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POLY(N-VINYLCARBAZOLE)

CAS No.
25067-59-8
Chemical Name:
POLY(N-VINYLCARBAZOLE)
Synonyms
PVCz;PNVC;PNVK;PVCA;dh700;tuvical210;M.N. 56,400;luvicanm150;luvicanm170;M.N. 56,400 5GR
CBNumber:
CB3288478
Molecular Formula:
C42H33N3X2
Molecular Weight:
579.73
MDL Number:
MFCD00134336
MOL File:
25067-59-8.mol
MSDS File:
SDS
Last updated:2026-01-13 11:19:46
Product description Number Pack Size Price
Poly(9-vinylcarbazole) average Mw ~1,100,000, powder 182605 5g $125
Poly(9-vinylcarbazole) average Mw ~1,100,000, powder 182605 25g $550
Poly(N-vinylcarbazole) P0656 5g $151
Poly(N-vinylcarbazole) P0656 25g $599
Poly(n-vinyl carbazole) 093 5g $32
More product size

POLY(N-VINYLCARBAZOLE) Properties

Melting point >300 °C
Density 1.2 g/mL at 25 °C(lit.)
Tg 227
refractive index n20/D 1.683
form powder
color Off-white
Stability Stable. Incompatible with strong oxidizing agents.
InChI 1S/C14H11N/c1-2-15-13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h2-10H,1H2
InChIKey KKFHAJHLJHVUDM-UHFFFAOYSA-N
SMILES [n]1(c2c(c3c1cccc3)cccc2)C=C
CAS DataBase Reference 25067-59-8(CAS DataBase Reference)
EPA Substance Registry System 9H-Carbazole, 9-ethenyl-, homopolymer (25067-59-8)
UNSPSC Code 12352103
NACRES NA.23

SAFETY

Risk and Safety Statements

Safety Statements  24/25
WGK Germany  2
RTECS  FE6225480
TSCA  TSCA listed
HS Code  29339900
Storage Class 11 - Combustible Solids
NFPA 704
0
1 0

POLY(N-VINYLCARBAZOLE) price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 182605 Poly(9-vinylcarbazole) average Mw ~1,100,000, powder 25067-59-8 5g $125 2025-07-31 Buy
Sigma-Aldrich 182605 Poly(9-vinylcarbazole) average Mw ~1,100,000, powder 25067-59-8 25g $550 2025-07-31 Buy
TCI Chemical P0656 Poly(N-vinylcarbazole) 25067-59-8 5g $151 2024-03-01 Buy
TCI Chemical P0656 Poly(N-vinylcarbazole) 25067-59-8 25g $599 2024-03-01 Buy
scipoly 093 Poly(n-vinyl carbazole) 25067-59-8 5g $32 2024-07-03 Buy
Product number Packaging Price Buy
182605 5g $125 Buy
182605 25g $550 Buy
P0656 5g $151 Buy
P0656 25g $599 Buy
093 5g $32 Buy

POLY(N-VINYLCARBAZOLE) Chemical Properties,Uses,Production

Chemical Properties

off-white crystalline powder

Uses

PVK:graphene oxide composite can be used as a hybrid film which can be coated on silica substrate for the fabrication of organic field effect transistors (OFETs). It can also form a nano-composite film with carbon nanospheres (CNS) which can be potentially used in supercapacitors and sensor based applications.

Preparation

N-Vinyl carbazole may be obtained from phenylhydrazine and cyclohexanone by the following route:

25067-59-8 synthesis


The second step in this synthesis is an example of the Fischer indole synthesis. Carbazole also occurs in coal tar.
Poly(vinyl carbazole) is produced by adiabatic bulk polymerization under nitrogen pressure using azobisisobutyronitrile and di-tert-butyl peroxide as initiators. Heating to 80-90??C causes an onset of polymerization and a rapid increase in temperature. After the maximum temperature has been reached the mass is cooled under pressure.
Poly(vinyl carbazole) is a very brittle material with a high softening point (about 195??C Vicat). It is insoluble in most organic solvents except aromatic and chlorinated hydrocarbons and tetrahydrofuran. The polymer is difficult to mould, requiring high process temperatures, namely about 300??C for injection moulding and 250??C for compression moulding. More usually the material is cast as thin film from solution. The most significant property of poly(vinyl carbazole) is its high photoconductivity and this has resulted in widespread use of the polymer in electrostatic dry-copying machines. When an electrostatic charge is applied to the polymer in the dark it discharges to an equilibrium value but when the polymer is illuminated almost complete discharging occurs. This phenomenon is used to create a latent electrostatic image which is then developed by transferring the charge to the toner.
Poly(vinyl carbazole) also has good electrical insulation characteristics which are maintained over a wide range of temperature and frequency. On account of these characteristics, the polymer has been used as a capacitor dielectric, but this application is now of minor importance.

Definition

ChEBI: A macromolecule composed of repeating 9-ethylcarbazole units.

General Description

Poly(9-vinylcarbazole) (PVK) is a conductive polymer which is mainly used as a hole transporting medium at high efficiencies with low driving voltage. It can also be used as an anode for hole injection and can act as an effective charge transferring gate by co-doping it with organic dyes.

Solubility in organics

Benzene, chloroform, dichloromethane, dioxane, THF, toluene

Purification Methods

Precipitate it seven times from tetrahydrofuran with MeOH, with final freeze-drying from *benzene. Dry it under vacuum.

POLY(N-VINYLCARBAZOLE) Preparation Products And Raw materials

Global( 155)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20128 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29833 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5600 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5742 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 11728 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739 info@dycnchem.com China 52846 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 17259 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615531151365 mina@chuanghaibio.com China 18126 58
PT CHEM GROUP LIMITED
+86-85511178; peter68@ptchemgroup.com China 35425 58

View Lastest Price from POLY(N-VINYLCARBAZOLE) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
poly(n-vinylcarbazole) pictures 2025-09-25 poly(n-vinylcarbazole)
25067-59-8
US $188.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
POLY(N-VINYLCARBAZOLE) pictures 2019-07-06 POLY(N-VINYLCARBAZOLE)
25067-59-8
US $300.00 / KG 10G 99% customise Career Henan Chemical Co
tuvical210 N-VINYLCARBAZOLE POLYMER POLYVINYL CARBAZOLE POLY(N-VINYLCARBAZOL) POLY(9-VINYLCARBAZOLE), SECONDARY STANDA RD Poly(N-vinylcarbazole), approx. M.W. 90,000 Poly(N-vinylcarbazole), secondary standard M.N. 56,400 Poly(N-vinylcarbazole), secondary standard, M.W. 135,600 9-Vinyl-9H-carbazole POLY(N-VINYLCARBAZOLE) POLY(9-VINYLCARBAZOLE) 9-ethenyl-9h-carbazolhomopolymer 9-vinylcarbazolehomopolymer 9-vinyl-carbazolpolymer dh700 luvicanm150 luvicanm170 Poly(9-vinylcarbazole) average Mn 25,000-50,000 Poly(9-vinylcarbazole) average Mw ~1,100,000, powder poly(vinylcarbazole) macromolecule Poly(N-vinylcarbazole), average M.W. 90,000 n-vinylcarbazolehomopolymer polyvinyl carbazole (PVK) Poly(n-vinylcarbazole), secondary standard, MW. 135,600: MN. 56,400 9-Vinylcarbazole polymer Poly(9-vinyl-9H-carbazole) Poly(N-vinylcarbazole) [approx. M.W. 9000] Poly(9-vinylcarbazole),PVK PVK , Poly(N-vinylcarbazole) M.N. 56,400 5GR Poly(N-vinylcarbazole), approx. M.W. 90,000 10GR Poly(N-vinylcarbazole), approx. M.W. 90,000 25GR PVCz PNVC PNVK Poly(9-ethenyl-9H-carbazole) Poly[1-(N-carbazolyl)ethylene] PVCA PVK, Poly(9-vinylcarbazole) Poly(9-vinylcarbazole) MW:180000 25067-59-8 C42H33N3X2 -C12H6NHCHCH2n C12H8NCHCH2n POLB - POLY Alphabetic Electroluminescence Carbazoles (for Conduting Polymer Research) Carbazoles Reagents for Conducting Polymer Research Analytical Standards Analytical Chromatography Product Catalog Carbazoles Carbazoles (for Conduting Polymer Research) Electroluminescence Functional Materials Reagents for Conducting Polymer Research