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(1R,2R)-(+)-1-Phenylpropylene oxide

(1R,2R)-(+)-1-Phenylpropylene oxide structure

CAS No.: 14212-54-5

Chemical Name:: (1R,2R)-(+)-1-Phenylpropylene oxide

Synonyms: (2r-trans)-oxiran;1-phenylpropylene oxide;(r,r)-phenylpropyleneoxide;2-epoxypropyl)benzene(1r,2r)-(;[(2R,3R)-3-Methyloxiranyl]benzene;(1,2-epoxypropyl)-,(1r,2r)-benzen;(1R,2R)-(+)-1-Phenylpropylene oxide;(2R,3R)-(+)-2-METHYL-3-PHENYLOXIRANE;[2R,3R,(+)]-3-Methyl-2-phenyloxirane;(1r,2r)-(+)-1-phenyl-1,2-epoxypropane

CBNumber:: CB2263647

Molecular Formula:: C9H10O

Molecular Weight:: 134.18

MDL Number:: MFCD00064482

MOL File:: 14212-54-5.mol

MSDS File:: SDS

Last updated:2026-09-12 18:50:36

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(1R,2R)-(+)-1-Phenylpropylene oxide Properties

Boiling point	201-207 °C(lit.)
Density	1.006 g/mL at 25 °C(lit.)
refractive index	n20/D 1.518(lit.)
Flash point	156 °F
form	liquid
optical activity	[α]20/D +110°, neat
InChI	1S/C9H10O/c1-7-9(10-7)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-,9+/m1/s1
InChIKey	YVCOJTATJWDGEU-APPZFPTMSA-N
SMILES	C[C@H]1O[C@@H]1c2ccccc2
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
target organs	Respiratory system
PPE	Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
RTECS	DA0177000
Storage Class	10 - Combustible liquids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

(1R,2R)-(+)-1-Phenylpropylene oxide price More Price(2)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
AHH	MT-21263	(1R,2R)-(+)-1-Phenylpropylene oxide 97%		10g	$425	2026-05-26	Buy
American Custom Chemicals Corporation	CCH0002952	(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE 95.00%	14212-54-5	1G	$751.3	2021-12-16	Buy

Product number	Packaging	Price	Buy
MT-21263	10g	$425	Buy
CCH0002952	1G	$751.3	Buy

(1R,2R)-(+)-1-Phenylpropylene oxide Chemical Properties,Uses,Production

Synthesis

A solution of 0.05 M Na2HPO4 (10.0 mL) was added to a 25-mL solution of undiluted commercial household bleach (Clorox). The pH of the resulting buffered solution (0.55 M in NaOCl) was adjusted to pH 11.3 by addition of a few drops of 1 M NaOH solution. This solution was cooled to 0 °C and then added at once to a 0 °C solution of the manganese catalyst (260 mg, 0.4 mmol) and cis-o-methylstyrene (1.18 g, 10 mmol) in 10 mL of CH2Cl2. The two-phase mixture was stirred at room temperature, and the reaction progress was monitored by TLC. After 3 h, 100 mL of hexane was added to the mixture and the brown organic phase was separated, washed twice with 100 mL of H2O and once with 100 mL of saturated NaCl solution, and then dried (Na2SO4). After solvent removal, the residue was purifified by flflash chromatography on silica gel to afford the epoxide (0.912 g, 68%). The ee of the epoxide was determined to be 84% by 1 H NMR analysis in the presence of Eu(hfc)3.
(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE
Reference: Zhang, W.; Jacobsen, E. N. J. Org. Chem. 1991, 56, 2296−2298.

Uses

Chiral building block. Tool for studying enzyme hydrolysis rates.

(1R,2R)-(+)-1-Phenylpropylene oxide synthesis

Synthesis of (1R,2R)-(+)-1-Phenylpropylene oxide from trans-beta-Methylstyrene

(1R,2R)-(+)-1-Phenylpropylene oxide Preparation Products And Raw materials

Raw materials

cis-Stilbene oxide trans-beta-Methylstyrene β-Methylstyrene cis-Stilbene

Preparation Products

Oxirane, 2-methyl-3-phenyl-, (2R,3S)- (1S,2S)-(-)-1-Phenylpropylene oxide Benzaldehyde

(1R,2R)-(+)-1-Phenylpropylene oxide Suppliers

Global( 17)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Finetech Industry Limited	027-87465837 19945049750	sales@finetechnology-ind.com	China	9331	58
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51389	80
Shandong Ono Chemical Co., Ltd.	0539-6362799 20）		China	9998	58
Aikon International Limited	025-58859352 15955137747	sales01@aikonchem.com	China	16021	58
Nanjing Shizhou Biology Technology Co.,Ltd	13675144456	sean.lv@synzest.com	China	10778	58
QUALITY CONTROL SOLUTIONS LTD.	+86-0755-66853366 +86-13670046396	export03@qcsrm.com	China	24318	58
Shaanxi Dideu Medichem Co. Ltd	81148925 17391631969	1023@dideu.com	China	9999	58
DAYANG CHEM (HANGZHOU) CO.,LTD	+86-88938639 +86-17705817739	info@dycnchem.com	China	53799	58

Supplier	Advantage
Energy Chemical	61
Finetech Industry Limited	58
Sigma-Aldrich	80
Shandong Ono Chemical Co., Ltd.	58
Aikon International Limited	58
Nanjing Shizhou Biology Technology Co.,Ltd	58
QUALITY CONTROL SOLUTIONS LTD.	58
Shaanxi Dideu Medichem Co. Ltd	58
DAYANG CHEM (HANGZHOU) CO.,LTD	58

View Lastest Price from (1R,2R)-(+)-1-Phenylpropylene oxide manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	(1R,2R)-(+)-1-Phenylpropylene oxide 14212-54-5	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd

(1R,2R)-(+)-1-Phenylpropylene oxide
14212-54-5
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(1R,2R)-(+)-1-Phenylpropylene oxide Spectrum

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE(14212-54-5)¹HNMR (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE(14212-54-5)Raman

14212-54-5((1R,2R)-(+)-1-Phenylpropylene oxide)Related Search:

[3-(2-Nitrophenyl)oxiran-2-yl](phenyl)methanone 6a-Methyl-5a,6,6a,7,8,9,9a,9b,10,11-decahydrocyclopenta[7,8]phenanthro[4b,5-b]oxirene-2,7-diol (1R,2R)-(+)-1-Phenylpropylene oxide (1S,2S)-(-)-1-Phenylpropylene oxide trans-Stilbene oxide

2-PHENYLPROPYLENE OXIDE 2,2-DIMETHYL-3,3-DIPHENYLOXIRANE Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate dynemicin A TETRAPHENYLETHYLENE OXIDE

TRANS-1,3-DIPHENYL-2,3-EPOXYPROPAN-1-ONE TRANS-4-PHENYLCHALCONE OXIDE HYPOTHEMYCIN (2R,3R)-3-PHENYLGLYCIDOL 2-(ACETYLOXY)-6A-METHYL-5A,6,6A,7,8,9,9A,9B,10,11-DECAHYDROCYCLOPENTA[7,8]PHENANTHRO[4B,5-B]OXIREN-7-YL ACETATE

(2R,3R)-(+)-2,3-EPOXY-3-(4-NITROPHENYL)-1-PROPANOL

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1-phenylpropylene oxide [(2R,3R)-3-Methyloxiranyl]benzene [2R,3R,(+)]-3-Methyl-2-phenyloxirane (1R,2R)-(+)-1-Phenylpropylene oxide 97% (1,2-epoxypropyl)-,(1r,2r)-benzen (1r,2r)-(+)-1-phenyl-1,2-epoxypropane (2r-trans)-oxiran (r,r)-phenylpropyleneoxide 2-epoxypropyl)benzene(1r,2r)-( (2R,3R)-(+)-2-METHYL-3-PHENYLOXIRANE Oxirane, 2-methyl-3-phenyl-, (2R,3R)- (9CI) Oxirane, 2-methyl-3-phenyl-, (2R,3R)- (1R,2R)-(+)-1-Phenylpropylene oxide (1R,2R)-(+)-1-Phenylpropylene oxide 14212-54-5 Epoxides Organic Building Blocks Chiral Building Blocks Asymmetric Synthesis EPOXYDE