Bis(tetrabutylammonium) dichromate
- CAS No.
- 56660-19-6
- Chemical Name:
- Bis(tetrabutylammonium) dichromate
- Synonyms
- TETRABUTYLAMMONIUM DICHROMATE;TBADC;BIS(TETRABUTYLAMMONIUM) DICHROMATE;Tetra-n-butylaMMoniuM dichroMate, 99%;BIS(TETRA-N-BUTYLAMMONIUM) DICHROMATE;TBADC, Tetrabutylammonium dichromate;Bis(tetrabutylammonium) dichromate 99%;Bis(tetrabutylammonium) Dichromate Bis(tetrabutylammonium) Dichromate,0.97;tetrabutylammonium, salt with chromic acid (2:1)
- CBNumber:
- CB2272092
- Molecular Formula:
- C32H72Cr2N2O7
- Molecular Weight:
- 700.92
- MDL Number:
- MFCD00013104
- MOL File:
- 56660-19-6.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 139-143 °C (lit.) |
|---|---|
| solubility | sol dichloromethane, chloroform. |
| form | powder to crystaline |
| color | Light yellow to Brown |
| Water Solubility | Soluble in water. |
| Exposure limits |
OSHA: Ceiling 0.1 mg/m3 NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3 |
| InChI | 1S/2C16H36N.2Cr.7O/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;;;;/h2*5-16H2,1-4H3;;;;;;;;;/q2*+1;;;;;;;;2*-1 |
| InChIKey | MMKQSIQNDMIVIN-UHFFFAOYSA-N |
| SMILES | [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC |
| UNSPSC Code | 12352116 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS03,GHS07,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H272-H317-H350-H410 | |||||||||
| Precautionary statements | P202-P210-P273-P280-P302+P352-P308+P313 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | O,T,N | |||||||||
| Risk Statements | 49-8-43-50/53 | |||||||||
| Safety Statements | 53-45-60-61 | |||||||||
| RIDADR | UN 1479 5.1/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| F | 8 | |||||||||
| HazardClass | 5.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 5.1B - Oxidizing hazardous materials | |||||||||
| Hazard Classifications | Aquatic Acute 1 Aquatic Chronic 1 Carc. 1B Ox. Sol. 2 Skin Sens. 1 |
|||||||||
| NFPA 704 |
|
Bis(tetrabutylammonium) dichromate price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 223964 | Bis(tetrabutylammonium) dichromate 99% | 56660-19-6 | 10g | $242 | 2026-04-30 | Buy |
| TCI Chemical | B1123 | Bis(tetrabutylammonium) Dichromate [Oxidizing Reagent] >97.0%(T) | 56660-19-6 | 10g | $99 | 2026-04-30 | Buy |
| Usbiological | 267187 | Bis(tetrabutylammonium) Dichromate Asreported | 56660-19-6 | 5g | $305 | 2026-06-03 | Buy |
| Usbiological | 267187 | Bis(tetrabutylammonium) Dichromate Asreported | 56660-19-6 | 10g | $416 | 2026-06-03 | Buy |
| Usbiological | 267187 | Bis(tetrabutylammonium) Dichromate Asreported | 56660-19-6 | 25g | $585 | 2026-06-03 | Buy |
Bis(tetrabutylammonium) dichromate Chemical Properties,Uses,Production
Uses
Reagent for:
- Preparation of nitrophenol derivatives and quinones under aprotic reaction conditions
- Conversion of oximes to carbonyl compounds under microwave irradiation
- Catalyst precursor for catalytic gas phase dehydration of acetic acid to ketene
- Crosslinking agent
Application
Bis(tetrabutylammonium) Dichromate (TBADC) is a mild selective oxidizing agent for benzylic and allylic alcohols[1]. It can oxidize carbon-halogen bonds[2].
Preparation
Preparative Method of Bis(tetrabutylammonium) Dichromate (TBADC): a concentrated aqueous solution (300 mL) of Potassium Dichromate (29.4 g, 0.1 mol) is added to a saturated aqueous solution (300 mL) of Tetra-n-butylammonium Bromide (64.4 g, 0.2 mol). TBADC precipitates and can be removed by filtration (62.8 g, 90% yield).
reaction suitability
reagent type: oxidant
storage
Bis(tetrabutylammonium) dichromate was reported to be a toxic agent. The reagent should be handled in a fume hood.
Purification Methods
Wash it with water and dry it in a vacuum. Recrystallise it from hexane (m 79-80o). [Santaniello & Ferraboschi Synth Commun 10 75 1980, Beilstein 4 IV 556.] (Possible CARCINOGEN.)
References
1. (a) Santaniello, E.; Ferraboschi, P. SC 1980, 10, 75. (b) Luzzio, F. A.; Guziec, F. S. OPP 1988, 20, 533.
2. Landini, D.; Rolla, F. CI(L) 1979, 213.
Bis(tetrabutylammonium) dichromate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Tianjin heowns Biochemical Technology Co., Ltd. | 400 638 7771 | sales@heowns.com | China | 14412 | 57 |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 7236 | 62 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
View Lastest Price from Bis(tetrabutylammonium) dichromate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-08 | Bis(tetrabutylammonium) dichromate
56660-19-6
|
$2.00 | 1KG | 99 | 100kg | Career Henan Chemical Co |
-
- Bis(tetrabutylammonium) dichromate
56660-19-6
- $2.00
- 99
- Career Henan Chemical Co
56660-19-6(Bis(tetrabutylammonium) dichromate)Related Search:
1of4
