3-(Benzyloxy)phenol
- CAS No.
- 3769-41-3
- Chemical Name:
- 3-(Benzyloxy)phenol
- Synonyms
- 3-Aenzyloxyphenol;3-(benzloxy)phenol;3-(BENZYLOXY)PHENOL;TIMTEC-BB SBB008506;M-(BENZYLOXY)PHENOL;3-(Benzyloxy)phenol>MONOBENZYL RESOURCINOL;3-(phenylmethoxy)phenol;3-(Benzyloxy)phenol ,95%;Phenol, 3-(phenylmethoxy)-
- CBNumber:
- CB2209878
- Molecular Formula:
- C13H12O2
- Molecular Weight:
- 200.23
- MDL Number:
- MFCD00134682
- MOL File:
- 3769-41-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 3-(Benzyloxy)phenol >95.0%(GC) | B2070 | 5g | $143 |
| 3-(Benzyloxy)phenol >95.0%(GC) | B2070 | 25g | $450 |
| 3-(Benzyloxy)phenol 97% | B56779 | 250mg | $86 |
| 3-(Benzyloxy)phenol 97% | B56779 | 1g | $96 |
| 3-(Benzyloxy)phenol 97% | B56779 | 5g | $100 |
| More product size | |||
| Melting point | 50°C |
|---|---|
| Boiling point | 200 °C / 5mmHg |
| Density | 1.0907 (rough estimate) |
| refractive index | 1.5906 (estimate) |
| storage temp. | Inert atmosphere,Room Temperature |
| pka | 9.59±0.10(Predicted) |
| form | powder to crystal |
| color | White to Almost white |
| CAS DataBase Reference | 3769-41-3 |
| NIST Chemistry Reference | Benzyl 3-hydroxyphenyl ether(3769-41-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-41 | |||||||||
| Safety Statements | 26-36/37/39-39 | |||||||||
| HS Code | 29095000 | |||||||||
| NFPA 704 |
|
3-(Benzyloxy)phenol price More Price(47)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B2070 | 3-(Benzyloxy)phenol >95.0%(GC) | 3769-41-3 | 5g | $143 | 2026-04-30 | Buy |
| TCI Chemical | B2070 | 3-(Benzyloxy)phenol >95.0%(GC) | 3769-41-3 | 25g | $450 | 2026-04-30 | Buy |
| Synthonix | B56779 | 3-(Benzyloxy)phenol 97% | 3769-41-3 | 250mg | $86 | 2026-05-06 | Buy |
| Synthonix | B56779 | 3-(Benzyloxy)phenol 97% | 3769-41-3 | 1g | $96 | 2026-05-06 | Buy |
| Synthonix | B56779 | 3-(Benzyloxy)phenol 97% | 3769-41-3 | 5g | $100 | 2026-05-06 | Buy |
3-(Benzyloxy)phenol Chemical Properties,Uses,Production
Chemical Properties
White solid
Uses
3-(Benzyloxy)phenol is an isomer of benzyloxyphenol (BLP), which contains the structures 2-BLP, 3-BLP, and 4-BLP. 3-BLP is used for chromatographic identification or isomer extraction and separation studies.
Synthesis
100-39-0
108-46-3
3769-41-3
General procedure for the preparation of 3-benzyloxyphenol: Resorcinol (10.0 g, 90.9 mmol) was dissolved in acetone (50 mL) and cooled to 5-10 °C. With continuous stirring, anhydrous potassium carbonate (18.8 g, 136.3 mmol) was added. Maintaining this temperature, benzyl bromide (10.88 g, 63.6 mmol) was added slowly and the cooling bath was removed after 10 minutes. The reaction mixture was refluxed for 12 to 17 hours. After the temperature was reduced to 20 to 40°C, the solid potassium carbonate was removed by filtration. The filtrate was concentrated, poured into ice water, acidified with 6N hydrochloric acid and subsequently extracted with ethyl acetate (3 x 25 mL). The organic layers were combined, washed with water, dried over anhydrous sodium sulfate and evaporated to give a brown colloidal substance. Purification by column chromatography (230-400 mesh silica gel, eluent ethyl acetate:petroleum ether = 10:90), discarding the dibenzyloxyditerpene by-product, gave pure light brown colloidal target product 3-benzyloxyphenol. Yield: 13.5 g, 68% yield. Product characterization data: 1H NMR (CDCl3, 200MHz): δ 7.50-7.30 (m, 5H), 7.12 (t, J = 8.2Hz, 1H), 6.57 (dd, J = 1.8, 6.2Hz, 1H), 6.50-6.40 (m, 2H), 5.02 (s, 2H), 4.86 (bs, 1H, D2O exchangeable). Mass spectrum (CI): m/z 201 (M++1). IR (KBr, cm-1): 3406, 3032, 1595, 1490, 1454.
References
[1] Patent: US2014/256657, 2014, A1. Location in patent: Paragraph 0399
[2] Tetrahedron, 2007, vol. 63, # 43, p. 10698 - 10708
[3] Journal of Organic Chemistry, 1997, vol. 62, # 10, p. 3062 - 3075
[4] Journal of Medicinal Chemistry, 2004, vol. 47, # 17, p. 4155 - 4158
[5] Chemical Communications, 2018, vol. 54, # 39, p. 4935 - 4938
3-(Benzyloxy)phenol Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 4000 | 58 |
| Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29640 | 60 |
| Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | CHINA | 722 | 55 | |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10000 | 58 |
| Kindchem(Nanjing)Co.,Ltd | +86-025-025-85281586 +8618651653755 | sales@kindchem.cn | China | 1226 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
View Lastest Price from 3-(Benzyloxy)phenol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-07-14 | 3-Benzyloxyphenol
3769-41-3
|
$1.00 | 1KG | 99% | 20t | Shaanxi Dideu Medichem Co. Ltd | |
 |
2020-01-09 | 3-Benzyloxyphenol
3769-41-3
|
$1.00 | 1KG | 99% | 10000KGS | Career Henan Chemical Co |
-
- 3-Benzyloxyphenol
3769-41-3
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-
- 3-Benzyloxyphenol
3769-41-3
- $1.00
- 99%
- Career Henan Chemical Co
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