Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO
- CAS No.
- 1295649-40-9
- Chemical Name:
- Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO
- Synonyms
- Ru-MACHO(regR);Ru-MACHO?;Ru-MACHO (contains 5% Toluene at maximum) ;Ru-MACHO[R] (contains 5% Toluene at maximum);Ru-MACHO(regR) (contains 5% Toluene at maximum);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II);Carbonylchlorohydrido(bis((2-diphenylphosphino)ethyl)amine)ruthenium(II);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO;Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM)
- CBNumber:
- CB22709282
- Molecular Formula:
- C29H31ClNOP2Ru
- Molecular Weight:
- 608.04
- MDL Number:
- MFCD22377801
- MOL File:
- 1295649-40-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Properties
| Melting point | 260-290 °C |
|---|---|
| storage temp. | 2-8°C, stored under nitrogen |
| form | Powder |
| color | white to yellow |
| Sensitive | air sensitive |
| InChI | 1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1 |
| InChIKey | GQFWSAKCCNATEV-UHFFFAOYSA-M |
| SMILES | Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4 |
| CAS DataBase Reference | 1295649-40-9 |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| WGK Germany | WGK 3 | |||||||||
| HS Code | 2843.90.0000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
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| NFPA 704 |
|
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 739103 | Ru-MACHO® | 1295649-40-9 | 250MG | $80 | 2026-04-30 | Buy |
| Sigma-Aldrich | 739103 | Ru-MACHO® | 1295649-40-9 | 1G | $304 | 2026-04-30 | Buy |
| Sigma-Aldrich | 739103 | Ru-MACHO® | 1295649-40-9 | 5G | $509 | 2026-04-30 | Buy |
| TCI Chemical | R0136 | Ru-MACHO[R] (contains 5% Toluene at maximum) | 1295649-40-9 | 200mg | $65 | 2026-04-30 | Buy |
| TCI Chemical | R0136 | Ru-MACHO[R] (contains 5% Toluene at maximum) | 1295649-40-9 | 1g | $203 | 2026-04-30 | Buy |
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Chemical Properties, Uses, Production
Reaction
- Highly efficient ruthenium-catalyzed used in the N-formylation of amines with hydrogen and carbon dioxide.
- Rutheniumcatalyzed hydrogen generation from glycerol and selective synthesis of lactic acid
Uses
<ul>
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul>
reaction suitability
core: ruthenium
reagent type: catalyst
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Preparation Products And Raw materials
Raw materials
Preparation Products
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| parabiochem | 025-83453382-8005 | sale@parabiochem.com | China | 9577 | 55 |
| Nanijing m&m biotechnology Co. ,Ltd. | 025-87782433 18021532344 | 1345332203@qq.com | China | 4226 | 58 |
| 9ding chemical ( Shanghai) Limited | 021-021-52271985 17721149837 | sales@9dingchem.com | China | 19780 | 60 |
| Rhawn Reagent | 400-400-1332688 18019345275 | huyue@rhawn.cn | China | 14942 | 58 |
| Nanjing Haolv Biotechnology Co.,Ltd | 025-84622273 17361806303 | kexin.zhou@haolvbiotech.com | China | 3009 | 58 |
| Angel Pharmatech, Ltd. | 17317130613 | 3358272972@qq.com | China | 3307 | 58 |





