2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID
- CAS No.
- 259269-84-6
- Chemical Name:
- 2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID
- Synonyms
- BUTTPARK 35\07-04;2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID;2-Amino-3-bromo-5-fluorobenzoicacid,95%;Benzoic acid, 2-amino-3-bromo-5-fluoro-;3-Bromo-5-fluoroanthranilic acid, 2-Bromo-6-carboxy-4-fluoroaniline
- CBNumber:
- CB3129296
- Molecular Formula:
- C7H5BrFNO2
- Molecular Weight:
- 234.02
- MDL Number:
- MFCD00662509
- MOL File:
- 259269-84-6.mol
- MSDS File:
- SDS
| Boiling point | 344.0±42.0 °C(Predicted) |
|---|---|
| Density | 1.877±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| pka | 4.21±0.10(Predicted) |
| form | Solid |
| Appearance | Off-white to yellow Solid |
| InChI | InChI=1S/C7H5BrFNO2/c8-5-2-3(9)1-4(6(5)10)7(11)12/h1-2H,10H2,(H,11,12) |
| InChIKey | LTOCPZGBNWZMBA-UHFFFAOYSA-N |
| SMILES | C(O)(=O)C1=CC(F)=CC(Br)=C1N |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 2922498590 | |||||||||
| NFPA 704 |
|
2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID price More Price(31)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | A594855 | 2-Amino-3-bromo-5-fluorobenzoicAcid | 259269-84-6 | 50mg | $60 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FA105769 | 2-amino-3-bromo-5-fluorobenzoic Acid | 259269-84-6 | 1g | $60 | 2021-12-16 | Buy |
| Oakwood | 034810 | 2-Amino-3-bromo-5-fluorobenzoicacid 90% | 259269-84-6 | 10g | $75 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FA105769 | 2-amino-3-bromo-5-fluorobenzoic Acid | 259269-84-6 | 2g | $96 | 2021-12-16 | Buy |
| Apolloscientific | PC32490 | 2-Amino-3-bromo-5-fluorobenzoicacid | 259269-84-6 | 1g | $15 | 2021-12-16 | Buy |
2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID Chemical Properties,Uses,Production
Synthesis
446-08-2
259269-84-6
General procedure for the synthesis of 2-amino-3-bromo-5-fluorobenzoic acid from 2-amino-5-fluorobenzoic acid: N-bromosuccinimide (631 mg, 3.55 mmol) was added in batches to a stirred solution of 2-amino-5-fluorobenzoic acid (7,500 mg, 3.22 mmol) dissolved in acetic acid (5 mL) and the reaction mixture was stirred at room temperature overnight . The resulting precipitate was collected by filtration, washed with petroleum ether (20 mL) and dried to constant weight to afford 2-amino-3-bromo-5-fluorobenzoic acid (11,501 mg, 66.4% yield) as a clear beige solid. The product was used without further purification. The product characterization data were as follows: LCMS (t R = 1.35 min, purity = 100%), no ions detected at ESI m/z; 1H NMR (DMSO-d6) δ (ppm) 6.76 (broad single peak, 2H), 7.55 (double peak, J = 3.0 Hz, JH-F = 9.4 Hz, 1H), 7.71 (double peak, J = 3.0 Hz, JH F = 7.8 Hz, 1H), 12.72 (broad single peak, 1H); 13C NMR (DMSO-d6) δ (ppm) 109.4 (double peak, JC-F = 7.1 Hz), 111.1 (double peak, JC-F = 7.1 Hz), 116.2 (double peak, JC-F = 22.1 Hz), 124.9 (double peak, JC-F = 24.8 Hz), 145.1, 151.4 (double peaks, JC-F = 235.3 Hz), 168.1 (double peaks, JC-F = 2.7 Hz).
References
[1] Tetrahedron, 2012, vol. 68, # 2, p. 534 - 543
[2] Patent: EP3287463, 2018, A1. Location in patent: Paragraph 0203; 0208
[3] Patent: US2018/208604, 2018, A1. Location in patent: Paragraph 0502-0503
[4] Patent: WO2016/105564, 2016, A1. Location in patent: Paragraph 0288
2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hefei Lbao Physical & Chemical Science Co.,Ltd | +1-5184799099 | lbaochemicals@gmail.com | China | 218 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29854 | 58 |
| Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2161 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569262 +86-15003564040 | 1087@dideu.com | China | 3958 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9644 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
View Lastest Price from 2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-09-24 | 2-Amino-3-bromo-5-fluorobenzoic acid
259269-84-6
|
US $0.00 / kg | 1kg | 98% | Customise | Hefei Lbao Physical & Chemical Science Co.,Ltd | |
 |
2025-07-25 | 2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID
259269-84-6
|
US $0.00 / kg | 1kg | 98% | 1000kg | Shaanxi Dideu New Materials Co. Ltd | |
 |
2025-01-03 | 2-AMino-3-broMo-5-fluorobenzoicacid
259269-84-6
|
US $0.00-0.00 / KG | 5mg | 99%HPLC | 2000tons | Shaanxi Dideu Medichem Co. Ltd |
-
- 2-Amino-3-bromo-5-fluorobenzoic acid
259269-84-6
- US $0.00 / kg
- 98%
- Hefei Lbao Physical & Chemical Science Co.,Ltd
-
- 2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID
259269-84-6
- US $0.00 / kg
- 98%
- Shaanxi Dideu New Materials Co. Ltd
-
- 2-AMino-3-broMo-5-fluorobenzoicacid
259269-84-6
- US $0.00-0.00 / KG
- 99%HPLC
- Shaanxi Dideu Medichem Co. Ltd
