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ChemicalBook >> CAS DataBase List >>(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy Structure
(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy structure
CAS No.
656233-53-3
Chemical Name:
(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy
Synonyms
(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY;(S)-SHIP;(R)-SHIP;1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY;PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97%;Phenyl-[(R)-1,1′-spirobiindane-7,7′-diyl]-phosphite((R)-ShiP);12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine;(R)-12-phenoxy-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine
CBNumber:
CB7382271
Molecular Formula:
C23H19O3P
Molecular Weight:
374.37
MDL Number:
MFCD08459341
MOL File:
656233-53-3.mol
Last updated:2026-09-12 18:54:55
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(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy Properties

Melting point 104-106°C
alpha +216° (c 0.5, CH2Cl2)
Boiling point 454.8±45.0 °C(Predicted)
storage temp. -20°C, protect from light, stored under nitrogen
form solid
color white
Sensitive moisture sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Hazard Codes  Xn
Risk Statements  22

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-5156 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP 656233-53-3 100mg $113 2022-04-27 Buy
Strem Chemicals 15-5156 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP 656233-53-3 500mg $452 2022-04-27 Buy
American Custom Chemicals Corporation ING0001117 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 95.00% 656233-53-3 50MG $614.87 2021-12-16 Buy
American Custom Chemicals Corporation ING0001117 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 95.00% 656233-53-3 250MG $821.64 2021-12-16 Buy
Product number Packaging Price Buy
15-5156 100mg $113 Buy
15-5156 500mg $452 Buy
ING0001117 50MG $614.87 Buy
ING0001117 250MG $821.64 Buy

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy Chemical Properties, Uses, Production

Reaction

  1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
  2. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
  3. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
  4. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
  5. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.
Reactions of 656233-53-3_1
Reactions of 656233-53-3_2

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy Preparation Products And Raw materials

Raw materials

Calcium hydride Benzyl chloride Ethanol Acetone Sodium bromide
Methanesulfonic acid Hydrogen peroxide Toluene Phenol N,N-Diisopropylethylamine
Nickel Cinchonidine Triethylamine Boron tribromide Palladium
3-Hydroxybenzaldehyde Phosphorus trichloride (R)-1,1'-Spirobiindane-7,7'-diol Tetrahydrofuran Ethyl acetate
Hydrochloric acid Sodium bicarbonate Hydrogen Dichloromethane Sodium hydroxide
Petroleum ether (S)-1,1'-Spirobiindane-7,7'-diol

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Preparation Products

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy Suppliers

Global Suppliers ( 35)
Supplier Tel Email Country ProdList Advantage
Shanghai Boyle Chemical Co., Ltd. 021-50182298 021-50180596 sales@boylechem.com China 2202 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4045 58
3A Chemicals 400-668-9898 service@3achem.com China 20535 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5978 58
Jiangsu aikang biomedical research and development co., LTD 025-58859352 17714375163 qzhang@aikonchem.com China 15525 58
Labnetwork lnc. +86-27-50766799 +86-18062016861 contact@labnetwork.com China 19981 58
Supplier Advantage
Shanghai Boyle Chemical Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Bide Pharmatech Ltd. 60
Shanghai YuanYe Biotechnology Co., Ltd. 60
LaaJoo 58
Greenherbs Science and Technology Development Co., Ltd. 58
3A Chemicals 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
Jiangsu aikang biomedical research and development co., LTD 58
Labnetwork lnc. 58

656233-53-3 ((11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy) Related Search:

Indacaterol (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy Triphenyl phosphite 2-Pyridinemethanamine, N-[(1aS,4aS,9bS)-10-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-1a,2,3,4,4a,5-hexahydro-1H-indeno[2,1-d]fluoren-9-yl]-3-methyl- 2-Pyridinemethanamine, N-[(1S)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl-
Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy

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(R)-SHIP (S)-SHIP PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy,min.98%(R)-ShiP Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy 1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97% (11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,99%e.e. Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 10,11,12,13-tetrahydro-5-phenoxy-, (11aR)- Phenyl-[(R)-1,1′-spirobiindane-7,7′-diyl]-phosphite((R)-ShiP) 12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1'',7''-fg][1,3,2]dioxaphosphocin-5-phenoxy (11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin 11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP (11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin (R)-12-phenoxy-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy 656233-53-3