5-IODO-1-METHYL-1H-PYRAZOLE
- CAS No.
- 34091-51-5
- Chemical Name:
- 5-IODO-1-METHYL-1H-PYRAZOLE
- Synonyms
- 5-Iodo-1-methylpyrazole;1-Methyl-5-iodopyrazole;5-Iodo-1-methylpyrazole>5-IODO-1-METHYL-1H-PYRAZOLE;1H-Pyrazole, 5-iodo-1-methyl-;5-Iodo-1-methyl-1H-pyrazole,97%;5-Iodo-1-methyl-1H-pyrazole
- CBNumber:
- CB31486886
- Molecular Formula:
- C4H5IN2
- Molecular Weight:
- 208
- MDL Number:
- MFCD11109327
- MOL File:
- 34091-51-5.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 5-Iodo-1-methyl-1H-pyrazole 97% | 756334 | 1g | $115 |
| 5-Iodo-1-methylpyrazole >98.0%(GC) | I0963 | 1g | $115 |
| 5-Iodo-1-methylpyrazole >98.0%(GC) | I0963 | 5g | $340 |
| 5-Iodo-1-methyl-1H-pyrazole | I709043 | 50mg | $45 |
| 5-Iodo-1-methyl-1H-pyrazole | I709043 | 100mg | $60 |
| More product size | |||
| Melting point | 80℃ |
|---|---|
| Boiling point | 226.9±13.0℃ (760 Torr) |
| Density | 2.07±0.1 g/cm3 (20 ºC 760 Torr) |
| Flash point | 91.1±19.8℃ |
| storage temp. | 2-8°C |
| solubility | soluble in Methanol |
| form | solid |
| pka | 1.02±0.10(Predicted) |
| Appearance | Off-white to light yellow Solid |
| Sensitive | Moisture & Light Sensitive |
| InChIKey | RJYWUQWCLZYCTI-UHFFFAOYSA-N |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H318-H335 | |||||||||
| Precautionary statements | P280a-P304+P340-P405-P501a-P261-P280-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 37/38-41 | |||||||||
| Safety Statements | 26-39 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2933199090 | |||||||||
| NFPA 704 |
|
5-IODO-1-METHYL-1H-PYRAZOLE price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 756334 | 5-Iodo-1-methyl-1H-pyrazole 97% | 34091-51-5 | 1g | $115 | 2023-06-20 | Buy |
| TCI Chemical | I0963 | 5-Iodo-1-methylpyrazole >98.0%(GC) | 34091-51-5 | 1g | $115 | 2025-07-31 | Buy |
| TCI Chemical | I0963 | 5-Iodo-1-methylpyrazole >98.0%(GC) | 34091-51-5 | 5g | $340 | 2025-07-31 | Buy |
| TRC | I709043 | 5-Iodo-1-methyl-1H-pyrazole | 34091-51-5 | 50mg | $45 | 2021-12-16 | Buy |
| TRC | I709043 | 5-Iodo-1-methyl-1H-pyrazole | 34091-51-5 | 100mg | $60 | 2021-12-16 | Buy |
5-IODO-1-METHYL-1H-PYRAZOLE Chemical Properties,Uses,Production
Synthesis
930-36-9
34091-51-5
Under nitrogen protection, 1-methylpyrazole (6.00 g) was dissolved in tetrahydrofuran (120 mL) and n-butyllithium (39.0 mL, 2.6 M hexane solution) was slowly added dropwise. After the dropwise addition, the reaction solution was stirred for 30 minutes. Subsequently, the reaction solution was cooled in an ice bath and stirred for 1 hour. Next, the temperature of the reaction solution was lowered to -78°C and a tetrahydrofuran (50 mL) solution of iodine (28.0 g) was slowly added dropwise. After the dropwise addition was completed, the reaction solution continued to be stirred at -78 °C for 1 hour. Afterwards, the reaction solution was allowed to slowly warm to room temperature and stirred overnight. Upon completion of the reaction, 30% aqueous sodium thiosulfate was added to the reaction solution to quench the reaction, followed by distillation under reduced pressure to remove the solvent. The residue was extracted with ethyl acetate and the organic layer was washed with saturated brine and dried over anhydrous sodium sulfate. The dried organic layer was concentrated under reduced pressure and the solid obtained was washed with n-hexane to give the final 5-iodo-1-methyl-1H-pyrazole (11.4 g) in the form of a maroon solid. The product was characterized by 1H NMR (200 MHz, chloroform-d): δppm 3.94 (s, 3H), 6.43 (d, J = 2.20 Hz, 1H), 7.47 (d, J = 1.76 Hz, 1H); mass spectrum (ESI pos.) m/z 209 [M + H]+.
References
[1] Chemical Communications, 2014, vol. 50, # 85, p. 12859 - 12862
[2] Patent: WO2016/109706, 2016, A1. Location in patent: Page/Page column 214; 215
[3] Tetrahedron Letters, 2011, vol. 52, # 36, p. 4590 - 4594
[4] Journal of Organic Chemistry, 1984, vol. 49, # 24, p. 4687 - 4695
[5] Patent: US2013/123500, 2013, A1. Location in patent: Paragraph 0225; 0226
5-IODO-1-METHYL-1H-PYRAZOLE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 3999 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21618 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29850 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8830 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Jinjiangchem Corporation | 512-50133713 | sales@jinjiangchem.com | CHINA | 1072 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
View Lastest Price from 5-IODO-1-METHYL-1H-PYRAZOLE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2024-08-05 | 5-Iodo-1-Methyl-1H-pyrazole
34091-51-5
|
US $1.00 / Kg | 1Kg | 98% | 20T | Shaanxi Dideu Medichem Co. Ltd | |
 |
2019-07-06 | 5-IODO-1-METHYL-1H-PYRAZOLE
34091-51-5
|
US $1.00 / kg | 1kg | 98% | 200KG | Career Henan Chemical Co |
-
- 5-Iodo-1-Methyl-1H-pyrazole
34091-51-5
- US $1.00 / Kg
- 98%
- Shaanxi Dideu Medichem Co. Ltd
-
- 5-IODO-1-METHYL-1H-PYRAZOLE
34091-51-5
- US $1.00 / kg
- 98%
- Career Henan Chemical Co
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