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N-(3-Bromophenyl)methansulfonamide

CAS No.
83922-51-4
Chemical Name:
N-(3-Bromophenyl)methansulfonamide
Synonyms
N-(3-Bromophenyl)methansulfonamide;3-BROMO PHENYL METHANE SULPHONAMIDE;3-(methylsulfonyl)amino-1-bromo-benzene
CBNumber:
CB22130976
Molecular Formula:
C7H8BrNO2S
Molecular Weight:
250.11
MDL Number:
MFCD01213915
MOL File:
83922-51-4.mol
MSDS File:
SDS
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
N-(3-Bromophenyl)methanesulfonamide B698330 1g $75
N-(3-BROMOPHENYL)METHANESULFONAMIDE BP-21291 1g $106
N-(3-Bromophenyl)methansulfonamide X5390 5g $192
N-(3-Bromophenyl)methanesulfonamide 8669-9-57 1g $245
METHANESULFONAMIDE, N-(3-BROMOPHENYL)- 95.00% HCH0137515 1G $721.57

N-(3-Bromophenyl)methansulfonamide Properties

Boiling point 330.7±44.0 °C(Predicted)
Density 1.711±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka 7.47±0.10(Predicted)
Appearance White to gray Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
HS Code  2935909099

N-(3-Bromophenyl)methansulfonamide price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B698330 N-(3-Bromophenyl)methanesulfonamide 83922-51-4 1g $75 2021-12-16 Buy
BroadPharm BP-21291 N-(3-BROMOPHENYL)METHANESULFONAMIDE 83922-51-4 1g $106 2021-12-16 Buy
AK Scientific X5390 N-(3-Bromophenyl)methansulfonamide 83922-51-4 5g $192 2021-12-16 Buy
SynQuest Laboratories 8669-9-57 N-(3-Bromophenyl)methanesulfonamide 83922-51-4 1g $245 2021-12-16 Buy
American Custom Chemicals Corporation HCH0137515 METHANESULFONAMIDE, N-(3-BROMOPHENYL)- 95.00% 83922-51-4 1G $721.57 2021-12-16 Buy
Product number Packaging Price Buy
B698330 1g $75 Buy
BP-21291 1g $106 Buy
X5390 5g $192 Buy
8669-9-57 1g $245 Buy
HCH0137515 1G $721.57 Buy

N-(3-Bromophenyl)methansulfonamide Chemical Properties,Uses,Production

Synthesis

Methanesulfonyl chloride

124-63-0

3-Bromoaniline

591-19-5

N-(3-Bromophenyl)methansulfonamide

83922-51-4

Step i: To a stirred solution of anhydrous dichloromethane (200 ml) of m-bromoaniline (6 g, 34.87 mmol) was sequentially added pyridine (4.13 mg, 52.31 mmol) and methanesulfonyl chloride (5.194 g, 45.34 mmol) at 10 °C. The reaction mixture was stirred at room temperature for 15 h. The progress of the reaction was monitored by thin layer chromatography (TLC, the unfolding agent was a hexane solution of 35% ethyl acetate). After completion of the reaction, the reaction mixture was diluted with dichloromethane (50 ml) and washed with 1N hydrochloric acid (25 ml). The organic layer was dried with anhydrous sodium sulfate and concentrated under reduced pressure to give N-(3-bromophenyl)methane sulfonamide 8.45 g in 96.3% yield. The product was structurally confirmed by 1H NMR (DMSO-d6, 300 MHz) and mass spectrometry (MS: m/z = 251.8 [M + 1]).

References

[1] Patent: WO2014/6554, 2014, A1. Location in patent: Page/Page column 28
[2] Synthetic Communications, 2004, vol. 34, # 20, p. 3807 - 3819
[3] Patent: WO2017/18803, 2017, A1. Location in patent: Paragraph 791; 792; 793
[4] Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1982, vol. 38, # 7, p. 791 - 796
[5] Heterocycles, 2001, vol. 54, # 1, p. 105 - 108

N-(3-Bromophenyl)methansulfonamide Preparation Products And Raw materials

N-(3-Bromophenyl)methansulfonamide Suppliers

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N-(3-Bromophenyl)methansulfonamide Spectrum

N-(3-Bromophenyl)methansulfonamide 3-(methylsulfonyl)amino-1-bromo-benzene 3-BROMO PHENYL METHANE SULPHONAMIDE 83922-51-4 Aryl Building Blocks