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ChemicalBook >> CAS DataBase List >>2,2,3,4,4,4-Hexafluoro-1-butanol

2,2,3,4,4,4-Hexafluoro-1-butanol

2,2,3,4,4,4-Hexafluoro-1-butanol Structure
2,2,3,4,4,4-Hexafluoro-1-butanol structure
CAS No.
382-31-0
Chemical Name:
2,2,3,4,4,4-Hexafluoro-1-butanol
Synonyms
Hexafluorobutanol;2,2,3,4,4,4-HEXAFLUOROBUTAN-1-OL;uoro-1-butanoL;HEXAFLUORO-1-BUTANOL;Hexafluorobutanol (HFB);1H,1H,3H-HEXAFLUOROBUTANOL;1H,1H,3H-PerfluoroButan-1-ol;2,2,3,4,4,4-HEXAFLUOROBUTANOL;2,2,3,4,4,4-HEXAFLUOROBUTANOL-1;2,2,3,4,4,4-Hexafluoro-1-butanol
CBNumber:
CB2372389
Molecular Formula:
C4H4F6O
Molecular Weight:
182.06
MDL Number:
MFCD00042309
MOL File:
382-31-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:50:38
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2,2,3,4,4,4-Hexafluoro-1-butanol Properties

Melting point 68°C
Boiling point 114 °C/740 mmHg (lit.)
Density 1.557 g/mL at 25 °C (lit.)
refractive index n20/D 1.312(lit.)
Flash point 125 °F
storage temp. 2-8°C
form clear liquid
pka 13.10±0.10(Predicted)
Specific Gravity 1.557
color Colorless to Light yellow
BRN 1753872
Henry's Law Constant 3.2×10-1 mol/(m3Pa) at 25℃, I. et al. (1999)
InChI InChI=1S/C4H4F6O/c5-2(4(8,9)10)3(6,7)1-11/h2,11H,1H2
InChIKey LVFXLZRISXUAIL-UHFFFAOYSA-N
SMILES C(O)C(F)(F)C(F)C(F)(F)F
CAS DataBase Reference 382-31-0(CAS DataBase Reference)
EPA Substance Registry System 1-Butanol, 2,2,3,4,4,4-hexafluoro- (382-31-0)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H302-H315-H319-H332-H335-H227
Precautionary statements  P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P403+P235-P501-P303+P361+P353-P405-P501a-P261-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn,Xi,F
Risk Statements  20/22-36/37/38
Safety Statements  26-36/37/39
RIDADR  UN 1987 3/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  III
HS Code  29055900
Storage Class 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
2
2 0

2,2,3,4,4,4-Hexafluoro-1-butanol price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical H0649 2,2,3,4,4,4-Hexafluoro-1-butanol >94.0%(GC) 382-31-0 25g $49 2026-04-30 Buy
SynQuest Laboratories 2101-3-13 2,2,3,4,4,4-Hexafluorobutan-1-ol 95% 382-31-0 500g $225 2026-05-22 Buy
SynQuest Laboratories 2101-3-13 2,2,3,4,4,4-Hexafluorobutan-1-ol 95% 382-31-0 1kg $395 2026-05-22 Buy
Chem-Impex 46266 2,2,3,4,4,4-Hexafluoro-1-butanol ≥94%(GC) 382-31-0 25G $135.7 2026-05-19 Buy
Matrix Scientific 001231 2,2,3,4,4,4-Hexafluoro-1-butanol 382-31-0 100.00g $46 2026-05-18 Buy
Product number Packaging Price Buy
H0649 25g $49 Buy
2101-3-13 500g $225 Buy
2101-3-13 1kg $395 Buy
46266 25G $135.7 Buy
001231 100.00g $46 Buy

2,2,3,4,4,4-Hexafluoro-1-butanol Chemical Properties, Uses, Production

Chemical Properties

Colorless liquid

Uses

2,2,3,4,4,4-Hexafluoro-1-butanol may be used in the preparation of fluorinated cationic guar gum (FCGG)., It may be employed as solvent to evaluate the dynamic nuclear polarization (DNP) parameters for the solutions of free radicals Galvinoxyl (GALV) and α,γ-bisdiphenylene-β-phenyl allyl complex with benzene (1:1) (BDPA).

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 910, 1955 DOI: 10.1021/ja01609a033

Synthesis

5 g of C7H14O4 and 300 g of methanol were placed in a high-pressure vessel and degassed, followed by the addition of 300 g of hexafluoropropene, and the reaction was carried out by adding nitrogen to bring the pressure in the high-pressure vessel up to 300 psi. 20 minutes later, the temperature was heated to 40C, and the reaction was maintained at this temperature for 24 hours, at which time the pressure was monitored, and the pressure was replenished with nitrogen to 300 psi when the pressure dropped below 250 psi during the reaction. When the pressure dropped below 250 psi during the reaction, it was replenished with nitrogen to 300 psi. the product solution was removed from the reaction and distilled, and 98 grams of the evaporated product were collected.

2,2,3,4,4,4-Hexafluoro-1-butanol synthesis

67-56-1
116-15-4
382-31-0
Synthesis of 2,2,3,4,4,4-Hexafluoro-1-butanol from Methanol and Hexafluoropropylene

2,2,3,4,4,4-Hexafluoro-1-butanol Preparation Products And Raw materials

Raw materials

Butane, 2-(difluoromethyl)-1,1,1,2,3,3,4,4-octafluoro- 2,2,3,4,4,4-Hexafluorobutyl formate 1,1,1,2,3,3-hexafluoro-4-methoxybutane 2,2,3,4,4,4-Hexafluorobutyl difluoromethyl ether Methyl 2,2,3,4,4,4-hexafluorobutyrate
Methyl nonafluorobutyl ether Methanol 1,4-Butanediol Hexafluoropropylene

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Preparation Products

2,2,3,4,4,4-Hexafluoro-1-butanol Suppliers

Global Suppliers ( 230)
Supplier Tel Email Country ProdList Advantage
XIANJU DOEASTCHEM Co., Ltd. 0576-87788985 13586230158 504833149@qq.com China 31 58
HARBIN XEOGIA FLUORINE –SILICON CHEMICAL CO.,LTD. 18686783750 18686783750 xeogia@vip.163.com China 16 58
Shangfluoro 021-65170832 15601903708 qinba_2@163.com China 318 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Supplier Advantage
XIANJU DOEASTCHEM Co., Ltd. 58
HARBIN XEOGIA FLUORINE –SILICON CHEMICAL CO.,LTD. 58
Shangfluoro 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56

View Latest Price from 2,2,3,4,4,4-Hexafluoro-1-butanol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL pictures 2026-09-02 2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL
382-31-0
 $2.00-10.00 1KG 99% Henan Fengda Chemical Co., Ltd
2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL pictures 2026-05-22 2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL
382-31-0
 99.99% 2000000kg Anhuyan (Hainan) Biotechnology Co., LTD
2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL pictures 2025-04-04 2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL
382-31-0
 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

2,2,3,4,4,4-Hexafluoro-1-butanol Spectrum

2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL(382-31-0)1HNMR2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL(382-31-0)Raman2,2,3,4,4,4-HEXAFLUORO-1-BUTANOL(382-31-0)IR

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1H,1H,3H-HEXAFLUOROBUTANOL 2,2,3,4,4,4-HEXAFLUOROBUTAN-1-OL 2,2,3,4,4,4-HEXAFLUOROBUTANOL 2,2,3,4,4,4-HEXAFLUOROBUTANOL-1 2,2,3,4,4,4-Hexafluorobutan-1-ol 95% 2,2,3,4,4,4-Hexafluorobutan-1-ol95% 2,2,3,3,4,4,4-HEXAFLUOROBUTANOL-1 2,2,3,4,4,4-Hexafluoro-1-butanol (HFB) 2,2,3,4,4,4-Hexafluorobutane-1-ol 2,2,3,4,4,4-Hexafluoro-1-butanol,95% 1H,1H,3H-PerfluoroButan-1-ol 2,2,3,4,4,4-Hexafluroro-1-butanol 1,1,1,2,3,3-Hexafluoro-4-hydroxybutane 1-Butanol,2,2,3,4,4,4-hexafluoro- (3R)-2,2,3,4,4,4-hexafluoro-1-butanol HEXAFLUORO-1-BUTANOL 2,2,3,4,4,4-Hexafluoro-1-butanol> uoro-1-butanoL Hexafluorobutanol (HFB) Hexafluorobutanol 2,2,3,4,4,4-Hexafluoro-1-butanol 382-31-0 CF3CHFCF2CH2OH ALCOHOL Oxygen Compounds Organic Building Blocks C2 to C6 Building Blocks Alcohols Alcohols C2 to C6 Oxygen Compounds