology Co.,Ltd. | 6206333 13167063860 | anhua.mao@aladdin-e.com | China | 43586 | 58 |
