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Sodium ethanesulfinate

CAS No.
20035-08-9
Chemical Name:
Sodium ethanesulfinate
Synonyms
Nsc371084;ethanesulfinate;Sodium Ethanesulfinate;sodium 1-sulfinatoethane;ETHANE SULFINIC ACID SODIUM;ETHANE SULFINIC ACID SODIUM SALT;Ethanesulfinic acid, sodium salt (8CI,9CI)
CBNumber:
CB2447829
Molecular Formula:
C2H5NaO2S
Molecular Weight:
116.11
MDL Number:
MFCD06659476
MOL File:
20035-08-9.mol
MSDS File:
SDS
Last updated:2026-05-28 00:29:11

Sodium ethanesulfinate Properties

Melting point 292°C
Density 1.372
storage temp. Inert atmosphere,Room Temperature
form solid
Appearance White to light yellow Solid
InChI InChI=1S/C2H6O2S.Na/c1-2-5(3)4;/h2H2,1H3,(H,3,4);/q;+1/p-1
InChIKey UWIVVFQECQYHOB-UHFFFAOYSA-M
SMILES S(CC)(=O)[O-].[Na+]
UNSPSC Code 12352001
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P305+P351+P338
WGK Germany  WGK 3
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2

Sodium ethanesulfinate price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich ALD00294 Sodium ethylsulfinate 20035-08-9 500MG $283 2026-04-30 Buy
Matrix Scientific 067067 Ethane sulfinic acid sodium salt 20035-08-9 25.00g $49 2026-05-18 Buy
Matrix Scientific 067067 Ethane sulfinic acid sodium salt 20035-08-9 100.00g $197 2026-05-18 Buy
Matrix Scientific 067067 Ethane sulfinic acid sodium salt 20035-08-9 500.00g $680 2026-05-18 Buy
Synthonix S39781 Sodium ethanesulfinate 95+% 20035-08-9 1g $20 2026-05-06 Buy
Product number Packaging Price Buy
ALD00294 500MG $283 Buy
067067 25.00g $49 Buy
067067 100.00g $197 Buy
067067 500.00g $680 Buy
S39781 1g $20 Buy

Sodium ethanesulfinate Chemical Properties, Uses, Production

Uses

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

Synthesis

Ethanesulfonyl chloride

594-44-5

Sodium ethanesulfinate

20035-08-9

The general procedure for the synthesis of sodium ethylsulfite from ethylsulfonyl chloride was as follows: sodium sulfite (53.9 g, 0.428 mol), sodium bicarbonate (65.34 g, 0.778 mol), and deionized water (325 mL) were added to a four-necked flask equipped with a stirrer at room temperature and under nitrogen protection. The reaction mixture was stirred continuously at 80 °C for 1.3 hours. Subsequently, ethanesulfonyl chloride (50.0 g, 0.389 mol) was slowly added dropwise to the reaction system and the reaction continued to be stirred at the same temperature for 4.2 hours. Upon completion of the reaction, the reaction mixture was concentrated by rotary evaporator. Anhydrous ethanol was added to the concentrated residue and concentrated again. Next, toluene was added to the residue and the concentration process was repeated to completely remove water. The resulting solid was dried under vacuum, then anhydrous ethanol (100 mL) was added and the mixture was heated to reflux. The mixture was hot filtered and the solids were washed with a small amount of ethanol. All the filtrate and washings were combined and finally concentrated by rotary evaporator to give a white solid sodium ethylsulfite (38.96 g, yield calculated based on ethylsulfonyl chloride).

References

[1] RSC Advances, 2013, vol. 3, # 35, p. 15114 - 15120
[2] Chemistry - A European Journal, 2016, vol. 22, # 50, p. 18085 - 18091
[3] Macromolecules, 2018, vol. 51, # 20, p. 8188 - 8196
[4] Chemistry - A European Journal, 2016, vol. 22, # 25, p. 8694 - 8699
[5] Journal of Medicinal Chemistry, 1989, vol. 32, # 11, p. 2436 - 2442

Sodium ethanesulfinate Preparation Products And Raw materials

Global Suppliers ( 137)
Supplier Tel Email Country ProdList Advantage
Shanghai Taijilin Industrial Co., Ltd. 02150630626 17717886015 kate@tajilin.com China 1341 58
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Yancheng Yuntao Chemical Co., Ltd. 13512592619 2838893166@qq.com China 103 58
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. +86-21-54098501 sales@sinch.com.cn China 11592 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shandong Xiya Chemical Co., Ltd 13355009207 13355009207 3007715519@qq.com China 18722 57
China Langchem Inc. 0086-21-58956006 China 7798 57

View Latest Price from Sodium ethanesulfinate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ETHANE SULFINIC ACID SODIUM SALT pictures 2019-07-06 ETHANE SULFINIC ACID SODIUM SALT
20035-08-9
$100.00 1KG 99% Career Henan Chemical Co

Sodium ethanesulfinate Spectrum

ETHANE SULFINIC ACID SODIUM SALT Nsc371084 Sodium Ethanesulfinate sodium 1-sulfinatoethane Ethanesulfinic acid, sodium salt (8CI,9CI) ethanesulfinate ETHANE SULFINIC ACID SODIUM 20035-08-9 C2H5NaO2S C2H5O2SNa