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Acetoacetamide

CAS No.
5977-14-0
Chemical Name:
Acetoacetamide
Synonyms
3-oxobutanamide;Nsc632231;Aids134414;Aids-134414;Acetoacetamid;ACETIACETAMIDE;ACETOACETAMIDE;β-Oxobutanamide;3-Oxobutyramide;Acetylacetamide
CBNumber:
CB1743902
Molecular Formula:
C4H7NO2
Molecular Weight:
101.1
MDL Number:
MFCD00025528
MOL File:
5977-14-0.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

Acetoacetamide Properties

Melting point 53-56 °C(lit.)
Boiling point 271.0±23.0 °C(Predicted)
Density 1.093±0.06 g/cm3(Predicted)
vapor pressure 0.93Pa at 20℃
Flash point >230 °F
storage temp. Refrigerator
solubility water: soluble1g/10 mL, clear, colorless
pka 12.38±0.46(Predicted)
form Crystalline Powder
color white to yellowish
Water Solubility 1000g/L at 20℃
BRN 1560550
InChIKey GCPWJFKTWGFEHH-UHFFFAOYSA-N
LogP -1.4 at 23℃
CAS DataBase Reference 5977-14-0(CAS DataBase Reference)
FDA UNII 6O9U7CFY0T
EPA Substance Registry System Butanamide, 3-oxo- (5977-14-0)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
WGK Germany  1
RTECS  EJ3667188

Acetoacetamide price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 328812 Acetoacetamide 97% 5977-14-0 100g $61.4 2023-06-20 Buy
Sigma-Aldrich 328812 Acetoacetamide 97% 5977-14-0 500g $132 2023-06-20 Buy
Sigma-Aldrich 688789 Acetoacetamide Lonza quality, 98.5-100.3% (w/w) (T) 5977-14-0 1kg $270 2023-06-20 Buy
Sigma-Aldrich 688789 Acetoacetamide Lonza quality, 98.5-100.3% (w/w) (T) 5977-14-0 25kg $1400 2023-06-20 Buy
TRC A161805 Acetoacetamide 5977-14-0 500g $415 2021-12-16 Buy
Product number Packaging Price Buy
328812 100g $61.4 Buy
328812 500g $132 Buy
688789 1kg $270 Buy
688789 25kg $1400 Buy
A161805 500g $415 Buy

Acetoacetamide Chemical Properties,Uses,Production

Chemical Properties

White to yellowish crystals

Uses

Acetoacetamide is used as intermediate for different organic syntheses, mainly organic dyestuffs. Product Data Sheet

Uses

Acetoacetamide was used in a study to assess the stability of artificial sweeteners- aspartame, acesulfame-K and binary sweetener blend of aspartame x acesulfame-K during storage. Acetoacetamide was also used in analysis of multiple sweeteners and their degradation products in lassi by HPLC.

Uses

Acetoacetamide is a β-keto amide commonly used in building heterocyclic systems. It can be used in synthesizing various N-substituted acetoacetamides, that are primary precursors for several organic dyes and pigments.

Definition

ChEBI: Acetoacetamide is a monocarboxylic acid amide of acetoacetic acid. It is functionally related to an acetoacetic acid.

General Description

Acetoacetamide is a degradation product of acesulfame-K, sweetener. Acetoacetamide undergoes alkaline hydrolysis to form salt of acetoacetic acid.

Flammability and Explosibility

Not classified

Purification Methods

Recrystallise the amide from CHCl3, or Me2CO/pet ether. It also crystallises from pyridine with 4mols of solvent. It is slightly soluble in H2O, EtOH and AcOH but is insoluble in Et2O. The phenylhydrazone has m 128o. [Kato Chem Pharm Bull Jpn 15 921 923 1967, Claisen & Meyer Chem Ber 35 583 1902, Beilstein 3 H 659, 3 I 231, 3 III 1204, 3 IV 1545.]

Global( 213)Suppliers
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View Lastest Price from Acetoacetamide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Acetoacetamide pictures 2025-07-25 Acetoacetamide
5977-14-0
US $0.00 / kg 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
Acetoacetamide pictures 2020-01-08 Acetoacetamide
5977-14-0
US $1.00 / KG 1KG 99.0% 100kg Career Henan Chemical Co
  • Acetoacetamide pictures
  • Acetoacetamide
    5977-14-0
  • US $0.00 / kg
  • 99%
  • Shaanxi Dideu New Materials Co. Ltd
Acetyl acetomide ACETOACETAMIDE PURUM ACETIACETAMIDE acetessigsaureamid alpha-acetylacetamide 3-Oxobutyramide β-Oxobutanamide Aids134414 Aids-134414 Nsc632231 Acetoacetamide Lonza quality, 98.5-100.3% (w/w) (T) Acetoacetamid Butanamide, 3-oxo- ACETOACETAMIDE acetoaceticacidamide Acetylacetamide 3-oxo-butanamid 3-oxobutanamide 3-oxo-Butanamide Acesulfame EP Impurity A 3-Oxobutanamide (Acetylacetamide) Acesulfame potassium EP Impurity A Acesulfame Potassium Impurity A Acesulfame Potassium Impurity A/ Acetoacetamide Acetoacetamide,cas:5977-14-0 Acetoacetamide CAS NO.5977-14-0 Acesulfame Potassium EP Impurity A (Acetoacetamide) Acesulfame Potassium Impurity (Acetoacetamide) 5977-14-0 CH3COCH2CONH2 Organic Building Blocks Amides Building Blocks Carbonyl Compounds Amides Carbonyl Compounds Organic Building Blocks Building Blocks Carbonyl Compounds Chemical Synthesis Organic Building Blocks Pharmaceutical Intermediates bc0001