2-BROMO-4-HYDROXYMETHYL-PHENOL
- CAS No.
- 29922-56-3
- Chemical Name:
- 2-BROMO-4-HYDROXYMETHYL-PHENOL
- Synonyms
- RARECHEM AL BD 0697;3-broMo-4-hydroxybenzylalchol;2-BROMO-4-HYDROXYMETHYL-PHENOL;3-BROMO-4-HYDROXYBENZYL ALCOHOL;3-Bromo-4-hydroxybenzenemethanol;Benzenemethanol, 3-bromo-4-hydroxy-;3-Bromo-4-hydroxybenzyl alcohol, (3-Bromo-4-hydroxyphenyl)methanol
- CBNumber:
- CB2304988
- Molecular Formula:
- C7H7BrO2
- Molecular Weight:
- 203.03
- MDL Number:
- MFCD00016869
- MOL File:
- 29922-56-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 3-Bromo-4-hydroxybenzyl alcohol | FB67229 | 250mg | $72.5 |
| 3-Bromo-4-hydroxybenzyl alcohol | FB67229 | 500mg | $115 |
| 2-Bromo-4-(hydroxymethyl)phenol | OR2644 | 1g | $34 |
| 2-Bromo-4-(hydroxymethyl)phenol | 2704-9-X0 | 1g | $37 |
| 3-Bromo-4-hydroxybenzyl alcohol | FB67229 | 1g | $200 |
| Melting point | 128-132℃ |
|---|---|
| Boiling point | 307.8±27.0 °C(Predicted) |
| Density | 1.722±0.06 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| form | solid |
| pka | 8.21±0.18(Predicted) |
| color | Yellow |
| CAS DataBase Reference | 29922-56-3(CAS DataBase Reference) |
| FDA UNII | NCR2ARL56P |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P280g-P305+P351+P338 |
| Hazard Codes | Xi |
| HazardClass | IRRITANT |
| HS Code | 2908190090 |
2-BROMO-4-HYDROXYMETHYL-PHENOL price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth Carbosynth | FB67229 | 3-Bromo-4-hydroxybenzyl alcohol | 29922-56-3 | 250mg | $72.5 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB67229 | 3-Bromo-4-hydroxybenzyl alcohol | 29922-56-3 | 500mg | $115 | 2021-12-16 | Buy |
| Apolloscientific | OR2644 | 2-Bromo-4-(hydroxymethyl)phenol | 29922-56-3 | 1g | $34 | 2021-12-16 | Buy |
| SynQuest Laboratories | 2704-9-X0 | 2-Bromo-4-(hydroxymethyl)phenol | 29922-56-3 | 1g | $37 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB67229 | 3-Bromo-4-hydroxybenzyl alcohol | 29922-56-3 | 1g | $200 | 2021-12-16 | Buy |
2-BROMO-4-HYDROXYMETHYL-PHENOL Chemical Properties,Uses,Production
Chemical Properties
off-white crystalline
Synthesis
29415-97-2
29922-56-3
Methyl 3-bromo-4-hydroxybenzoate (12, 0.185 g, 0.80 mmol) in anhydrous CH2Cl2 (14 mL) was added slowly to a THF solution of DIBAL-H (1.0 M, 1.92 mL, 1.92 mmol) at -78 °C. The reaction mixture was stirred at -78 °C for 1 h before the reaction was quenched by addition of MeOH and water. Subsequently, saturated potassium sodium tartrate solution was added and stirring was continued for 1 hour. The aqueous layer was extracted with ethyl acetate (3 x 20 mL), the organic layers were combined, washed sequentially with 10% aqueous NaHCO3 and water, dried over anhydrous Na2SO4, filtered and concentrated. The residue was purified by fast column chromatography (eluent: ethyl acetate/hexane, 1:1) to afford the target product 3-bromo-4-hydroxybenzenemethanol (13, 0.111 g, 68% yield) as a white solid. The product characterization data were as follows: melting point 125 °C; elemental analysis (measured value: C, 41.45; H, 3.42. theoretical value of C7H7BrO2: C, 41.41; H, 3.48); thin-layer chromatography Rf-value of 0.6 (unfolding reagent: ethyl acetate/hexanes, 65:35); IR (Nujol) νmax 3510, 3060, 2982, 1610 , 1505, 1425, 1270, 905, 750, 710 cm-1; 1H NMR (300MHz, DMSO-d6) δ: 7.38 (d, J=2.0Hz, 1H), 7.08 (dd, J=2.0,8.2Hz, 1H), 6.87 (d, J=8.2Hz, 1H), 5.07 (t, J=5.7 Hz, 1H), 4.34 (d, J=5.7Hz, 2H); 13C NMR (75MHz, DMSO-d6) δ: 153.3, 135.4, 131.6, 127.6, 116.5, 109.4, 62.5.
References
[1] Tetrahedron, 2011, vol. 67, # 34, p. 6300 - 6307
2-BROMO-4-HYDROXYMETHYL-PHENOL Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
2-BROMO-4-HYDROXYMETHYL-PHENOL Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10035 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30229 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24727 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49973 | 58 |
| Nanjing Bicbiotechnology Co., Ltd | +86-2552131256 +86-18251840740 | sales@bicbiotech.com | China | 5994 | 58 |
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