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(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%

CAS No.
817176-80-0
Chemical Name:
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
Synonyms
(S)-Tol-SDP;(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%;(S)-7,7'-Bis(di-p-tolylphosphanyl)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene];(S)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine);(S)-7,7'-bis[di(4-methylphenyl)phosphanyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[indene;(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;1,1'-[(1S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)phosphine;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE];Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-
CBNumber:
CB32129579
Molecular Formula:
C45H42P2
Molecular Weight:
644.76
MDL Number:
MFCD08459345
MOL File:
817176-80-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 01:03:03

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Properties

Melting point 150-152°C
alpha -221° (c 0.54, CH2Cl2)
Boiling point 722.0±60.0 °C(Predicted)
storage temp. -20°C
form solid
color white
optical activity [α]22/D 206°, c = 1 in chloroform
Sensitive air sensitive
InChIKey VLIOMJFCGWZUON-UHFFFAOYSA-N
SMILES Cc1ccc(cc1)P(c2ccc(C)cc2)c3cccc4CCC5(CCc6cccc(P(c7ccc(C)cc7)c8ccc(C)cc8)c56)c34
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
WGK Germany  3
Storage Class 13 - Non Combustible Solids

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 700835 (S)-Tol-SDP 817176-80-0 50mg $169 2022-05-15 Buy
Strem Chemicals 15-5181 (S)-(-)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-Tol-SDP min.97% 817176-80-0 25mg $78 2026-04-30 Buy
Strem Chemicals 15-5181 (S)-(-)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-Tol-SDP min.97% 817176-80-0 100mg $235 2026-04-30 Buy
aablocks AA003CLW (S)-Tol-SDP min.97% 817176-80-0 25mg $132 2026-05-28 Buy
aablocks AA003CLW (S)-Tol-SDP ≥97% 817176-80-0 100mg $302 2026-05-28 Buy
Product number Packaging Price Buy
700835 50mg $169 Buy
15-5181 25mg $78 Buy
15-5181 100mg $235 Buy
AA003CLW 25mg $132 Buy
AA003CLW 100mg $302 Buy

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Chemical Properties, Uses, Production

Reaction

  1. Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
  2. Ligands used for palladium-catalyzed asymmetric allylic alkylations. 

Global Suppliers ( 33)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 7909 65
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 4501 58
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4045 58
Aikon International Limited 025-58859352 13913916777 dt3@aikonchem.com China 15490 58
(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% 1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE] Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)- (S)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine) (S)-Tol-SDP (S)-7,7'-bis[di(4-methylphenyl)phosphanyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[indene 1,1'-[(1S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)phosphine (S)-7,7'-Bis(di-p-tolylphosphanyl)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene] 817176-80-0