ChemicalBook >> CAS DataBase List >>Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO

CAS No.
1295649-40-9
Chemical Name:
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO
Synonyms
Ru-MACHO(regR);Ru-MACHO?;Ru-MACHO (contains 5% Toluene at maximum) ;Ru-MACHO[R] (contains 5% Toluene at maximum);Ru-MACHO(regR) (contains 5% Toluene at maximum);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II);Carbonylchlorohydrido(bis((2-diphenylphosphino)ethyl)amine)ruthenium(II);Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO;Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM)
CBNumber:
CB22709282
Molecular Formula:
C29H31ClNOP2Ru
Molecular Weight:
608.04
MDL Number:
MFCD22377801
MOL File:
1295649-40-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 00:04:27

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Properties

Melting point 260-290 °C
storage temp. 2-8°C, stored under nitrogen
form Powder
color white to yellow
Sensitive air sensitive
InChI 1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1
InChIKey GQFWSAKCCNATEV-UHFFFAOYSA-M
SMILES Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4
CAS DataBase Reference 1295649-40-9
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
WGK Germany  WGK 3
HS Code  2843.90.0000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
1 0

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 739103 Ru-MACHO® 1295649-40-9 250MG $80 2026-04-30 Buy
Sigma-Aldrich 739103 Ru-MACHO® 1295649-40-9 1G $304 2026-04-30 Buy
Sigma-Aldrich 739103 Ru-MACHO® 1295649-40-9 5G $509 2026-04-30 Buy
TCI Chemical R0136 Ru-MACHO[R] (contains 5% Toluene at maximum) 1295649-40-9 200mg $65 2026-04-30 Buy
TCI Chemical R0136 Ru-MACHO[R] (contains 5% Toluene at maximum) 1295649-40-9 1g $203 2026-04-30 Buy
Product number Packaging Price Buy
739103 250MG $80 Buy
739103 1G $304 Buy
739103 5G $509 Buy
R0136 200mg $65 Buy
R0136 1g $203 Buy

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Chemical Properties, Uses, Production

Reaction

  1. Highly efficient ruthenium-catalyzed used in the N-formylation of amines with hydrogen and carbon dioxide.
  2. Rutheniumcatalyzed hydrogen generation from glycerol and selective synthesis of lactic acid
Reactions of 1295649-40-9

Uses

<ul>
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul>

reaction suitability

core: ruthenium
reagent type: catalyst

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Preparation Products And Raw materials

Raw materials

Preparation Products

Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Suppliers

Global Suppliers ( 51)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28364 80
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
parabiochem 025-83453382-8005 sale@parabiochem.com China 9577 55
Nanijing m&m biotechnology Co. ,Ltd. 025-87782433 18021532344 1345332203@qq.com China 4226 58
9ding chemical ( Shanghai) Limited 021-021-52271985 17721149837 sales@9dingchem.com China 19780 60
Rhawn Reagent 400-400-1332688 18019345275 huyue@rhawn.cn China 14942 58
Nanjing Haolv Biotechnology Co.,Ltd 025-84622273 17361806303 kexin.zhou@haolvbiotech.com China 3009 58
Angel Pharmatech, Ltd. 17317130613 3358272972@qq.com China 3307 58

1295649-40-9 (Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO) Related Search:

Ru-MACHO(regR) Ru-MACHO(regR) (contains 5% Toluene at maximum) Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO Ru-MACHO (contains 5% Toluene at maximum) Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II) Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM) Ru-MACHO[R] (contains 5% Toluene at maximum) Carbonylchlorohydrido(bis((2-diphenylphosphino)ethyl)amine)ruthenium(II) Ru-MACHO? 1295649-40-9 C29H30ClNOP2Ru